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The second virial coefficient for the Mie potential is evaluated using the method of brackets. This method converts a definite integral into a series in the parameters of the problem, in this case this is the temperature $T$. The results…

Mathematical Physics · Physics 2024-10-17 Ivan Gonzalez , Igor Kondrashuk , Victor H. Moll , Daniel Salinas-Arizmendi

The second viral coefficient calculated using the equation suggested in the paper of Kaplun A.B., Meshalkin A.B. Equation for the second virial coefficient published in High temperature high pressure, 1999, Volume 31, pages 253-258 is…

Statistical Mechanics · Physics 2013-06-11 I. H. Umirzakov

This note examines the second virial coefficient for an imperfect gas subject to a 2n-n interparticle potential in any dimension d between 0 and n. A compact analytic expression is presented for this quantity which shows that, apart from a…

Statistical Mechanics · Physics 2016-08-31 M. Lawrence Glasser

In our previous work [1], using indirect evaluation methods we concluded that the uncertainties of the second and the third density virial coefficient, B and C, of helium-4 at 5 K calculated by various authors had been overestimated. To…

Instrumentation and Detectors · Physics 2024-01-05 Haiyang Zhang , Wenjing Liu , Xiangjie Kong , Bo Gao , Yaonan Song , Mark Plimmer , Laurent Pitre

The second virial coefficient and the second acoustic virial coefficient for helium-4 and helium-3 are computed for a wide range of temperatures (0.5 - 1000K) using a highly accurate nonrelativistic interaction potential [M. Przybytek et…

Using a high temperature virial expansion, we present a controllable study of the thermodynamics of strongly correlated Fermi gases near the BEC-BCS crossover region. We propose a practical way to determine the expansion coefficients for…

Quantum Gases · Physics 2009-04-25 Xia-Ji Liu , Hui Hu , Peter D. Drummond

An exact analytic form for the second virial coefficient, valid for the entire range of temperature, is presented for the Lennard-Jones fluid in this paper. It is derived by making variable transformation that gives rise to the Hamiltonian…

Chemical Physics · Physics 2009-09-21 Byung Chan Eu

Recent advances regarding the interplay between ab initio calculations and metrology are reviewed, with particular emphasis on gas-based techniques used for temperature and pressure measurements. Since roughly 2010, several thermophysical…

We use LVDSMC simulations to calculate the second-order temperature jump coefficient for a dilute gas whose temperature is governed by the Poisson equation with a constant forcing term. Both the hard sphere gas and the BGK model of the…

Fluid Dynamics · Physics 2015-06-03 Gregg A. Radtke , Nicolas G. Hadjiconstantinou , Shigeru Takata , Kazuo Aoki

The van-der-Waals version of the second virial coefficient is not far from being exact if the model parameters are appropriately chosen. It is shown how the van-der-Waals resemblance originates from the interplay of thermal averaging and…

Statistical Mechanics · Physics 2008-06-02 K. Baerwinkel , J. Schnack

In this work, we propose indirect evaluation methods to check the accuracy and the uncertainty of ab initio calculated virial coefficients. To this end, we have used single-pressure refractive-index gas thermometry (SPRIGT) to estimate the…

Instrumentation and Detectors · Physics 2024-01-05 Haiyang Zhang , Bo Gao , Mark Plimmer , Laurent Pitre

We study the thermodynamical properties of an ideal gas of non-Abelian Chern-Simons particles and we compute the second virial coefficient, considering the effect of general soft-core boundary conditions for the two-body wavefunction at…

High Energy Physics - Theory · Physics 2013-04-19 Francesco Mancarella , Andrea Trombettoni , Giuseppe Mussardo

It is shown that the interaction potentials for argon, krypton, xenon, carbon dioxide, ammonia, water, n-pentane, n-octane, 1-propanol, suggested in [1] cannot describe experimental second density virial coefficient data within their…

Statistical Mechanics · Physics 2016-04-19 I. H. Umirzakov

It is shown that the potential of Keesom which depends on temperature cannot be used for calculate the second virial coefficient of polar molecules and the formulae for second virial coefficient of [2] have no molecular statistical…

Other Condensed Matter · Physics 2016-04-18 I. H. Umirzakov

Aims: We investigate temperature fluctuations in H II regions in terms of a two-phase model, which assumes that the nebular gas consists of a hot and a cold phase. Methods: We derive general formulae for T([O III), the [O III] forbidden…

Astrophysics · Physics 2008-06-18 Y. Zhang , B. Ercolano , X. -W. Liu

We have used the generalized two-atom ideal gas model in Tsallis statistics for the statistical description of a real gas. By comparing the heat capacity with the experimental results for the two-atom molecule gases such as N2, O2 and CO,…

Statistical Mechanics · Physics 2015-08-19 Lina Guo , Jiulin Du

We derive path-integral expressions for the second and third virial coefficients of monatomic quantum gases. Unlike previous work that considered only Boltzmann statistics, we include exchange effects (Bose-Einstein or Fermi-Dirac…

Statistical Mechanics · Physics 2020-05-25 Giovanni Garberoglio , Allan H. Harvey

We follow the generalisation of exclusion statistics to infinite dimensional Hilbert space as envisaged in Phys. Rev. Lett. {\bf{72}}, 3629, 1994. We reproduce the third virial coefficients at leading order for single species of anionic gas…

Other Condensed Matter · Physics 2014-12-02 Saptarshi Mandal

Improved two-body and three-body potentials for helium have been used to calculate from first principles the third density and acoustic virial coefficients for both $^4$He and $^3$He. For the third density virial coefficient $C(T)$,…

Chemical Physics · Physics 2024-08-13 Daniele Binosi , Giovanni Garberoglio , Allan H. Harvey

We derive an explicit analytic expression for the first quantum correction to the second virial coefficient of a $d$-dimensional fluid whose particles interact via the generalized Lennard-Jones $(2n,n)$ potential. By introducing an…

Statistical Mechanics · Physics 2025-12-12 Daniel Parejo , Andrés Santos
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