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The computation of excited electronic states is an important application for quantum computers. In this work, we simulate the excited state spectra of four aromatic heterocycles on IBM superconducting quantum computers, focusing on active…

Quantum Physics · Physics 2023-09-19 Maria A. Castellanos , Mario Motta , Julia E. Rice

The excited states of polyatomic systems are rather complex, and often exhibit meta-stable dynamical behaviors. Static analysis of reaction pathway often fails to sufficiently characterize excited state motions due to their highly…

Chemical Physics · Physics 2017-08-22 Fang Liu , Likai Du , Dongju Zhang , Jun Gao

We simulate the excited states of the Lipkin model using the recently proposed Quantum Equation of Motion (qEOM) method. The qEOM generalizes the EOM on classical computers and gives access to collective excitations based on quasi-boson…

Calculations of highly excited and delocalized molecular vibrational states are computationally challenging tasks, which strongly depends on the choice of coordinates for describing vibrational motions. We introduce a new method that…

State mapping between atoms and photons, and photon-photon interactions play an important role in scalable quantum information processing. We consider the interaction of a two-level atom with a quantized \textit{propagating} pulse in free…

Quantum Physics · Physics 2013-05-29 Yimin Wang , Jiří Minář , Lana Sheridan , Valerio Scarani

The amplitude and probability of quantum transitions are represented as a path integrals in energy state space of the investigated multi-level quantum system. Using this approach we consider rotational dynamics of nitrogen molecules…

Quantum Physics · Physics 2014-07-16 Alexander Biryukov , Mark Shleenkov

Variational optimization of orbitals in time-independent density functional calculations of excited electronic states presents a significant challenge, as excited states typically correspond to saddle points on the electronic energy…

Chemical Physics · Physics 2026-04-02 Yorick L. A. Schmerwitz , Elli Selenius , Gianluca Levi

We propose a new particle acceleration mechanism. Electron can be accelerated to relativistic energy within a few electromagnetic wave cycles through the mechanism which is named electromagnetic and magnetic field resonance acceleration…

Plasma Physics · Physics 2007-05-23 Hong Liu , X. T. He , S. G. Chen , W. Y. Zhang

The future applications of the short-duration, multi-MeV ion beams produced in the interaction of high-intensity laser pulses with solid targets will require improvements in the conversion efficiency, peak ion energy, beam monochromaticity,…

Plasma Physics · Physics 2009-11-13 Tatiana Liseykina , Marco Borghesi , Andrea Macchi , Sara Tuveri

The asymmetrically mounted flat plasma actuator is studied using a self-consistent 2-DIM fluid model at atmospheric pressure. The computational model use the drift-diffusion approximation and a simple plasma phenomenological kinetic model.…

Plasma Physics · Physics 2019-05-10 Mario J. Pinheiro , Alexandre A. Martins

A systematic method for determining correlated wavefunctions of extended systems in the ground and excited states is presented. It allows to fully exploit the power of quantum-chemical programs designed for correlation calculations of…

Other Condensed Matter · Physics 2007-05-23 V. Bezugly

Variational analysis techniques in lattice QCD are powerful tools that give access to the excited state spectrum of QCD. At zero momentum, these techniques are well established and can cleanly isolate energy eigenstates of either positive…

High Energy Physics - Lattice · Physics 2017-01-26 Finn M. Stokes , Waseem Kamleh , Derek B. Leinweber , Benjamin J. Owen

For a description of large-amplitude collective motion associated with nuclear pairing, requantization of time-dependent mean-field dynamics is performed using the stationary-phase approximation (SPA) to the path integral. We overcome the…

Nuclear Theory · Physics 2019-01-02 Fang Ni , Nobuo Hinohara , Takashi Nakatsukasa

We present an optimized random phase approximation method (optRPA26) that significantly improves upon conventional RPA. The method employs an empirically constructed hybrid functional to generate DFT orbitals to evaluate the RPA correlation…

Chemical Physics · Physics 2026-02-06 Neung-Kyung Yu , Johannes Voss , Andrew J. Medford

This paper explores the utility of the quantum phase estimation (QPE) in calculating high-energy excited states characterized by promotions of electrons occupying inner energy shells. These states have been intensively studied over the last…

The determination of thermal and vibrational relaxation rates of triatomic systems suitable for application in hypersonic model calculations is discussed. For this, potential energy surfaces for ground and electronically excited state…

Chemical Physics · Physics 2020-11-06 Debasish Koner , Raymond J. Bemish , Markus Meuwly

A new approach to simulating warm and hot dense matter that combines density functional theory based calculations of the electronic structure to classical molecular dynamics simulations with pair interaction potentials is presented. The new…

Plasma Physics · Physics 2015-06-22 C. E. Starrett , J. Daligault , D. Saumon

We use the random phase approximation (RPA) method with the singles correlation energy contributions to calculate lattice energies of ten molecular solids. While RPA gives too weak binding, underestimating the reference data by $13.7$\% on…

Chemical Physics · Physics 2016-09-21 Jiří Klimeš

In this paper, we propose a cost-reduced method for finite-temperature molecular dynamics on a near-term quantum computer, Quantum Car-Parrinello molecular dynamics (QCPMD). One of the most promising applications of near-term quantum…

Quantum Physics · Physics 2022-12-23 Kohdai Kuroiwa , Takahiro Ohkuma , Hirokazu Sato , Ryosuke Imai

Recently proposed non-adiabatic ring polymer molecular dynamics (NRPMD) approach has shown to provide accurate quantum dynamics by incorporating explicit electronic state descriptions and nuclear quantizations. Here, we present a rigorous…

Chemical Physics · Physics 2019-07-24 Sutirtha N. Chowdhury , Pengfei Huo