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We explore the non-Hermitian extension of quantum chemistry in the complex plane and its link with perturbation theory. We observe that the physics of a quantum system is intimately connected to the position of complex-valued energy…

Chemical Physics · Physics 2021-06-14 Antoine Marie , Hugh G. A. Burton , Pierre-François Loos

A new formalism is introduced to treat problems in quantum field theory, using coherent functional expansions rather than path integrals. The basic results and identities of this approach are developed. In the case of a Bose gas with…

Quantum Physics · Physics 2017-10-25 P. D. Drummond

Recently developed strong-coupling theory open up the possibility of treating quantum-mechanical systems with hard-wall potentials via perturbation theory. To test the power of this theory we study here the exactly solvable quantum…

Condensed Matter · Physics 2009-10-31 H. Kleinert , A. Chervyakov , B. Hamprecht

A wide class of boundary problems in quantum mechanics is discussed by using path integrals. This includes motion in half-spaces, radial boxes, rings, and moving boundaries. As a preparation the formalism for the incorporation of…

High Energy Physics - Theory · Physics 2016-09-06 Christian Grosche

In a previous paper (J. Phys. A 36, 11807 (2003)), we introduced the `asymptotic iteration method' for solving second-order homogeneous linear differential equations. In this paper, we study perturbed problems in quantum mechanics and we…

Mathematical Physics · Physics 2009-11-11 Hakan Ciftci , Richard L. Hall , Nasser Saad

We present a new perturbation theory for quantum mechanical energy eigenstates when the potential equals the sum of two localized, but not necessarily weak potentials $V_{1}(\vec{r})$ and $V_{2}(\vec{r})$, with the distance $L$ between the…

Quantum Physics · Physics 2007-05-23 Seok Kim , Choonkyu Lee

We study quantum mechanical systems with a discrete spectrum. We show that the asymptotic series associated to certain paths of steepest-descent (Lefschetz thimbles) are Borel resummable to the full result. Using a geometrical approach…

High Energy Physics - Theory · Physics 2018-02-01 Marco Serone , Gabriele Spada , Giovanni Villadoro

We develop a perturbation theory of quantum (and classical) master equations with slowly varying parameters, applicable to systems which are externally controlled on a time scale much longer than their characteristic relaxation time. We…

Quantum Physics · Physics 2017-08-09 Vasco Cavina , Andrea Mari , Vittorio Giovannetti

We report lowest-order series expansions for primary matrix functions of quantum states based on a perturbation theory for functions of linear operators. Our theory enables efficient computation of functions of perturbed quantum states that…

Quantum Physics · Physics 2023-03-24 Michael R Grace , Saikat Guha

Perturbation theory in quantum mechanics studies how quantum systems interact with their environmental perturbations. Harmonic perturbation is a rare special case of time-dependent perturbations in which exact analysis exists. Some…

Quantum Physics · Physics 2008-01-01 Jie-Hong R. Jiang , Dah-Wei Chiou , Cheng-En Wu

A modification of the spiked harmonic oscillator is studied in the case for which the perturbation potential contains both an inverse power and a linear term. It is then possible to evaluate trial functions by solving an integral equation…

Quantum Physics · Physics 2007-05-23 Giampiero Esposito

The double-well potential is a good example, where we can compute the splitting in the bound state energy of the system due to the tunneling effect with various methods, namely WKB or instanton calculations. All these methods are…

Quantum Physics · Physics 2019-07-18 Fatih Erman , O. Teoman Turgut

The explicit semiclassical treatment of the logarithmic perturbation theory for the bound-state problem for the spherical anharmonic oscillator and the screened Coulomb potential is developed. Based upon the $\hbar$-expansions and suitable…

Mathematical Physics · Physics 2007-12-13 I. V. Dobrovolska , R. S. Tutik

Using the basic ingredient of supersymmetry, we develop a simple alternative approach to perturbation theory in one-dimensional non-relativistic quantum mechanics. The formulae for the energy shifts and wave functions do not involve tedious…

Quantum Physics · Physics 2009-11-10 Bulent Gonul

Quantum mechanics of unitary systems is considered in quasi-Hermitian representation. In this framework the concept of perturbation is found counterintuitive, for three reasons. The first one is that in this formalism we are allowed to…

Quantum Physics · Physics 2024-05-21 Miloslav Znojil

It is shown that for the one-dimensional anharmonic oscillator with potential $V(x)= a x^2 + b g x^3 +\ldots=\frac{1}{g^2}\,\hat{V}(gx)$, as well as for the radial oscillator $V(r)=\frac{1}{g^2}\,\hat{V}(gr)$ and for the perturbed Coulomb…

Quantum Physics · Physics 2024-02-08 A. V. Turbiner , E. Shuryak

Perturbation theory (PT) might be one of the most powerful and fruitful tools for both physicists and chemists, which evoked an explosion of applications with the blooming of atomic and subatomic physics. Even though PT is well-used today,…

Quantum Physics · Physics 2023-05-16 Junxu Li , Barbara A. Jones , Sabre Kais

It is well known that quantum-mechanical perturbation theory often give rise to divergent series that require proper resummation. Here I discuss simple ways in which these divergences can be avoided in the first place. Using the elementary…

Quantum Physics · Physics 2022-12-19 Matteo Smerlak

We study properties of eigenfunctions of perturbed systems, given on the eigenbases of unperturbed, integrable systems. For a given pair of perturbed and unperturbed systems, with respect to the energy of each perturbed state, the…

Quantum Physics · Physics 2019-09-04 Jiaozi Wang , Wen-ge Wang

Standard derivations of ``time-independent perturbation theory'' of quantum mechanics cannot be applied to the general case where potentials are energy dependent or where the inverse free Green function is a non-linear function of energy.…

High Energy Physics - Theory · Physics 2007-05-23 A. N. Kvinikhidze , B. Blankleider
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