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We present new efficient (O(N log N)) methods for computing three quantities crucial to electronic structure calculations: the ionic potential, the electron-ion contribution to the Born-Oppenheimer forces, and the electron-ion contribution…

Materials Science · Physics 2009-11-07 Nicholas Choly , Efthimios Kaxiras

Here we describe an approach for simulating electronic structure on quantum computers with significantly lower asymptotic complexity than prior work. The approach uses a real-space first-quantised representation of the molecular Hamiltonian…

This review discusses progress in efficient solvers which have as their foundation a representation in real space, either through finite-difference or finite-element formulations. The relationship of real-space approaches to linear-scaling…

Materials Science · Physics 2009-10-31 Thomas L. Beck

We present a new method for calculating electronic states in low-dimensional semiconductor heterostructures, which is based on the real-space Hamiltonian in the envelope function approximation. The numerical implementation of the method is…

Mesoscale and Nanoscale Physics · Physics 2011-06-01 Yong-Hee Cho , Alexey Belyanin

We study the accuracy of the divide-and-conquer method for electronic structure calculations. The analysis is conducted for a prototypical subdomain problem in the method. We prove that the pointwise difference between electron densities of…

Numerical Analysis · Mathematics 2015-04-07 Jingrun Chen , Jianfeng Lu

A new method of solution to the local spin density approximation to the electronic Schr\"{o}dinger equation is presented. The method is based on an efficient, parallel, adaptive multigrid eigenvalue solver. It is shown that adaptivity is…

mtrl-th · Physics 2009-09-25 E. Bylaska , S. Khon , S. Baden , A. Edelman , R. Kawai , M. E. G. Ong , J. H. Weare

The standard particle-in-cell algorithm suffers from grid heating. There exists a gridless alternative which bypasses the deposition step and calculates each Fourier mode of the charge density directly from the particle positions. We show…

Plasma Physics · Physics 2019-09-04 Matthew S. Mitchell , Matthew T. Miecnikowski , Gregory Beylkin , Scott E. Parker

In this paper, we propose a parallel optimization method for electronic structure calculations based on a single orbital-updating approximation. It is shown by our numerical experiments that the method is efficient and reliable for atomic…

Numerical Analysis · Mathematics 2015-11-20 Xiaoying Dai , Zhuang Liu , Xin Zhang , Aihui Zhou

Optimal exploitation of supercomputing resources for the evaluation of electrostatic forces remains a challenge in molecular dynamics simulations of very large systems. The most efficient methods are currently based on particle-mesh Ewald…

Computational Physics · Physics 2025-09-23 Federica Troni , Davide Grassano , Jayashree Narayan , Benoît Roux , Sara Bonella

In this paper, we propose an orbital iteration based parallel approach for electronic structure calculations. This approach is based on our understanding of the single-particle equations of independent particles that move in an effective…

Numerical Analysis · Mathematics 2014-11-06 Xiaoying Dai , Xingao Gong , Aihui Zhou , Jinwei Zhu

A novel low complexity method to perform self-consistent electronic-structure calculations using the Kohn-Sham formalism of density functional theory is presented. Localization constraints are neither imposed nor required thereby allowing…

Computational Physics · Physics 2007-05-23 M. J. Rayson

Micro-Electro-Mechanical-Systems are complex structures, often involving nonlinearites of geometric and multiphysics nature, that are used as sensors and actuators in countless applications. Starting from full-order representations, we…

Dynamical Systems · Mathematics 2023-04-04 Giorgio Gobat , Stefania Fresca , Andrea Manzoni , Attilio Frangi

We propose a non grid-based interpolation scheme based on the information from the data collected from the vicinity of the query point. As a non-grid-based interpolation, the data points can be distributed randomly in a small region, and…

Numerical Analysis · Mathematics 2016-09-21 Kai Lin , Wei-Liang Qian

We discuss our new implementation of the Real-space Electronic Structure method for studying the atomic and electronic structure of infinite periodic as well as finite systems, based on density functional theory. This improved version which…

Materials Science · Physics 2009-10-31 U. V. Waghmare , Hanchul Kim , I. J. Park , Normand Modine , P. Maragakis , Efthimios Kaxiras

An efficient and robust linear scaling method is presented for large scale {\it ab initio} electronic structure calculations of a wide variety of materials including metals. The detailed short range and the effective long range…

Other Condensed Matter · Physics 2016-08-31 Taisuke Ozaki

A recently developed density functional method, within Hohenberg-Kohn-Sham framework, is used for faithful description of atoms, molecules in Cartesian coordinate grid, by using an LCAO-MO ansatz. Classical Coulomb potential is obtained by…

Chemical Physics · Physics 2013-07-16 Amlan K. Roy

An approximate relativistic two-component Hamiltonian for use in molecular electronic structure calculations is derived in the form of a sum of fixed atom-centered kinetic and spin-orbit operators added to the non-relativistic Hamiltonian.…

Chemical Physics · Physics 2019-02-13 Dimitri N. Laikov

Hybrid density functional calculation is indispensable to accurate description of electronic structure, whereas the formidable computational cost restricts its broad application. Here we develop a deep equivariant neural network method…

Materials Science · Physics 2023-02-17 Zechen Tang , He Li , Peize Lin , Xiaoxun Gong , Gan Jin , Lixin He , Hong Jiang , Xinguo Ren , Wenhui Duan , Yong Xu

In this work, we present a high-fidelity and efficient point-particle direct numerical simulation framework based on a multi-block overset curvilinear grid system, enabling large-scale Lagrangian particle tracking in complex geometries with…

Fluid Dynamics · Physics 2025-09-10 Taiyang Wang , Baoqing Meng , Baolin Tian , Yaomin Zhao

We present a higher-order extension of the dual cell method for the time-domain Maxwell equations in three spatial dimensions. The approach builds upon a variational reinterpretation of the Finite Integration Technique on dual meshes and…

Numerical Analysis · Mathematics 2026-04-16 Lorenzo Codecasa , Bernard Kapidani , Joachim Schöberl , Markus Wess