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The dynamics of a quantum system coupled to a classical environment and subject to constraints that drive it out of equilibrium is described. The evolution of the system is governed by the quantum-classical Liouville equation. Rather than…

Statistical Mechanics · Physics 2025-01-15 Jeremy Schofield , Raymond Kapral

We consider dynamical systems that are described by fractional power of coordinates and momenta. The fractional powers can be considered as a convenient way to describe systems in the fractional dimension space. For the usual space the…

Statistical Mechanics · Physics 2009-11-11 Vasily E. Tarasov

The quantum-classical Liouville equation describes the dynamics of a quantum subsystem coupled to a classical environment. It has been simulated using various methods, notably, surface-hopping schemes. A representation of this equation in…

Other Condensed Matter · Physics 2010-11-17 Hyojoon Kim , Ali Nassimi , Raymond Kapral

The classical Hamilton equations of motion yield a structure sufficiently general to handle an almost arbitrary set of ordinary differential equations. Employing elementary algebraic methods, it is possible within the Hamiltonian structure…

Classical Physics · Physics 2008-07-30 B. Aycock , A. Roe , J. L. Silverberg , A. Widom

By examining both the divergence of the velocity vector in orthogonal Cartesian coordinate space $\mathbf{\Gamma} $ of dimension $\R^{\textrm {2fN}}$ and the structure of the Hamiltonian determining a system trajectory, it is shown that the…

Chaotic Dynamics · Physics 2007-05-23 Christopher G. Jesudason

Physical systems that dissipate, mix and develop turbulence also irreversibly transport statistical density. In statistical physics, laws for these processes have a mathematical form and tractability that depends on whether the description…

Statistical Mechanics · Physics 2022-11-16 Swetamber Das , Jason R. Green

The notion of microscopic state of the system at a given moment of time as a point in the phase space as well as a notion of trajectory is widely used in classical mechanics. However, it does not have an immediate physical meaning, since…

Mathematical Physics · Physics 2013-04-24 A. S. Trushechkin , I. V. Volovich

In this paper we derive the canonical distribution as a stationary solution of the Liouville equation for the classical dissipative system. Dissipative classical systems can have stationary states look like canonical Gibbs distributions.…

Statistical Mechanics · Physics 2009-11-10 Vasily E. Tarasov

In this paper we consider a generalized classical mechanics with fractional derivatives. The generalization is based on the time-clock randomization of momenta and coordinates taken from the conventional phase space. The fractional…

Classical Physics · Physics 2011-11-15 Aleksander Stanislavsky

In this article, it is suggested that a pedagogical point of departure in the teaching of classical mechanics is the Liouville theorem. The theorem is interpreted to define the condition that describe the conservation of information in…

Statistical Mechanics · Physics 2022-07-14 Andreas Henriksson

We propose a highly efficient mixed quantum-classical molecular dynamics scheme based on a solution of the quantum-classical Liouville equation (QCLE). By casting the equations of motion for the quantum subsystem and classical bath degrees…

Chemical Physics · Physics 2018-07-06 Junjie Liu , Gabriel Hanna

We present solutions to the classical Liouville equation for ergodic and completely integrable systems - systems that are known to attain equilibrium. Ergodic systems are known to thermal equilibrate with a Maxwell-Boltzmann distribution…

Statistical Mechanics · Physics 2014-06-26 Jose A. Magpantay , Cilicia Uzziel M. Perez

The classical Lagrange formalism is generalized to the case of arbitrary stationary (but not necessarily conservative) dynamical systems. It is shown that the equations of motion for such systems can be derived in the standard ways from the…

Classical Physics · Physics 2022-12-26 Alex Ushveridze

In this work simple and effective quantization procedure of classical dynamical systems is proposed and illustrated by a number of examples. The procedure is based entirely on differential equations which describe time evolution of systems.

Quantum Physics · Physics 2009-11-26 M. A. Sokolov

In many situations, one can approximate the behavior of a quantum system, i.e. a wave function subject to a partial differential equation, by effective classical equations which are ordinary differential equations. A general method and…

Mathematical Physics · Physics 2007-05-23 Martin Bojowald , Aureliano Skirzewski

The reasons which restrict opportunities of classical mechanics at the description of nonequilibrium systems are discussed. The way of overcoming of the key restrictions is offered. This way is based on an opportunity of representation of…

General Physics · Physics 2012-05-14 V. M. Somsikov

Often quantum systems are not isolated and interactions with their environments must be taken into account. In such open quantum systems these environmental interactions can lead to decoherence and dissipation, which have a marked influence…

Quantum Physics · Physics 2016-11-14 Raymond Kapral

The dynamics of classical and quantum systems which are driven by a high frequency ($\omega$) field is investigated. For classical systems the motion is separated into a slow part and a fast part. The motion for the slow part is computed…

Chaotic Dynamics · Physics 2009-11-10 Saar Rahav , Ido Gilary , Shmuel Fishman

The Liouville equation is of fundamental importance in the derivation of continuum models for physical systems which are approximated by interacting particles. However, when particles undergo instantaneous interactions such as collisions,…

Statistical Mechanics · Physics 2019-10-16 T. D. Hurst , B. D. Goddard , M. Wilkinson

We consider the class of non-Hamiltonian and dissipative statistical systems with distributions that are determined by the Hamiltonian. The distributions are derived analytically as stationary solutions of the Liouville equation for…

Statistical Mechanics · Physics 2009-11-11 Vasily E. Tarasov
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