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We study the energy of relativistic electrons and positrons interacting via the second quantized Coulomb potential in the field of a nucleus of charge Z within the Hartree-Fock approximation. We show that the associated functional has a…

Mathematical Physics · Physics 2007-05-23 J. -M. Barbaroux , W. Farkas , B. Helffer , H. Siedentop

We construct a general theory of operator monotonicity and apply it to the Fr\"ohlich polaron hamiltonian. This general theory provides a consistent viewpoint of the Fr\"ohlich model.

Mathematical Physics · Physics 2015-06-12 Tadahiro Miyao

The static and dynamic electric multipolar polarizabilities and second hyperpolarizabilities of the H$_2^+$, D$_2^+$, and HD$^+$ molecular ions in the ground and first excited states are calculated nonrelativistically using explicitly…

Atomic Physics · Physics 2014-09-23 Li-Yan Tang , Zong-Chao Yan , Ting-Yun Shi , James F. Babb

This paper reports an implementation of Hartree-Fock linear response with complex orbitals for computing electronic spectra of molecules in a strong external magnetic fields. The implementation is completely general, allowing for…

Chemical Physics · Physics 2019-02-01 Sangita Sen , Kai K. Lange , Erik I. Tellgren

We study the spectra of the molecular orbital Hessian (stability matrix) and random-phase approximation Hamiltonian of broken-symmetry Hartree-Fock solutions, focusing on zero eigenvalue modes. After all negative eigenvalues are removed…

The Hamiltonian operator plays a central role in quantum theory being a generator of unitary quantum dynamics. Its expectation value describes the energy of a quantum system. Typically being a non-unitary operator, the action of the…

Quantum Physics · Physics 2021-08-03 Tatiana A. Bespalova , Oleksandr Kyriienko

The multiconfigurational time-dependent Hartree-Fock equations are discussed and solved for a one-dimensional model of the Helium atom. Results for the ground state energy and two-particle density as well as the absorption spectrum are…

Quantum Physics · Physics 2015-03-13 D. Hochstuhl , S. Bauch , M. Bonitz

The Hartree-Fock-Bogoliubov equation for the ground states of even-even atomic nuclei is solved using the canonical representation in the coordinate space for zero range interactions like the Skyrme force. The gradient method is improved…

Nuclear Theory · Physics 2007-05-23 Naoki Tajima

In our work we construct a Hamiltonian, whose eigenstates approximate the solutions of the self-consistent Hartree-Fock equations for nonrelativistic atoms and ions. Its eigenvalues are given by completely algebraic expressions and the…

Quantum Physics · Physics 2025-06-18 N. Q. San , O. D. Skoromnik , V. V. Triguk , I. D. Feranchuk

The ground-state energy, the addition energies and the optical absorption spectra are derived for interacting polarons in parabolic quantum dots in three and two dimensions. A path integral formalism for identical particles is used in order…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 S. N. Klimin , V. M. Fomin , F. Brosens , J. T. Devreese

The Hartree-Fock based diagonalization is a computational method for the investigation of the low-energy properties of correlated electrons in disordered solids. The method is related to the quantum-chemical configuration interaction…

Disordered Systems and Neural Networks · Physics 2007-05-23 Michael Schreiber , Thomas Vojta

The energy levels of hydrogen and helium atoms in strong magnetic fields are calculated in this study. The current work contains estimates of the binding energies of the first few low-lying states of these systems that are improvements upon…

Astrophysics · Physics 2012-02-08 Anand Thirumalai , Jeremy S. Heyl

Solving analytic systems using inversion can be implemented in a variety of ways. One method is to use Lagrange inversion and variations. Here we present a different approach, based on dual vector fields. For a function analytic in a…

Classical Analysis and ODEs · Mathematics 2011-02-11 Ph. Feinsilver , R. Schott

We explore the existence and behaviour of holomorphic restricted Hartree-Fock (h-RHF) solutions for two-electron problems. Through algebraic geometry, the exact number of solutions with $n$ basis functions is rigorously identified as…

Chemical Physics · Physics 2018-01-15 Hugh G. A. Burton , Mark Gross , Alex J. W. Thom

A perturbation theory scheme in terms of electron hopping, which is based on the Wick theorem for Hubbard operators, is developed. Diagrammatic series contain single-site vertices connected by hopping lines and it is shown that for each…

Strongly Correlated Electrons · Physics 2009-10-31 A. M. Shvaika

We describe the new version (v1.75r) of the code HFODD which solves the nuclear Skyrme-Hartree-Fock problem by using the Cartesian deformed harmonic-oscillator basis. Three minor errors that went undetected in the previous version have been…

Nuclear Theory · Physics 2009-11-06 J. Dobaczewski , J. Dudek

The short range repulsion between nucleons is treated by a unitary correlation operator which shifts the nucleons away from each other whenever their uncorrelated positions are within the replusive core. By formulating the correlation as a…

Nuclear Theory · Physics 2009-10-30 H. Feldmeier , T. Neff , R. Roth , J. Schnack

On the grounds of a Feynman-Kac--type formula for Hamiltonian lattice systems we derive analytical expressions for the matrix elements of the evolution operator. These expressions are valid at long times when a central limit theorem…

Other Condensed Matter · Physics 2007-05-23 Massimo Ostilli , Carlo Presilla

A method is presented in which the ground-state subspace is projected out of a Hamiltonian representation. As a result of this projection, an effective Hamiltonian is constructed where its ground-state coincides with an excited-state of the…

Quantum Physics · Physics 2023-08-14 P. Jouzdani , S. Bringuier , M. Kostuk

A resonant level strongly coupled to a local phonon under nonequilibrium conditions is investigated. The nonequilibrium Hartree-Fock approximation is shown to correspond to approximating the steady state density matrix by delta functions at…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 A. Mitra , I. Aleiner , A. J. Millis
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