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Theoretical design of global optimization algorithms can profitably utilize recent statistical mechanical treatments of potential energy surfaces (PES's). Here we analyze a particular method to explain its success in locating global minima…

Statistical Mechanics · Physics 2008-02-03 Jonathan Doye , David Wales

We describe a global optimization technique using `basin-hopping' in which the potential energy surface is transformed into a collection of interpenetrating staircases. This method has been designed to exploit the features which recent work…

Condensed Matter · Physics 2007-05-23 David Wales , Jonathan Doye

We present an adaptive and parallel implementation of the Basin Hopping (BH) algorithm for the global optimization of atomic clusters interacting via the Lennard-Jones (LJ) potential. The method integrates local energy minimization with…

Global optimization is an active area of research in atomistic simulations, and many algorithms have been proposed to date. A prominent example is basin hopping Monte Carlo, which performs a modified Metropolis Monte Carlo search to explore…

Chemical Physics · Physics 2020-02-04 Martín Leandro Paleico , Jörg Behler

Recently, Locatelli and Schoen proposed a transformation of the potential energy that aids the global optimization of Lennard-Jones clusters with non-icosahedral global minima. These cases are particularly difficult to optimize because the…

Condensed Matter · Physics 2007-05-23 Jonathan Doye

Basin-Hopping (BH) or Monte-Carlo Minimization (MCM) is so far the most reliable algorithms in chemical physics to search for the lowest-energy structure of atomic clusters and macromolecular systems. BH transforms the complex energy…

Materials Science · Physics 2009-11-10 Masao Iwamatsu , Yutaka Okabe

A new atomic cluster structure corresponding to the global minimum of the 98-atom Lennard-Jones cluster has been found using a variant of the basin-hopping global optimization algorithm. The new structure has an unusual tetrahedral symmetry…

Condensed Matter · Physics 2007-05-23 Robert Leary , Jonathan Doye

A method is presented that can find the global minimum of very complex condensed matter systems. It is based on the simple principle of exploring the configurational space as fast as possible and of avoiding revisiting known parts of this…

Materials Science · Physics 2007-05-23 Stefan Goedecker

Associative memory Hamiltonian structure prediction potentials are not overly rugged, thereby suggesting their landscapes are like those of actual proteins. In the present contribution we show how basin-hopping global optimization can…

Biomolecules · Quantitative Biology 2009-11-13 Michael C. Prentiss , David J. Wales , Peter G. Wolynes

We present a novel method, which we call dual minima hopping method (DMHM), that allows us to find the global minimum of the potential energy surface (PES) within density functional theory for systems where a fast but less accurate…

Other Condensed Matter · Physics 2009-11-11 Stefan Goedecker , Waldemar Hellmann , Thomas Lenosky

Locating the global minimum of a complex potential energy surface is facilitated by considering a homotopy, namely a family of surfaces that interpolate continuously from an arbitrary initial potential to the system under consideration.…

Computational Physics · Physics 2009-11-07 J. S. Hunjan , S. Sarkar , R. Ramaswamy

We show that molecular dynamics based moves in the Minima Hopping (MH) method are more efficient than saddle point crossing moves which select the lowest possible saddle point. For binary systems we incorporate identity exchange moves in a…

Statistical Mechanics · Physics 2015-05-19 Michael Sicher , Stephan Mohr , Stefan Goedecker

We created a computational workflow to analyze the potential energy surface (PES) of materials using machine-learned interatomic potentials in conjunction with the minima hopping algorithm. We demonstrate this method by producing a…

Materials Science · Physics 2025-02-14 Hossein Tahmasbi , Kushal Ramakrishna , Mani Lokamani , Attila Cangi

We investigate a novel stochastic technique for the global optimization of complex potential energy surfaces (PES) that avoids the freezing problem of simulated annealing by allowing the dynamical process to tunnel energetically…

Computational Physics · Physics 2009-10-31 W. Wenzel , K. Hamacher

We review recent results on the potential energy landscape (PES) of model liquids. The role of saddle-points in the PES in connecting dynamics to statics is investigated, confirming that a change between minima-dominated and…

Soft Condensed Matter · Physics 2012-11-26 Antonio Scala , Luca Angelani , Roberto Di Leonardo , Giancarlo Ruocco , Francesco Sciortino

We report our studies of the potential energy surface (PES) of selected binary Lennard-Jones clusters. The effect of adding selected impurity atoms to a homogeneous cluster is explored. Inherent structures and transition states are found by…

Materials Science · Physics 2009-11-10 Dubravko Sabo , J. D. Doll , David L. Freeman

It is analyzed whether the potential energy landscape of a glass-forming system can be effectively mapped on a random model which is described in statistical terms. For this purpose we generalize the simple trap model of Bouchaud and…

Disordered Systems and Neural Networks · Physics 2009-11-11 A. Heuer , B. Doliwa , A. Saksaengwijit

We develop an efficient numerical algorithm for the identification of a large number of saddle points of the potential energy function of Lennard- Jones clusters. Knowledge of the saddle points allows us to find many thousand adjacent…

Condensed Matter · Physics 2009-10-31 G. Daldoss , O. Pilla , G. Viliani , G. Ruocco

Global optimization is a challenging problem, with plenty of algorithms displaying empirical success, but scarce theoretical backing. In this work, we propose a new theoretical framework called Proximal Basin Hopping (PBH), carefully…

Machine Learning · Computer Science 2026-05-19 Guillaume Lauga , Cesare Molinari , Samuel Vaiter

We study the relation of the potential energy landscape (PEL) topography to relaxation dynamics of a small model glass former of Lennard-Jones type. The mechanism under investigation is the hopping betweem superstructures of PEL mimima,…

Disordered Systems and Neural Networks · Physics 2009-11-07 Burkhard Doliwa , Andreas Heuer
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