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We study by Monte Carlo simulations and scaling analysis two models of pairs of confined and dense ring polymers in two dimensions. The pair of ring polymers are modelled by squared lattice polygons confined within a square cavity and they…

Soft Condensed Matter · Physics 2022-01-05 EJ Janse van Rensburg , E Orlandini

The phase structure of self-avoiding polymerized membranes is studied by extensive Hybrid Monte Carlo simulations. Several folding transitions from the flat to a collapsed state are found. Using a suitable order parameter and finite size…

Condensed Matter · Physics 2009-10-28 Christian Münkel , Dieter W. Heermann

We use the method of dimensional reduction to show that a branching polymer with excluded volume interaction confined between two flat plates has, in the thermodynamic limit, a confinement free energy and density profile that is the same as…

Statistical Mechanics · Physics 2009-11-13 Rouzbeh Ghafouri , Joseph Rudnick , Robijn Bruinsma

We show how dynamic heterogeneities (DH), a hallmark of glass-forming materials, depend on chain flexibility and chain length in polymers. For highly flexible polymers, a relatively large number of monomers ($N_c\sim500$) undergo correlated…

Soft Condensed Matter · Physics 2025-11-25 Matthew Reynolds , Daniel L. Baker , Peter D. Olmsted , Johan Mattsson

We study the thermodynamic properties of a semiflexible polymer confined inside strips of widths L<=9 defined on a square lattice. The polymer is modeled as a self-avoiding walk and a short range interaction between the monomers and the…

Statistical Mechanics · Physics 2007-05-23 Jurgen F. Stilck

The coupled dynamics of entangled polymers which span a broad time and length scales govern the unique viscoelastic properties of polymers. To follow chain mobility by numerical simulations from the intermediate Rouse and reptation regimes…

Soft Condensed Matter · Physics 2016-11-03 Gary S. Grest

We obtain the entropy of flexible linear chains composed of M monomers placed on the square lattice using a transfer matrix approach. An excluded volume interaction is included by considering the chains to be self-and mutually avoiding, and…

Statistical Mechanics · Physics 2009-11-07 W. G. Dantas , J. F. Stilck

We report dynamic Monte Carlo simulation on conformational transition of H-shaped branched polymers by varying main chain (backbone) and side chain (branch) length. H-shaped polymers in comparison with equivalent linear polymers exhibit a…

Soft Condensed Matter · Physics 2015-06-17 Ashok Kumar Dasmahapatra , Venkata Mahanth Sanka

Using the tensor network approach, we investigate the monomer-dimer models on a checkerboard lattice, in which there are interactions (with strength $\nu$) between the parallel dimers on half of the plaquettes. For the fully packed…

Statistical Mechanics · Physics 2015-04-08 Sazi Li , Wei Li , Ziyu Chen

We report extensive simulations of the relaxation dynamics of a self-avoiding polymer confined inside a cylindrical pore. In particular, we concentrate on examining how confinement influences the scaling behavior of the global relaxation…

Soft Condensed Matter · Physics 2009-11-13 A. Arnold , B. Bozorgui , D. Frenkel , B. -Y. Ha , S. Jun

The phase diagram for a two-dimensional self-avoiding walk model on the square lattice incorporating attractive short-ranged interactions between parallel sections of walk is derived using numerical transfer matrix techniques. The model…

Statistical Mechanics · Physics 2009-11-07 D. P. Foster , F. Seno

Trails (bond-avoiding walks) provide an alternative lattice model of polymers to self-avoiding walks, and adding self-interaction at multiply visited sites gives a model of polymer collapse. Recently, a two-dimensional model (triangular…

Statistical Mechanics · Physics 2013-02-01 Andrea Bedini , Aleksander L Owczarek , Thomas Prellberg

We present data of Monte Carlo simulations for monodisperse linear polymer chains in dense melts with degrees of polymerization between N=16 and N=512. The aim of this study is to investigate the crossover from Rouse-like dynamics for short…

Soft Condensed Matter · Physics 2009-10-31 T. Kreer , J. Baschnagel , M. Mueller , K. Binder

We study pressurised self-avoiding ring polymers in two dimensions using Monte Carlo simulations, scaling arguments and Flory-type theories, through models which generalise the model of Leibler, Singh and Fisher [Phys. Rev. Lett. Vol. 59,…

Statistical Mechanics · Physics 2011-05-12 Mithun K. Mitra , Gautam I. Menon , R. Rajesh

We present a unifying picture of the compact, dense and dilute phases of two-dimensional polymers. The lattice dependence of the scaling exponents for compact polymers is reconciled with their universality in the dense and dilute case. In…

Statistical Mechanics · Physics 2007-05-23 Jesper Lykke Jacobsen , Jane' Kondev

Recently it has been shown that a two-dimensional model of self-attracting polymers based on attracting segments displays two phase transitions, a theta-like collapse between swollen polymers and a globular state and another between the…

Soft Condensed Matter · Physics 2008-07-10 J. Krawczyk , A. L. Owczarek , T. Prellberg

The interplay of topological constraints, excluded volume interactions, persistence length and dynamical entanglement length in solutions and melts of linear chains and ring polymers is investigated by means of kinetic Monte Carlo…

Statistical Mechanics · Physics 2009-10-31 M. Mueller , J. P. Wittmer , J. -L. Barrat

Large-scale Monte Carlo simulations of a phase-separating colloid-polymer mixture are performed and compared to recent experiments. The approach is based on effective interaction potentials in which the central monomers of self-avoiding…

Soft Condensed Matter · Physics 2007-05-23 R. L. C. Vink , A. Jusufi , J. Dzubiella , C. N. Likos

Diffusion properties of a self-avoiding polymer embedded in regularly distributed obstacles with spacing a=20 and confined in two dimensions is studied numerically using the extended bond fluctuation method which we have developed recently.…

Soft Condensed Matter · Physics 2009-10-31 Ryuzo Azuma , Hajime Takayama

We have analyzed the equilibrium response of chain molecules to stretching. For a homogeneous sequence of monomers, the induced transition from compact globule to extended coil below the $\theta$-temperature is predicted to be sharp. For…

Soft Condensed Matter · Physics 2009-11-07 Phillip L. Geissler , Eugene I. Shakhnovich