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Colloidal particles or nanoparticles, with equal affinity for two fluids, are known to adsorb irreversibly to the fluid-fluid interface. We present large-scale computer simulations of the demixing of a binary solvent containing such…

Soft Condensed Matter · Physics 2007-05-23 K. Stratford , R. Adhikari , I. Pagonabarraga , J. -C. Desplat , M. E. Cates

The adsorption of polymer and surfactant molecules onto colloidal particles or droplets in solution can be characterized non-destructively by scattering techniques. In a first part, the general framework of Dynamic Light Scattering, Small…

Soft Condensed Matter · Physics 2007-05-24 Julian Oberdisse

The adsorption behavior of ions at liquid-vapor interfaces exhibits several unexpected yet generic features. In particular, energy and entropy are both minimum when the solute resides near the surface, for a variety of ions in a range of…

Statistical Mechanics · Physics 2017-02-08 Suriyanarayanan Vaikuntanathan , Patrick R. Shaffer , Phillip L. Geissler

The fiber bundle model is essentially an array of elements that break when sufficient load is applied on them. With a local loading mechanism, this can serve as a model for a one-dimensional interface separating the broken and unbroken…

Statistical Mechanics · Physics 2016-11-09 Soumyajyoti Biswas , Lucas Goehring

We report on the linear viscoelastic properties of mixtures comprising multiarm star (as model soft colloids) and long linear chain homopolymers in a good solvent. In contrast to earlier works, we investigated symmetric mixtures (with a…

Soft Condensed Matter · Physics 2020-07-01 Daniele Parisi , Domenico Truzzolillo , Vishnu D. Deepak , Mario Gauthier , Dimitris Vlassopoulos

A nonlocal diffuse interface model is used to study bubble assemblies in ternary systems. As model parameters vary, a large number of morphological phases appear as stable stationary states. One open question related to the polarity…

Soft Condensed Matter · Physics 2017-12-05 Chong Wang , Xiaofeng Ren , Yanxiang Zhao

Hypothesis:Diffusion in confinement is an important fundamental problem with significant implications for applications of supported liquid phases. However, resolving the spatially dependent diffusion coefficient, parallel and perpendicular…

Using fluorescence microscopy we study the adsorption of single latex microparticles at a water/water interface between demixing aqueous solutions of polymers, generally known as a water-in-water emulsion. Similar microparticles at the…

Soft Condensed Matter · Physics 2018-05-23 Louis Keal , Carlos E. Colosqui , Hans Tromp , Cecile Monteux

We study the partitioning of cosolute particles in a thin film of a semi-flexible polymer network by a combination of coarse-grained (implicit-solvent) stochastic dynamics simulations and mean-field theory. We focus on a wide range of…

Soft Condensed Matter · Physics 2017-08-22 Won Kyu Kim , Arturo Moncho-Jorda , Rafael Roa , Matej Kanduc , Joachim Dzubiella

We perform numerical simulations of isolated, partially active polymers, driven out-of-equilibrium by a fraction of their monomers. We show that, if the active beads are all gathered in a contiguous block, the position of the section along…

Soft Condensed Matter · Physics 2023-09-04 Marin Vatin , Sumanta Kundu , Emanuele Locatelli

Filler-polymer interactions are one of the keys to understanding the physical properties of polymer composites. These interactions give rise to an interface with specific properties that may have a nontrivial effect on the macroscopic…

Materials Science · Physics 2016-09-30 Yanhui Huang , Linda S. Schadler

We consider a model mixture of hard colloidal spheres and non-adsorbing polymer chains in a theta solvent. The polymer component is modelled as a polydisperse mixture of effective spheres, mutually noninteracting but excluded from the…

Soft Condensed Matter · Physics 2009-11-10 A. R. Denton , M. Schmidt

Using extensive Monte Carlo simulations, we investigate the surface adsorption of self-avoiding trails on the triangular lattice with two- and three-body on-site monomer-monomer interactions. In the parameter space of two-body, three-body,…

Statistical Mechanics · Physics 2020-01-01 Nathann T. Rodrigues , Tiago J. Oliveira , Thomas Prellberg , Aleksander L. Owczarek

Droplet coalescence is ubiquitous in nature and the same time key to various technologies, such as inkjet printing. Here, we report on the coalescence of polymer droplets with different chain lengths coalescing on substrates of different…

Soft Condensed Matter · Physics 2023-09-21 Soheil Arbabi , Panagiotis E. Theodorakis

Polyelectrolyte surfactant mixtures and their interactions with fluid interfaces are an important research field due to their use in technological applications. Most of the existing knowledge on these systems is based on models in which the…

A simple theoretical approach is used to investigate active colloids at the free interface and near repulsive substrates. We employ dynamical density functional theory to determine the steady-state density profiles in an effective…

Soft Condensed Matter · Physics 2017-02-03 René Wittmann , Joseph M. Brader

Adsorption on a boundary line confining a monolayer of particles self-assembling into clusters is studied by MC simulations. We focus on a system of particles interacting via competing interaction potential in which effectively short-range…

Soft Condensed Matter · Physics 2020-01-22 E. Bildanau , J. Pȩkalski , V. Vikhrenko , A. Ciach

We consider a lattice model of a mixture of repulsive, attractive, or neutral monodisperse star (species A) and linear (species B) polymers with a third monomeric species C, which may represent free volume. The mixture is next to a hard,…

Soft Condensed Matter · Physics 2009-11-13 Richard Batman , P. D. Gujrati

We experimentally study a gas of quantum degenerate $^{87}$Rb atoms throughout the full dimensional crossover, from a one-dimensional (1D) system exhibiting phase fluctuations consistent with 1D theory to a three-dimensional (3D)…

We study the equilibrium properties of a model for a binary mixture of catalytically-reactive monomers adsorbed on a two-dimensional substrate decorated by randomly placed catalytic bonds. The interacting $A$ and $B$ monomer species undergo…

Statistical Mechanics · Physics 2009-11-11 M. N. Popescu , S. Dietrich , G. Oshanin
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