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Related papers: Field theory fo charged fluids and colloids

200 papers

We present a theory that enables us to calculate the effective surface charge of colloidal particles and to efficiently obtain titration curves for different salt concentrations. The theory accounts for the shift of pH of solution due to…

Soft Condensed Matter · Physics 2022-11-01 Amin Bakhshandeh , Derek Frydel , Yan Levin

The structure of dilute electrolyte solutions close to a surface carrying a spatially inhomogeneous surface charge distribution is investigated by means of classical density functional theory (DFT) within the approach of fundamental measure…

Soft Condensed Matter · Physics 2020-06-23 Maximilian Mußotter , Markus Bier , S. Dietrich

The linearized Debye-H\"uckel theory for liquid state is shown to provide thermodynamically consistent virial and energy routes for any potential and for any dimensionality. The importance of this result for bounded potentials is discussed.

Statistical Mechanics · Physics 2009-11-14 Andrés Santos , Riccardo Fantoni , Achille Giacometti

We theoretically study sedimentation-diffusion equilibrium of dilute binary, ternary, and polydisperse mixtures of colloidal particles with different buoyant masses and/or charges. We focus on the low-salt regime, where the entropy of the…

Soft Condensed Matter · Physics 2009-11-11 Jos Zwanikken , rene van Roij

By using the Debye screened potential a generalized version of Newton's Shell Theorem is developed and analytical equations are derived to calculate i) the potential of a charged sphere surrounded by electrolyte, ii) the potential of two…

Soft Condensed Matter · Physics 2020-02-11 István P. Sugár

The effective field theory of the Calogero-Sutherland model represents a universality class of quantum hydrodynamic fluids in one spatial dimension. It describes quantum compressible fluids involving both chiralities in which the chiral…

High Energy Physics - Theory · Physics 2025-01-31 Federico L. Bottesi , Guillermo R. Zemba

In order to utilize the full potential of tailored flows of electromagnetic energy at the nanoscale, we need to understand its general behaviour given by its generic representation of interfering random waves. For applications in on-chip…

Optics · Physics 2020-04-28 M. A. van Gogh , T. Bauer , L. De Angelis , L. Kuipers

There exists a generic relationship between the thermodynamics of a continuous polymer with a generic self-interaction and the two-point function of an interacting field-theory. In addition, the (2N)-point function of the resulting field…

chem-ph · Physics 2008-02-03 Bo Soderberg

Despite decades of intensive studies, the effective interactions between strongly charged colloids still remain elusive. Here we show that a strongly charged surface with a layer of condensed counter- ions behaves effectively as a…

Soft Condensed Matter · Physics 2011-07-12 Xiangjun Xing , Zhenli Xu , Hongru Ma

The primitive model of ionic systems is investigated within a field-theoretic description for the whole range of size-, \lambda, and charge, Z, ratios of the two ionic species. Two order parameters (OP) are identified, and their relations…

Statistical Mechanics · Physics 2009-11-11 A. Ciach , W. T. Gozdz , G. Stell

Electrostatic interactions make a large contribution to solvation free energy in ionic fluids such as electrolytes and colloidal dispersions. The electrostatic contribution to solvation free energy has been ascribed to the self-energy of a…

Statistical Mechanics · Physics 2020-02-19 Hiroshi Frusawa

We present a theory for the equilibrium structure of polyelectrolyte solutions. The main element is a simple, new optimization scheme that allows theories such as the random phase approximation (RPA) to handle the harsh repulsive forces…

Soft Condensed Matter · Physics 2009-11-10 James P. Donley , David R. Heine , David T. Wu

Noncommutative \phi^3 field theory in six dimensions exhibits the logarithmic UV/IR mixing at the two-loop order. We show that open string theory in the presence of constant background NS-NS two-form field yields the same amplitude upon…

High Energy Physics - Theory · Physics 2008-11-26 Youngjai Kiem , Sangmin Lee , Jaemo Park

The driven transport of plastic systems in various disordered backgrounds is studied within mean field theory. Plasticity is modeled using non-convex interparticle potentials that allow for phase slips. This theory most naturally describes…

Disordered Systems and Neural Networks · Physics 2009-11-10 Karl Saunders , J. M. Schwarz , M. Cristina Marchetti , A. Alan Middleton

An effective field theory exists describing a very large class of biophysically interesting Coulomb gas systems: the lowest order (mean-field) version of this theory takes the form of a generalized Poisson-Boltzmann theory. Interaction…

High Energy Physics - Lattice · Physics 2008-11-26 Anthony Duncan

We develop a coarse-graining procedure for two-dimensional models of fluctuating loops by mapping them to interface models. The result is an effective field theory for the scaling limit of loop models, which is found to be a Liouville…

Condensed Matter · Physics 2015-06-25 Jane' Kondev

Whereas the majority of ions in the bulk of a solvent-free ionic liquid is bound into clusters, this is expected to change in the electrical double layer (EDL), in which the resulting electric field 'prefers' to interact with electrical…

Chemical Physics · Physics 2020-04-27 Yufan Zhang , Ting Ye , Ming Chen , Zachary Goodwin , Jun Huang , Guang Feng , Alexei Kornyshev

In a counter-ion only charged fluid, Coulomb coupling is quantified by a single dimensionless parameter. Yet, the theoretical treatment of moderately to strongly coupled charged fluids is a difficult task, central to the understanding of a…

Soft Condensed Matter · Physics 2016-11-03 L. Samaj , A. P. dos Santos , Y. Levin , E. Trizac

Despite the ubiquity of aqueous electrolytes, the effect of salt on water organization remains controversial. We introduce a nonlocal and nonlinear field theory for the nanoscale polarization of ions and water and derive the electrolyte…

We formulate a general mean-field theory of a flat electric double layer in ionic liquids and electrolyte solutions with ions possessing static polarizability and a permanent dipole moment on a charged electrode. We establish a new…

Statistical Mechanics · Physics 2021-08-17 Yu. A. Budkov , S. V. Zavarzin , A. L. Kolesnikov