Related papers: Dynamical-charge neutrality at a crystal surface
The charge inversion phenomenon is studied by molecular dynamics simulations, focusing on size and valence asymmetric salts, and a threshold of surface charge density for charge inversion. The charge inversion criteria by the…
We consider a confined sheared active polar liquid crystal with a uniform orientation and study the effect of variations in the magnitude of polarization. Restricting our analysis to one-dimensional geometries, we demonstrate that with…
In this short viewpoint, we discuss the assignment of ionic charges in solids. We argue that formal oxidation states serve a useful function, and that absolute values of partial charges should be interpreted and applied with caution; the…
The sliding motion of aqueous droplets on hydrohobic surfaces leads to charge separation at the trailing edge, with implications from triple-line friction to hydrovoltaic energy generation. Charges deposited on the solid surface have been…
Delivering the full benefits of first principles calculations to battery materials demands the development of accurate and computationally-efficient electronic structure methods that incorporate the effects of the electrolyte environment…
Although significant insights have been obtained into chemical and physical properties that govern to the performance of catalysts in traditional thermal processes, the work on electro-, photo-, or plasma-catalytic approaches has been…
We analyze the behavior of a suspension of active polar particles under shear. In the absence of external forces, orientationally ordered active particles are known to exhibit a transition to a state of non-uniform polarization and…
Uncompensated charges do not occur in Nature and any local charge should be a result of charge separation. Dissociable chemical groups at interfaces in contact with ions in solution, whose chemical equilibrium depends both on short-range…
We prove three exact sum rules that relate the polarization of active Brownian particles to their one-body current: (i) The total polarization vanishes, provided that there is no net flux through the boundaries, (ii) at any planar wall the…
We investigate the dynamics of negative surface discharges in air through numerical simulations with a 2D fluid model. A geometry consisting of a flat dielectric embedded between parallel-plate electrodes is used. Compared to negative…
Ionic crystals, such as solid electrolytes and complex oxides, are central to modern technologies for energy storage, sensing, actuation, and other functional applications. An important fundamental issue in the atomic and quantum-scale…
Surface properties of mixtures of charged platelike colloids and salt in contact with a charged planar wall are studied within density functional theory. The particles are modeled by hard cuboids with their edges constrained to be parallel…
Topological objects resulting from symmetry breakdown may be either stable or metastable depending on the pattern of symmetry breaking. However, if they trap zero-energy modes of fermions, and in the process acquire non-integer fermionic…
We revisit the stabilization of ionization of atoms subjected to a superintense laser pulse using nonlinear dynamics. We provide an explanation for the lack of complete ionization at high intensity and for the decrease of the ionization…
Silver iodide is one of the most potent inorganic ice nucleating particles known, a feature generally attributed to the excellent lattice match between its basal Ag-(0001) and I-(000-1) surfaces, and ice. This crystal termination, however,…
Electrostatics in the solution phase is governed by free electrical charges such as ions, as well as by bound charges that arise when a polarizable medium responds to an applied field. In a local medium, described by a constant dielectric…
The sum rule formalism is used to evaluate rigorous bounds for the density and current static response functions in superfluid helium at zero temperature. Both lower and upper bounds are considered. The bounds are expressed in terms of…
We study the stability of topologically protected zero-energy flat bands at the surface of nodal noncentrosymmetric superconductors, accounting for the alteration of the gap near the surface. Within a selfconsistent mean-field theory, we…
We investigate active electrolytes within the mean-field level of description. The focus is on how the double-layer structure of passive, thermalized charges is affected by active dynamics of all constituting ions. One feature of active…
In this paper we review different aspects of the dynamical Casimir- Polder potential between a neutral atom and a perfectly conducting plate under nonequilibrium conditions. In order to calculate the time evolution of the atom-wall…