Related papers: Spinodal-assisted crystallization in polymer melts
Using Kinetic Monte Carlo simulation, we model gas-liquid spinodal decomposition in a size-polydisperse square well fluid, representing a 'near-monodisperse' colloidal dispersion. We find that fractionation (demixing) of particle sizes…
We study a chemically active binary mixture undergoing phase separation and show that under non-equilibrium conditions, stable liquid spherical shells can form via a spinodal instability in the droplet center. A single liquid shell tends to…
The phase behavior of binary fluid mixtures of hard hyperspheres in four and five dimensions is investigated. Spinodal instability is found by using a recent and accurate prescription for the equation of state of the mixture that requires…
Strained amorphous solids often fail mechanically by creating a shear-band. It had been understood that the shear banding instability is usefully described as crossing a spinodal point (with disorder) in an appropriate thermodynamic…
We develop a series of molecular dynamics computer simulations of liquid water, performed with a polarizable potential model, to calculate the spinodal line and the curve of maximum density inside the metastable supercooled region. After…
A general Landau's free energy functional is used to study the dynamics of crystallization during liquid-solid Spinodal Decomposition (SD). The strong length scale selectivity imposed during the early stage of SD induces the appearance of…
A hexagonal columnar crystal undergoes a shear-melting transition above a critical shear rate or stress. We combine the analysis of the shear-thinning regime below the melting with that of synchrotron X-ray scattering data under shear and…
The phase diagram of nuclear matter is quite rich - it shows such phenomena as phase-transitions, formation of condensates, clustering, etc. From the analysis of the spinodal instability, one can learn about the region of liquid-gas…
The correlations between the segments of a semidilute polymer solution are found to induce correlations in the positions of small particles added to the solution. Small means a diameter much less than the polymer's correlation length. In…
Active systems of self-rotating elements inherently exhibit chirality, making them of fundamental interest due to parity violation. Using large-scale hydrodynamic simulations, we investigate the gelation of adhesive spinners confined to…
In many technical applications, but also in natural processes like ice nucleation in clouds, crystallization proceeds in the presence of stresses and flows, hence the importance to understand the crystallization mechanism in simple…
The addition of enough non-adsorbing polymer to an otherwise stable colloidal suspension gives rise to a variety of phase behavior and kinetic arrest due to the depletion attraction induced between the colloids by the polymers. We report a…
We investigate how the dynamics of a single chain influences the kinetics of early stage phase separation in a symmetric binary polymer mixture. We consider quenches from the disordered phase into the region of spinodal instability. On a…
The hydrodynamic stresses created by active particles can destabilise orientational order present in the system. This is manifested, for example, by the appearance of a bend instability in active nematics or in quasi-2-dimensional living…
We study numerically the crystallization of a hard-sphere mixture with 8\% polydispersity. Although often used as a model glass former, for small system sizes we observe crystallization in molecular dynamics simulations. This opens the…
We consider the phase separation of binary fluids in contact with a surface which is preferentially wetted by one of the components of the mixture. We review the results available for this problem and present new numerical results obtained…
We study phase separation and transient gelation in a mixture consisting of polydisperse colloids and non-adsorbing polymers, where the ratio of the average size of the polymer to that of the colloid is approximately 0.063. Unlike what has…
The stability of organic solar cells is strongly affected by the morphology of the photoactive layers, whose separated crystalline and/or amorphous phases are kinetically quenched far from their thermodynamic equilibrium during the…
Recently achieved chiral condensates open intriguing avenues for the study of the chiral properties induced by current-density interactions. An attempt to include these features in a spinor system is presented, which gives rise to a…
We model a melt of monodisperse side-chain liquid crystalline polymers as a melt of comb copolymers in which the side groups are rod-coil diblock copolymers. We consider both excluded volume and Maier-Saupe interactions. The first acts…