Related papers: Molecular Chirality and Chiral Parameters
In many biological materials with a hierarchical structure there is an intriguing and unique mechanism responsible for the 'propagation' of order from the molecular to the nano- or micro-scale level. Here we present a much simpler molecular…
Crystals and quasicrystals can be characterized by an order that is a purely geometric property of an instantaneous configuration, independent of particle dynamics or interactions. Glasses, on the other hand, are ostensibly amorphous…
The chirality of an object can be studied by measuring the circular dichroism, that is, the difference in absorption of light with different helicity. The chiral optical response of an object, however, can have two different origins. On the…
Geometrical chirality is a property of objects that describes three-dimensional mirror-symmetry violation and therefore it requires a non-vanishing spatial extent. In contrary, optical chirality describes only the local handedness of…
The occurrence of biological homochirality is attributed to symmetry breaking mechanisms which are still debatable1. Studies of symmetry breaking require tools for monitoring the population ratios of individual chiral nano-objects, such as…
Chirality in inorganic nanoparticles and nanostructures has gained increasing scientific interest, because of the possibility to tune their ability to interact differently with left- and right-handed circularly polarized light. In some…
Major advances in X-ray sources including the development of circularly polarized and orbital angular momentum pulses make it possible to probe matter chirality at unprecedented energy regimes and with Angstr\"om and femtosecond…
Topology, a well-established concept in mathematics, has nowadays become essential to describe condensed matter. At its core are chiral electron states on the bulk, surfaces and edges of the condensed matter systems, in which spin and…
Circular dichroism (CD), induced by chirality, is an important tool for manipulating light or for characterizing morphology of molecules, proteins, crystals and nano-structures. CD is manifested over a wide size-range, from molecules to…
Photons experience mirror asymmetry of macroscopic chiral media, as in circular dichroism and polarization rotation, since left and right handed circular polarizations differently couple with matter handedness. Conversely, free relativistic…
Most animal body plans have some degree of left-right asymmetry. This chirality at the tissue and organ level is often assumed to originate from the intrinsic handedness of biological molecules. How this handedness might be transferred from…
Electron chirality has been proposed as a microscopic quantity that characterizes electronic handedness, yet its underlying control parameter has not been clearly identified. Furthermore, its applicability is limited to systems with…
Chirality is a concept that one object is not superimposable on its mirror image by translation and rotation. In particular, chiral plasmonics have been widely investigated due to their excellent optical chiral properties, and have led to…
The presence of chirality in the main molecules of life may well be not just a structural artifact, but of pure biological advantage. The possibility of the existence of a phenomenon of a special mode of interaction, labeled as "chiral…
One of the molecular properties most intuitive to the human perception is the geometrical shape. However, when exploring a large chemical space the determination of shape needs to be automated. We present a fast and simple approach to…
We propose a predictive building-up of tetrahedral molecules, based on a previously derived chirality index, which characterizes a tetrahedral molecule, with n chiral centers, as achiral, diastereoisomer, or enantiomer as a function of the…
The coalescence of three levels has particular attractive features. Even though it may be difficult to realise such event in the laboratory (three additional real parameters must be adjusted), to take up the challenge seems worthwhile. In…
Chirality is considered by many scientists to be mainly a geometric concept. There exists also a physical aspect of chirality which is largely being overlooked at. Two examples of mechanical devices are introduced here that represent…
We have investigated the relationship between the morphology of helical particles and the features of the cholesteric (N$^\ast $) phase that they form. Using an Onsager-like theory, applied to systems of hard helices, we show that the…
We study the effective chiral interaction between molecules arising from quantum dispersion interactions within a model in which a) the dominant excited states of a molecule form a band whose width is small compared to the average…