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We propose excess Gibbs free energy graph neural networks (GE-GNNs) for predicting composition-dependent activity coefficients of binary mixtures. The GE-GNN architecture ensures thermodynamic consistency by predicting the molar excess…

Disordered Systems and Neural Networks · Physics 2024-11-05 Jan G. Rittig , Alexander Mitsos

A baroclinic model for the atmospheric jet at middle-latitudes is used as a stochastic generator of time series of the total energy of the system. Statistical inference of extreme values is applied to yearly maxima sequences of the time…

Geophysics · Physics 2009-11-11 Mara Felici , Valerio Lucarini , Antonio Speranza , Renato Vitolo

In QM/MM indirect free energy simulation, QM/MM corrections can be obtained from integration of partial derivatives of alchemical Hamiltonians or from perturbation-based estimators including free energy perturbation (FEP) and acceptance…

Chemical Physics · Physics 2018-10-05 Xiaohui Wang , Zhaoxi Sun

We propose a Monte Carlo method which performs a random walk in energy space using cluster-like collective updates. By imposing that bond probabilities depend continuously on the microcanonical temperature, we obtain dynamic exponents close…

Statistical Mechanics · Physics 2007-05-23 Sylvain Reynal , Hung-The Diep

We propose a novel family of test statistics to detect the presence of changepoints in a sequence of dependent, possibly multivariate, functional-valued observations. Our approach allows to test for a very general class of changepoints,…

Methodology · Statistics 2023-10-10 B. Cooper Boniece , Lajos Horváth , Lorenzo Trapani

Message-passing graph neural networks (GNNs) excel at capturing local relationships but struggle with long-range dependencies in graphs. In contrast, graph transformers (GTs) enable global information exchange but often oversimplify the…

Machine Learning · Computer Science 2024-10-08 Dexiong Chen , Till Hendrik Schulz , Karsten Borgwardt

Grain boundary (GB) energy is a fundamental property that affects the form of grain boundary and plays an important role to unveil the behavior of polycrystalline materials. With a better understanding of grain boundary energy distribution…

Computational Physics · Physics 2020-02-04 Haoyu Wang , Srikanth Patala , Brian J. Reich

Hybrid Bond Graph (HBG) is a Bond Graph-based modelling approach which provides an effective tool not only for dynamic modeling but also for fault detection and isolation (FDI) of switching systems. Bond graph (BG) has been proven useful…

Systems and Control · Computer Science 2013-12-10 Taher Mekki , Slim Triki , Anas Kamoun

Hypergraphs serve as an effective tool widely adopted to characterize higher-order interactions in complex systems. The most intuitive and commonly used mathematical instrument for representing a hypergraph is the incidence matrix, in which…

Social and Information Networks · Computer Science 2026-04-22 Junhao Bian , Yilin Bi , Tao Zhou

We obtain large deviation results for non-uniformly expanding maps with non-flat singularities or criticalities and for partially hyperbolic non-uniformly expanding attracting sets. That is, given a continuous function we consider its space…

Dynamical Systems · Mathematics 2018-09-14 V Araujo , M J Pacifico

Monte Carlo simulations have boosted the numerical study of several different physical systems and in particular, the canonical ensemble has been especially useful because of the existence of easy and efficient relaxation algorithms…

Statistical Mechanics · Physics 2019-10-29 G. Palma , A. Riveros

In a recent Letter, Baer et al. present a stochastic method for Kohn-Sham density functional theory calculations. Their convergence criterion is the self-averaging total energy per electron, which requires a number of statistical samples…

Materials Science · Physics 2014-04-15 Jonathan E. Moussa , Andrew D. Baczewski

In the evolving field of psychopathology, the accurate assessment and forecasting of data derived from Ecological Momentary Assessment (EMA) is crucial. EMA offers contextually-rich psychopathological measurements over time, that…

Machine Learning · Computer Science 2024-03-29 Mandani Ntekouli , Gerasimos Spanakis , Lourens Waldorp , Anne Roefs

Heterogeneous graphs, comprising diverse node and edge types connected through varied relations, are ubiquitous in real-world applications. Message-passing heterogeneous graph neural networks (HGNNs) have emerged as a powerful model class…

Machine Learning · Computer Science 2025-12-10 Junwei Su , Lingjun Mao , Zheng Da , Chuan Wu

Regression control charts are usually used to monitor variables of interest that are related to control variables. However, for fraction and/or proportion data, the use of standard regression control charts may not be adequate, since the…

Methodology · Statistics 2018-04-05 Fábio Mariano Bayer , Catia Michele Tondolo , Fernanda Maria Müller

In regimes of low signal strengths and therefore a small signal-to-noise ratio, standard data analysis methods often fail to accurately estimate system properties. We present a method based on Monte Carlo simulations to effectively restore…

The histogram is widely used as a simple, exploratory display of data, but it is usually not clear how to choose the number and size of bins. We construct a confidence set of distribution functions that optimally address the two main tasks…

Statistics Theory · Mathematics 2020-02-13 Housen Li , Axel Munk , Hannes Sieling , Guenther Walther

Power control in decentralized wireless networks poses a complex stochastic optimization problem when formulated as the maximization of the average sum rate for arbitrary interference graphs. Recent work has introduced data-driven design…

Information Theory · Computer Science 2021-05-04 Ivana Nikoloska , Osvaldo Simeone

In recent years, several approaches for modelling pedestrian dynamics have been proposed and applied e.g. for design of egress routes. However, so far not much attention has been paid to their 'quantitative' validation. This unsatisfactory…

Physics and Society · Physics 2008-10-13 A. Seyfried , M. Boltes , J. Kähler , W. Klingsch , A. Portz , T. Rupprecht , A. Schadschneider , B. Steffen , A. Winkens

Context. Explaining the accelerated expansion of the Universe is one of the fundamental challenges in physics today. Cosmography provides information about the evolution of the universe derived from measured distances, assuming only that…

Cosmology and Nongalactic Astrophysics · Physics 2016-10-05 Marek Demianski , Ester Piedipalumbo , Disha Sawant , Lorenzo Amati
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