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Based on our derivation of finite temperature reduced density matrix functional theory and the discussion of the performance of its first-order functional this work presents several different correlation-energy functionals and applies them…

Other Condensed Matter · Physics 2012-08-24 Tim Baldsiefen , E. K. U. Gross

A method is presented for calculating electron-hole pair excitation due to an incident atom or molecule interacting with a metal surface. Energy loss is described using an \textit{ab initio} approach that obtains a position-dependent…

Materials Science · Physics 2009-10-01 J. R. Trail , M. C. Graham , D. M. Bird , M. Persson , S. Holloway

Electron distributions produced by grazing impact of fast protons on Mg(0001), Cu(111), Ag(111) and Au(111) surfaces are investigated, focusing on the effects of the electronic band structure. The process is described within the…

Atomic Physics · Physics 2015-06-18 C. D. Archubi , M. Faraggi , V. M. Silkin , M. S. Gravielle

We consider electronic exchange and correlation effects in density-functional calculations of two-dimensional systems. Starting from wave function calculations of total energies and electron densities of inhomogeneous model systems, we…

Mesoscale and Nanoscale Physics · Physics 2012-05-30 Ilja Makkonen , Mikko M. Ervasti , Ville Kauppila , Ari Harju

Many methods for computing electronic correlation effects at finite temperature are related to many-body perturbation theory in the grand-canonical ensemble. In most applications, however, the average number of electrons is known rather…

Materials Science · Physics 2022-10-21 Felix Hummel

The ultimate goal of electronic structure calculations is to make the left and right hand sides of the titled ``equation'' as close as possible. This requires high-precision treatment of relativistic, correlation, and quantum…

Chemical Physics · Physics 2022-10-10 Wenjian Liu

We review studies of the electromagnetic response of various classes of correlated electron materials including transition metal oxides, organic and molecular conductors, intermetallic compounds with $d$- and $f$-electrons as well as…

Strongly Correlated Electrons · Physics 2011-06-14 Dimitri N. Basov , Richard D. Averitt , Dirk van der Marel , Martin Dressel , Kristjan Haule

The dynamics of electrons in the presence of a positive ion is considered for conditions of weak electron-electron couping but strong electron-ion coupling. The equilibrium electron density and electric field time correlation functions are…

Statistical Mechanics · Physics 2007-05-23 James W. Dufty , Ilya V. Pogorelov , Bernard Talin , Annette Calisti

Multi-configurational approaches yield universal wave function parameterizations that can qualitatively well describe electronic structures along reaction pathways. For quantitative results, multi-reference perturbation theory is required…

Chemical Physics · Physics 2016-09-08 Christopher J. Stein , Vera von Burg , Markus Reiher

The electronic band structure of bulk ferromagnetic iron is explored by angle-resolved photoemission for electron correlation effects. Fermi surface cross-sections as well as band maps are contrasted with density functional calculations.…

Strongly Correlated Electrons · Physics 2015-06-24 J. Schaefer , M. Hoinkis , Eli Rotenberg , P. Blaha , R. Claessen

Hidden singularities in correlated electron systems, which are caused by pair fluctuations of electron-electron or electron-hole bubbles obeying Bose-Einstein statistics, are clarified theoretically. The correlation function of each pair…

Superconductivity · Physics 2024-11-12 Takafumi Kita

The decay properties of the one-particle Green function in real space and imaginary time are systematically studied for solids. I present an analytic solution for the homogeneous electron gas at finite and at zero temperature as well as…

Materials Science · Physics 2007-05-23 Arno Schindlmayr

Single-particle excitation spectra of gamma-Fe in the paramagnetic state have been investigated by means of the first-principles dynamical coherent potential approximation theory which has recently been developed. It is found that the…

Strongly Correlated Electrons · Physics 2015-05-14 Y. Kakehashi , M. Atiqur R. Patoary , T. Tamashiro

The dynamic response of an interacting electron system is determined by an extension of the relaxation-time approximation forced to obey local conservation laws for number, momentum and energy. A consequence of these imposed constraints is…

Strongly Correlated Electrons · Physics 2009-11-07 G. S. Atwal , N. W. Ashcroft

We utilized a simple, robust, first principle method, based on basis set optimization with the BZW-EF method, to study the electronic and related properties of transition metal mono-nitrides: ScN and YN. We solved the KS system of equations…

Materials Science · Physics 2012-09-04 C. E. Ekuma , D. Bagayoko , M. Jarrell , J. Moreno

The electronic excitation spectrum of a material characterises the response to external electromagnetic perturbations through its energy loss function (ELF), which is obtained from several experimental sources that usually do not completely…

Materials Science · Physics 2024-12-20 Fan Cheng , Pablo de Vera , Rafael Garcia-Molina

The random phase approximation (RPA) for the electron correlation energy, combined with the exact-exchange energy, represents the state-of-the-art exchange-correlation functional within density-functional theory (DFT). However, the standard…

Other Condensed Matter · Physics 2015-05-20 Xinguo Ren , Patrick Rinke , Alexandre Tkatchenko , Matthias Scheffler

The electronic friction-Langevin dynamics (EF-LD) offers a simplified framework for describing nonadiabatic effects at metal surfaces, particularly in electrochemical and molecular electronic applications. We investigate the electronic…

Strongly Correlated Electrons · Physics 2025-09-03 Yunhao Liu , Wenjie Dou

Quantitative simulation of electronic structure of solids requires treating local and non-local electron correlations on an equal footing. We present a new ab initio formulation of Green's function embedding which, unlike dynamical…

Materials Science · Physics 2024-10-01 Jiachen Li , Tianyu Zhu

Perturbation theory using self-consistent Green's functions is one of the most widely used approaches to study many-body effects in condensed matter. On the basis of general considerations and by performing analytical calculations for the…

Strongly Correlated Electrons · Physics 2017-07-26 Walter Tarantino , Pina Romaniello , J. A. Berger , Lucia Reining