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A class of binary mixtures of Janus fluids formed by colloidal spheres with the hydrophobic hemispheres constrained to point either up or down are studied by means of Gibbs ensemble Monte Carlo simulations and simple analytical…

Soft Condensed Matter · Physics 2013-11-14 Riccardo Fantoni , Achille Giacometti , Miguel Ángel G. Maestre , Andrés Santos

We use specialized Monte Carlo simulation methods and moment free energy calculations to provide conclusive evidence that dense polydisperse spheres at equilibrium demix into coexisting fcc phases, with more phases appearing as the spread…

Statistical Mechanics · Physics 2013-05-29 Peter Sollich , Nigel B. Wilding

We consider classical hard-core particles moving on two parallel chains in the same direction. An interaction between the channels is included via the hopping rates. For a ring, the stationary state has a product form. For the case of…

Statistical Mechanics · Physics 2011-07-13 Vladislav Popkov , Ingo Peschel

One versatile route to the creation of two-dimensional crystal structures on the nanometer to micrometer scale is the self-assembly of colloidal particles at an interface. Here, we explore the crystal phases that can be expected from the…

Soft Condensed Matter · Physics 2020-05-29 Etienne Fayen , Anuradha Jagannathan , Giuseppe Foffi , Frank Smallenburg

We extend the transfer matrix method of one-dimensional hard core fluids placed between confining walls for that case where the particles can pass each other and at most two layers can form. We derive an eigenvalue equation for a…

Statistical Mechanics · Physics 2015-06-29 Peter Gurin , Szabolcs Varga

We present a novel framework exploiting the cascade of phase transitions occurring during a simulated annealing of the Expectation-Maximisation algorithm to cluster datasets with multi-scale structures. Using the weighted local covariance,…

Machine Learning · Statistics 2021-01-13 T. Bonnaire , A. Decelle , N. Aghanim

We consider mixtures of two species of spherical colloidal particles that differ in their hydrodynamic radii, but are otherwise identical, in the presence of an external field. Since the particle-particle and particle-field interactions are…

Soft Condensed Matter · Physics 2018-09-26 André S. Nunes , Akshat Gupta , Nuno A. M. Araújo , Margarida M. Telo da Gama

A binary colloidal mixture of unequal sizes, subjected to an external potential barrier, has been investigated using canonical ensemble molecular dynamics simulations. The attractive depletion interaction between the external barrier and…

Soft Condensed Matter · Physics 2022-03-11 Mahammad Mustakim , A. V. Anil Kumar

We study self-assembly of a binary mixture of components A and B confined in a slit-like pore with the walls modified by the stripes of tethered brushes made of beads of a sort A. The emphasis is on solvent mediated transitions between…

Soft Condensed Matter · Physics 2013-03-26 Ja. M. Ilnytskyi , S. Sokolowski , T. Patsahan

We use discontinuous molecular dynamics and grand-canonical transition-matrix Monte Carlo simulations to explore how confinement between parallel hard walls modifies the relationships between packing fraction, self-diffusivity, partial…

Soft Condensed Matter · Physics 2009-11-13 Jeetain Mittal , Vincent K. Shen , Jeffrey R. Errington , Thomas M. Truskett

Two-dimensional ionic liquids with single site anion and cation-neutral dimer are studied by computer simulations and integral equation techniques, with the aim of characterizing differences with single site anion-cation mixtures, and also…

Chemical Physics · Physics 2018-10-17 Perera Aurélien , Urbic Tomaz

We study a two-dimensional fluid of dipolar hard disks by Monte Carlo simulations in a square with periodic boundary conditions and on the surface of a sphere. The theory of the dielectric constant and the asymptotic behaviour of the…

Soft Condensed Matter · Physics 2015-10-28 Jean-Michel Caillol , Jean-Jacques Weis

We study fluid-fluid phase separation in a colloid-polymer mixture adsorbed in a colloidal porous matrix close to the \theta -point. For this purpose we consider the Asakura-Oosawa model in the presence of a quenched matrix of colloidal…

Soft Condensed Matter · Physics 2015-05-30 Mario Alberto Annunziata , Andrea Pelissetto

Spontaneous phase separation, or demixing, is important in biological phenomena such as cell sorting. In particle-based models, an open question is whether differences in diffusivity can drive such demixing. While…

Soft Condensed Matter · Physics 2023-07-10 Erin McCarthy , Ojan Damavandi , Raj Kumar Manna , M. Lisa Manning

We present dynamical density functional theory results for the time evolution of the density distribution of a sedimenting model two-dimensional binary mixture of colloids. The interplay between the bulk phase behaviour of the mixture, its…

Soft Condensed Matter · Physics 2015-06-17 Alexandr Malijevsky , Andrew J. Archer

We study the thermodynamic behavior of nonpolar liquid mixtures in the vicinity of curved charged objects, such as electrodes or charged colloids. For small enough charge on the object, or equivalently, small potential, the…

Statistical Mechanics · Physics 2009-11-13 Gilad Marcus , Sela Samin , Yoav Tsori

A theoretical scheme for the calculation of the full phase diagram (including cloud and shadow curves, binodals and distribution functions of the coexisting phases) for colloid-polymer mixtures with polymer chain length polydispersity and…

Soft Condensed Matter · Physics 2009-11-13 Y. V. Kalyuzhnyi , P. T. Cummings

It is found experimentally that the coexistence region of a vapor-liquid system or a binary mixture is substantially narrowed when the fluid is confined in a aerogel with a high degree of porosity (e.g. of the order of 95% to 99%). A…

Statistical Mechanics · Physics 2007-05-23 Rafael Salazar , Raul Toral , Amitabha Chakrabarti

We study a stochastic lattice gas of particles undergoing asymmetric diffusion in two dimensions. Transitions between a low-density uniform phase and high-density non-uniform phases characterized by localized or extended structure are…

Condensed Matter · Physics 2009-10-22 Kwan-tai Leung

Two-dimensional nematics possess peculiar properties that have been studied recently using computer simulation and various theoretical models. Here we review our own contribution to the field using density-functional theory, and present…

Soft Condensed Matter · Physics 2013-10-07 Daniel de las Heras , Yuri Martinez-Raton , Luis Mederos , Enrique Velasco