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A density matrix describes the statistical state of a quantum system. It is a powerful formalism to represent both the quantum and classical uncertainty of quantum systems and to express different statistical operations such as measurement,…

Machine Learning · Computer Science 2024-05-01 Fabio A. González , Alejandro Gallego , Santiago Toledo-Cortés , Vladimir Vargas-Calderón

We present a method to perform fully selfconsistent density-functional calculations, which scales linearly with the system size and which is well suited for very large systems. It uses strictly localized pseudoatomic orbitals as basis…

Condensed Matter · Physics 2009-10-28 Pablo Ordejon , Emilio Artacho , Jose M. Soler

Fourier extension is an approximation method that alleviates the periodicity requirements of Fourier series and avoids the Gibbs phenomenon when approximating functions. We describe a similar extension approach using regular wavelet bases…

Numerical Analysis · Mathematics 2020-04-08 Vincent Coppé , Daan Huybrechs

Methods exhibiting linear scaling with respect to the size of the system, so called O(N) methods, are an essential tool for the calculation of the electronic structure of large systems containing many atoms. They are based on algorithms…

Condensed Matter · Physics 2007-05-23 Stefan Goedecker

A nearly optimal explicitly-sparse representation for oscillatory kernels is presented in this work by developing a curvelet based method. Multilevel curvelet-like functions are constructed as the transform of the original nodal basis. Then…

Numerical Analysis · Mathematics 2025-04-29 Yanchuang Cao , Jun Liu , Dawei Chen

Anisotropic decompositions using representation systems such as curvelets, contourlet, or shearlets have recently attracted significantly increased attention due to the fact that they were shown to provide optimally sparse approximations of…

Functional Analysis · Mathematics 2015-03-17 Gitta Kutyniok

We present a generalization of the Li, Nunes and Vanderbilt density-matrix method to the case of a non-orthogonal set of basis functions. A representation of the real-space density matrix is chosen in such a way that only the overlap…

Condensed Matter · Physics 2009-10-22 R. W. Nunes , David Vanderbilt

We describe recent progress in developing practical ab initio methods for which the computer effort is proportional to the number of atoms: linear scaling or O(N) methods. It is shown that the locality property of the density matrix gives a…

Condensed Matter · Physics 2007-05-23 D. R. Bowler , I. J. Bush , M. J. Gillan

We present a detailed comparison between ONETEP, our linear-scaling density functional method, and the conventional pseudopotential plane wave approach in order to demonstrate its high accuracy. Further comparison with all-electron…

Materials Science · Physics 2009-11-11 Chris-Kriton Skylaris , Peter D. Haynes , Arash A. Mostofi , Mike C. Payne

Diffuse atomic orbital basis sets have proven to be essential to obtain accurate interaction energies, especially in regard to non-covalent interactions. However, they also have a detrimental impact on the sparsity of the one-particle…

Chemical Physics · Physics 2025-05-27 Henryk Laqua , Linus Bjarne Dittmer , Martin Head-Gordon

Using the finite Fourier transform, we introduce a generalization of Pauli-spin matrices for $d$-dimensional spaces, and the resulting set of unitary matrices $S(d) $ is a basis for $d\times d$ matrices. If $N=d_{1}\times…

Quantum Physics · Physics 2009-11-06 Arthur O. Pittenger , Morton H. Rubin

The density matrix formalism which is widely used in the theory of measurements, quantum computing, quantum description of chemical and biological systems always imply the averaging over the states of the environment. In practice this is…

Quantum Physics · Physics 2007-05-23 M. V. Altaisky

A finite dimensional quantum mechanical system is modeled by a density rho, a trace one, positive semi-definite matrix on a suitable tensor product space H[N] . For the system to demonstrate experimentally certain non-classical behavior,…

Quantum Physics · Physics 2007-05-23 Arthur O. Pittenger , Morton H. Rubin

The past thirteen years have seen the development of many algorithms for approximating matrix functions in O(N) time, where N is the basis size. These O(N) algorithms rely on assumptions about the spatial locality of the matrix function;…

Disordered Systems and Neural Networks · Physics 2011-11-09 Vincent E. Sacksteder

We consider the scattering matrices of massive quantum field theories with no bound states and a global $O(N)$ symmetry in two spacetime dimensions. In particular we explore the space of two-to-two S-matrices of particles of mass $m$…

High Energy Physics - Theory · Physics 2020-05-20 Lucía Córdova , Yifei He , Martin Kruczenski , Pedro Vieira

The aperture mass statistic is a common tool used in weak lensing studies. By convolving lensing maps with a filter function of a specific scale, chosen to be larger than the scale on which the noise is dominant, the lensing signal may be…

Cosmology and Nongalactic Astrophysics · Physics 2015-06-04 Adrienne Leonard , Sandrine Pires , Jean-Luc Starck

We analyze the problem of determining the electronic ground state within O(N) schemes, focusing on methods in which the total energy is minimized with respect to the density matrix. We note that in such methods a crucially important…

Condensed Matter · Physics 2007-05-23 D. R. Bowler , M. J. Gillan

The applications of machine learning techniques to chemistry and materials science become more numerous by the day. The main challenge is to devise representations of atomic systems that are at the same time complete and concise, so as to…

Chemical Physics · Physics 2025-10-06 Michael J. Willatt , Felix Musil , Michele Ceriotti

A quantum system's state is identified with a density matrix. Though their probabilistic interpretation is rooted in ensemble theory, density matrices embody a known shortcoming. They do not completely express an ensemble's physical…

Quantum Physics · Physics 2021-06-30 Fabio Anza , James P. Crutchfield

In this article, we introduce the concept of samplets by transferring the construction of Tausch-White wavelets to the realm of data. This way we obtain a multilevel representation of discrete data which directly enables data compression,…

Numerical Analysis · Mathematics 2021-11-17 Helmut Harbrecht , Michael Multerer
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