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Molecular dynamics simulations have been performed on pure liquid water, aqueous solutions of sodium chloride, and polymer solutions exposed to a strong external electric field with the goal to gain molecular insight into the structural…

Soft Condensed Matter · Physics 2016-08-08 I. Nezbeda , J. Jirsák , F. Moučka , W. R. Smith

Lipid membranes have complex compositions and modeling the thermodynamic properties of multi-component lipid systems remains a remote goal. In this work we attempt to describe the thermodynamics of binary lipid mixtures by mapping…

Soft Condensed Matter · Physics 2024-09-04 L. Berezovska , R. Kociurzynski , F. Thalmann

I briefly review a recent series of papers putting forward a coarse-grained theoretical approach to the physics of supercooled liquids approaching their glass transition. After a suitable coarse-graining, the dynamics of the liquid is…

Statistical Mechanics · Physics 2009-11-10 Ludovic Berthier

Molecular design requires systematic and broadly applicable methods to extract structure-property relationships. The focus of this study is on learning thermodynamic properties from molecular-liquid simulations. The methodology relies on an…

Materials Science · Physics 2023-07-04 Bernadette Mohr , Diego van der Mast , Tristan Bereau

Thermodynamic and electronic properties are obtained for a lattice-gas model fluid with self-consistent, partial, occupation of its sites; the self consistency consists in obtaining ionic configurations from grand-canonical Monte Carlo…

Statistical Mechanics · Physics 2009-10-30 M. Reinaldo-Falagan , P. Tarazona , E. Chacon , J. P. Hernandez

We report an ab initio molecular dynamics simulation study of several static and dynamic properties of the liquid 3d transition metals. The calculated static structure factors show qualitative agreement with the available experimental data,…

Soft Condensed Matter · Physics 2020-05-27 B. G. del Rio , C. Pascual , O. Rodriguez , L. E. González , D. J. González

In order to test the Vibration-Transit (V-T) theory of liquid dynamics, ab initio density functional theory (DFT) calculations of thermodynamic properties of Na and Cu are performed and compared with experimental data. The calculations are…

We investigate the occurrence of waterlike thermodynamic and dynamic anomalous behavior in a one dimensional lattice gas model. The system thermodynamics is obtained using the transfer matrix technique and anomalies on density and…

Soft Condensed Matter · Physics 2015-03-11 Marco Aurélio A. Barbosa , Fernando Vito Barbosa , Fernando Albuquerque de Oliveira

The interplay of slow dynamics and thermodynamic features of dense liquids is studied by examinining how the glass transition changes depending on the presence or absence of Lennard-Jones-like attractions. Quite different thermodynamic…

Materials Science · Physics 2009-11-13 Th. Voigtmann

We use numerical simulation to examine the possibility of a reversible liquid-liquid transition in supercooled water and related systems. In particular, for two atomistic models of water, we have computed free energies as functions of…

Statistical Mechanics · Physics 2012-05-11 David T. Limmer , David Chandler

In supercooled liquids, at a temperature between the glass transition temperature Tg and the melting point Tm, thermodynamic properties remain continuous, while dynamic behavior exhibits anomalies. The origin of such thermodynamics-dynamic…

Soft Condensed Matter · Physics 2025-06-17 X. R. Tian , D. M. Zhang , B. Zhang , D. Y. Sun , X. G. Gong

Three structural populations with distinct average mobility are identified within an equilibrium two-dimensional Lennard-Jones fluid simulated via molecular dynamics at a constant temperature and varying density. Quantifying the structure…

Soft Condensed Matter · Physics 2018-02-05 Tamoghna Das , Jack F. Douglas

Macroscopic systems of hydrogen molecules exhibit a rich thermodynamic phase behavior. Due to the simplicity of the molecular constituents a detailed exploration of the thermal properties of these boson systems at low temperatures is of…

Other Condensed Matter · Physics 2009-11-11 Thomas Lindenau , Manfred L. Ristig , Klaus A. Gernoth , Javier Dawidowski , Francisco J. Bermejo

The ground-state properties of one-dimensional 3He are studied using quantum Monte Carlo methods. The equation of state is calculated in a wide range of physically relevant densities and is well reproduced by a power-series fit. The…

Quantum Gases · Physics 2015-01-12 G. E. Astrakharchik , J. Boronat

We give a brief introduction to the mode-coupling theory of the glass transition, a theory which was proposed a while ago to describe the dynamics of supercooled liquids. After presenting the basic equations of the theory, we review some of…

Statistical Mechanics · Physics 2008-02-03 W. Kob

Dynamical crossover in water is studied by means of computer simulation. The crossover temperature is calculated from the behavior of velocity autocorrelation functions. The results are compared with experimental data. It is shown that the…

Soft Condensed Matter · Physics 2015-02-11 Yu. D. Fomin , V. N. Ryzhov , E. N. Tsiok , V. V. Brazhkin

Understand the nature of liquid structure and its evolution under different conditions is a major challenge in condensed physics and materials science. Here, we report a pressure-induced structure change spanning a wide pressure range in…

Materials Science · Physics 2025-01-28 X. Z. Yan , Y. M. Chen , Hua Y. Geng , Y. F. Wang , Y. Sun , L. L. Zhang , H. Wang , Y. L. Xu

Classical molecular dynamics simulations are performed on LiF in the framework of the polarizable ion model. The overlap-repulsion and polarization terms of the interaction potential are derived on a purely non empirical, first-principles…

Materials Science · Physics 2015-01-07 Dario Corradini , Dario Marrocchelli , Paul A. Madden , Mathieu Salanne

We apply to a liquid of linear molecules the semischematic mode-coupling model, previously introduced to describe the center of mass (COM) slow dynamics of a network-forming molecular liquid. We compare the theoretical predictions and…

Soft Condensed Matter · Physics 2009-10-31 Linda Fabbian , Rolf Schilling , Francesco Sciortino , Piero Tartaglia , Christoph Theis

Strongly interacting, dynamically disordered and with no small parameter, liquids took a theoretical status between gases and solids. We review different approaches to liquids and propose that liquids do not need classifying in terms of…

Soft Condensed Matter · Physics 2016-01-13 K. Trachenko , V. V. Brazhkin