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Ring torsion effects on optical excitation properties in poly(para-phenylene) (PPP) and polyaniline (PAN) are investigated by extending the Shimoi-Abe model [Synth. Met. 78, 219 (1996)]. The model is solved by the intermediate exciton…

Soft Condensed Matter · Physics 2016-08-31 Kikuo Harigaya

Component of photoexcited states with large spatial extent is investigated for optical absorption spectra of the electroluminescent conjugated polymers by using the intermediate exciton theory. We calculate the ratio of oscillator strengths…

Soft Condensed Matter · Physics 2008-02-03 Kikuo Harigaya

The component of photoexcited states with large spatial extent is investigated for poly(para-phenylenevinylene) using the intermediate exciton theory. We find a peak due to long-range excitons at the higher-energy side of the lowest main…

Condensed Matter · Physics 2008-02-03 Kikuo Harigaya

We perform ab initio calculations of optical properties for a typical semiconductor conjugated polymer, poly-para-phenylenevinylene, in both isolated chain and crystalline packing. In order to obtain results for excitonic energies and…

Materials Science · Physics 2009-11-07 Alice Ruini , Marilia J. Caldas , Giovanni Bussi , Elisa Molinari

The effects of the electron-phonon interaction on optical excitations can be understood in terms of exciton-phonon coupling, and require a careful treatment in low-dimensional materials with strongly bound excitons or strong electron-hole…

Materials Science · Physics 2022-02-17 Gabriel Antonius , Steven G. Louie

We discuss coherent exciton-polariton states in long molecular chains that are formed due to the interaction of molecular excitations with both vacuum photons and surface excitations of the neighboring reflecting substrate. The resonance…

Other Condensed Matter · Physics 2009-11-13 Yu. N. Gartstein , V. M. Agranovich

A phenomenological coupled exciton model is proposed in order to characterize optical excitations in extended dendrimers. An onsite exciton state is assigned at each phenyl rings and a nearest neighbor hopping integral which obeys the…

Materials Science · Physics 2016-08-31 Kikuo Harigaya

A novel type of exciton-phonon bound state -- interlayer polaron -- in a double-layer two-dimensional semiconductor with transition metal dichalcogenides as an example, is predicted. In these systems the interaction of the interlayer…

Materials Science · Physics 2020-10-06 M. A. Semina , M. M. Glazov , E. Ya. Sherman

A phenomenological coupled exciton model is proposed in order to characterize optical excitations in extended dendrimers. An onsite exciton state is assigned at each phenyl rings and a nearest neighbor hopping integral which obeys the…

Condensed Matter · Physics 2017-09-13 Kikuo Harigaya

Electronic structures and optical excitations in Moebius conjugated polymers are studied theoretically. Periodic and Moebius boundary conditions are applied to the tight binding model of poly(para-phenylene), taking exciton effects into…

Materials Science · Physics 2007-05-23 Kikuo Harigaya

We study the effect of magnetic field and geometric confinement on excitons confined to a quantum ring. We use analytical matrix elements of the Coulomb interaction and diagonalize numerically the effective-mass Hamiltonian of the problem.…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Jakyoung Song , Sergio E. Ulloa

The problem of long-range correlations of particles produced in high- energy collisions is discussed. Long-range correlations involve large groups of particles. Among them are, e.g., those correlations which lead to ring-like and elliptic…

High Energy Physics - Phenomenology · Physics 2016-09-06 I. M. Dremin

The two state molecular orbital (2-MO) model of the phenyl based semiconductors is used to calculate the low-lying spectra of the Ag and Bu states of poly(para-phenylene) (PPP). The model parameters are determined by fitting its predictions…

Condensed Matter · Physics 2009-10-31 W. Barford , R. J. Bursill , M. Yu. Lavrentiev

Exciton effects on conjugated polymers are investigated in the soliton lattice system. We use the Su-Schrieffer-Heeger model with long-range Coulomb interactions treated by the single-excitation configuration-interaction method. The soliton…

Condensed Matter · Physics 2008-02-03 Kikuo Harigaya , Yukihiro Shimoi , Shuji Abe

Excitons, composite electron-hole quasiparticles, are known to play an important role in optoelectronic phenomena in many semiconducting materials. Recent experiments and theory indicate that the band-gap optics of the newly discovered…

Mesoscale and Nanoscale Physics · Physics 2015-09-02 Yuri N. Gartstein , Xiao Li , Chuanwei Zhang

Electronic structures and optical excitations in Moebius conjugated polymers are studied theoretically. Periodic and Moebius boundary conditions are applied to the tight binding model of poly(para-phenylene), taking into account of the…

Materials Science · Physics 2007-05-23 Kikuo Harigaya

Exciton-polaritons in organic materials are hybrid states that result from the strong interaction of photons and the bound excitons that these materials host. Organic polaritons hold great interest for optoelectronic applications, however…

The effects of long-range intermolecular interactions on characteristic features of soliton bound states, consisting of localized excitons and polaritons in molecular crystals interacting with a high-intensity optical field, are…

Optics · Physics 2019-12-17 E. Nji Nde Aboringong , Alain M. Dikandé

Exciton-phonon dynamics on a 1D lattice with long-range exciton-exciton interaction have been introduced and elaborated. Long-range interaction leads to a nonlocal integral term in the motion equation of the exciton subsystem if we go from…

Mathematical Physics · Physics 2011-04-08 Nick Laskin

We explore the mechanism for the long-lived quantum coherence by considering the discrete phonon modes: these vibrational modes effectively weaken the exciton-environment interaction, due to the new composite (polaron) formed by excitons…

Chemical Physics · Physics 2017-07-10 Zhedong Zhang , Jin Wang
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