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The low temperature thermodynamics of correlated 1D fermionic models with spin and charge degrees of freedom is obtained by exact diagonalization (ED) of small systems and followed by density matrix renormalization group (DMRG) calculations…

Strongly Correlated Electrons · Physics 2022-03-11 Sudip Kumar Saha , Debasmita Maiti , Manoranjan Kumar , Zoltán G. Soos

During the past 15 years, the density matrix renormalization group (DMRG) has become increasingly important for ab initio quantum chemistry. Its underlying wavefunction ansatz, the matrix product state (MPS), is a low-rank decomposition of…

Chemical Physics · Physics 2014-09-25 Sebastian Wouters , Dimitri Van Neck

We have devised and implemented a local ab initio Density Matrix Renormalization Group (DMRG) algorithm to describe multireference nondynamic correlations in large systems. For long molecules that are extended in one of their spatial…

Strongly Correlated Electrons · Physics 2009-11-11 Johannes Hachmann , Wim Cardoen , Garnet Kin-Lic Chan

The performance of the density matrix renormalization group (DMRG) is strongly influenced by the choice of the local basis of the underlying physical lattice. We demonstrate that, for the two-dimensional Hubbard model, the hybrid…

Strongly Correlated Electrons · Physics 2017-03-22 G. Ehlers , S. R. White , R. M. Noack

We extend the spin-adapted density matrix renormalization group (DMRG) algorithm of McCulloch and Gulacsi [Europhys. Lett.57, 852 (2002)] to quantum chemical Hamiltonians. This involves two key modifications to the non-spin-adapted DMRG…

Chemical Physics · Physics 2014-08-22 Sandeep Sharma , Garnet Kin-Lic Chan

We study one dimensional models of diatomic molecules where both the electrons and nuclei are treated as quantum particles, going beyond the usual Born-Oppenheimer approximation. The continuous system is approximated by a grid which…

Strongly Correlated Electrons · Physics 2020-10-02 Mingru Yang , Steven R. White

We introduce a Lagrangian formulation of the Density Matrix Renormalization Group (DMRG). We present Lagrangians which when minimised yield the optimal DMRG wavefunction in a variational sense, both within the general matrix product ansatz,…

Strongly Correlated Electrons · Physics 2008-04-11 Garnet Kin-Lic Chan

Based on the original idea of the density matrix renormalization group (DMRG), i.e. to include the missing boundary conditions between adjacent blocks of the blocked quantum system, we present a rigorous and nonperturbative mathematical…

Statistical Mechanics · Physics 2009-10-31 Andreas Degenhard

We review the variational principle in the density matrix renormalization group (DMRG) method, which maximizes an approximate partition function within a restricted degrees of freedom; at zero temperature, DMRG mini- mizes the ground state…

Statistical Mechanics · Physics 2009-10-28 T. Nishino , K. Okunishi

In these lecture notes, we present a pedagogical review of a number of related {\it numerically exact} approaches to quantum many-body problems. In particular, we focus on methods based on the exact diagonalization of the Hamiltonian matrix…

Strongly Correlated Electrons · Physics 2007-05-23 Reinhard M. Noack , Salvatore R. Manmana

The emerging field of polaritonic chemistry explores the behavior of molecules under strong coupling with cavity modes. Despite recent developments in ab initio polaritonic methods for simulating polaritonic chemistry under electronic…

Chemical Physics · Physics 2024-07-02 Mikuláš Matoušek , Nam Vu , Niranjan Govind , Jonathan J. Foley , Libor Veis

Obtaining accurate representations of the eigenstates of an array of coupled superconducting qubits is a crucial step in the design of circuit quantum electrodynamics (QED)-based quantum processors. However, exact diagonalization of the…

Understanding the influence of vibrational degrees of freedom on transport through a heterostructure poses considerable theoretical and numerical challenges. In this work, we use the density-matrix renormalization group (DMRG) method…

Strongly Correlated Electrons · Physics 2021-11-17 David Jansen , Christian Jooss , Fabian Heidrich-Meisner

We use the density matrix renormalization group (DMRG) to map out the ground state of a XY-spin chain coupled to dispersionless phonons of frequency $% \omega $. We confirm the existence of a critical spin-phonon coupling $% \alpha…

Condensed Matter · Physics 2009-10-28 L. G. Caron , S. Moukouri

We introduce the Nuclear Electronic All-Particle Density Matrix Renormalization Group (NEAP-DMRG) method for solving the time-independent Schr\"odinger equation simultaneously for electrons and other quantum species. In contrast to already…

Chemical Physics · Physics 2020-05-29 Andrea Muolo , Alberto Baiardi , Robin Feldmann , Markus Reiher

Linear response theory for the density matrix renormalization group (DMRG-LRT) was first presented in terms of the DMRG renormalization projectors [Dorando et al., J. Chem. Phys. 130, 184111 (2009)]. Later, with an understanding of the…

Strongly Correlated Electrons · Physics 2014-02-25 Naoki Nakatani , Sebastian Wouters , Dimitri Van Neck , Garnet Kin-Lic Chan

We use the density matrix renormalization group (DMRG) method to study the ground and low-lying excited states of three kinds of uniform and dimerized alternating spin chains. The DMRG procedure is also employed to obtain low-temperature…

Strongly Correlated Electrons · Physics 2009-10-30 Swapan K. Pati , S. Ramasesha , Diptiman Sen

We introduce a block Lanczos (BL) recursive technique to construct quasi-one-dimensional models, suitable for density-matrix renormalization group (DMRG) calculations, from single- as well as multiple-impurity Anderson models in any spatial…

Strongly Correlated Electrons · Physics 2014-11-24 Tomonori Shirakawa , Seiji Yunoki

I present a density-matrix renormalization-group (DMRG) method for calculating dynamical properties and excited states in low-dimensional lattice quantum many-body systems. The method is based on an exact variational principle for dynamical…

Strongly Correlated Electrons · Physics 2009-11-07 Eric Jeckelmann

We present a construction of a matrix product state (MPS) that approximates the largest-eigenvalue eigenvector of a transfer matrix T, for the purpose of rapidly performing the infinite system density matrix renormalization group (DMRG)…

Statistical Mechanics · Physics 2010-05-20 Kouji Ueda , Tomotoshi Nishino , Kouichi Okunishi , Yasuhiro Hieida , Rene Derian , Andrej Gendiar
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