Related papers: Behavior of a polymer chain in a critical binary s…
Within self-consistent field theory we study the phase behaviour of a symmetric binary AB polymer blend confined into a thin film. The film surfaces interact with the monomers via short range potentials. One surface attracts the A component…
My means of extensive Monte Carlo simulations the mean radius of gyration and the end-to-end distance are calculated for a single chain in a solvent over a broad range of volume fractions, pressures and temperatures. Our results indicate…
We solve numerically a kinetic model of chiral polymerization in systems closed to matter and energy flow, paying special emphasis to its ability to amplify the small initial enantiomeric excesses due to the internal and unavoidable…
We study the effect of a random Flory-Huggins parameter in a symmetric diblock copolymer melt which is expected to occur in a copolymer where one block is near its structural glass transition. In the clean limit the microphase segregation…
We analyse scaling laws that govern macromolecules of different topology: polymer chains, homogeneous and miktoarm star polymers in a good solvent possibly constrained by a porous medium. The latter is modelled by long-range-correlated…
Two different models exhibiting self-organized criticality are analyzed by means of the dynamic renormalization group. Although the two models differ by their behavior under a parity transformation of the order parameter, it is shown that…
In this paper we study the shape characteristics of a polymer chain in a good solvent using a mesoscopic level of modelling. The dissipative particle dynamics simulations are performed in the $3D$ space at a range of chain lengths $N$. The…
Several methods for preparing well equilibrated melts of long chains polymers are studied. We show that the standard method in which one starts with an ensemble of chains with the correct end-to-end distance arranged randomly in the…
We study the effect of dielectric anisotropy of polymers on their equilibrium ordering within mean-field theory but with a formalism that takes into account the full n-body nature of van der Waals forces. Dielectric anisotropy within…
Monte Carlo simulations and finite-size scaling analysis have been carried out to study the critical behavior in a two-dimensional system of particles with two bonding sites that, by decreasing temperature or increasing density, polymerize…
A formula is derived for stiffness of a polymer chain in terms of the distribution function of end-to-end vectors. This relationship is applied to calculate the stiffness of Gaussian chains (neutral and carrying electric charges at the…
We investigate the wrapping conformations of a strongly adsorbed polymer chain on an oppositely charged nano-sphere by employing a reduced (dimensionless) representation of a primitive chain-sphere model. This enables us to determine the…
We study the polymer system consisting of two polymer chains situated in a fractal container that belongs to the three--dimensional Sierpinski Gasket (3D SG) family of fractals. Each 3D SG fractal has four fractal impenetrable 2D surfaces,…
The spin 1/2 XXZ chain in a random magnetic field pointing in the Z direction is numerically studied using the Density Matrix Renormalization Group (DMRG) method. The phase diagram as a function of the anisotropy of the XXZ Hamiltonian and…
Effective critical exponents for the \lambda \phi^4 scalar field theory are calculated as a function of the renormalization group block size k_o^{-1} and inverse critical temperature \beta_c. Exact renormalization group equations are…
Critical behaviour of a nearly critical system, subjected to vivid turbulent mixing, is studied by means of the field theoretic renormalization group. Namely, relaxational stochastic dynamics of a non-conserved order parameter of the…
The possibility to induce demixing in a colloidal mixture by adding small polymers, or other equivalent depletant agents, is theoretically investigated. By use of Mean Field Theory, suitably generalized to deal with short range effective…
We introduce a Renormalization scheme for the one and two dimensional Forest-Fire models in order to characterize the nature of the critical state and its scale invariant dynamics. We show the existence of a relevant scaling field…
Different perturbation theory treatments of the Ginzburg-Landau phase transition model are discussed. This includes a criticism of the perturbative renormalization group (RG) approach and a proposal of a novel method providing critical…
Critical fluctuations in fluids and fluid mixtures yield a nonanalytic asymptotic Ising-like critical thermodynamic behavior in terms of power laws with universal exponents. In polymer solutions, the amplitudes of these power laws depend on…