Related papers: Entropic Forces in Binary Hard Sphere Mixtures: Th…
The problem of surface effects at a fluid/force field boundary is investigated. A classical simple fluid with a locally introduced field simulating a solid is considered. For the case of a hard-core field, rigid, exponential, realistic, and…
The Barker-Henderson perturbation theory is a bedrock of liquid-state physics, providing quantitative predictions for the bulk thermodynamic properties of realistic model systems. However, this successful method has not been exploited for…
Binary mixtures of hard-spheres with different diameters and square-well attraction between different particles are studied by theory and Monte Carlo simulations. In our mesoscopic theory, local fluctuations of the volume fraction of the…
Following earlier work, reference is made to the classical entropic force which results from spatially variable disorder, an exclusively repulsive force. In terms of macroscopic variables it is applied to magnetohydrodynamics, causing minor…
We study various manifestations of structural crossover in the properties of a binary mixture of hard-spheres. For homogeneous mixtures that are sufficiently asymmetric, there is a crossover line in the phase diagram such that for…
We experimentally study the jamming of quasi-two-dimensional emulsions. Our experiments consist of oil-in-water emulsion droplets confined between two parallel plates. From the droplet outlines, we can determine the forces between every…
A monte carlo density functional theory is developed for chain molecules which both intra and intermolecularly associate. The approach can be applied over a range of chain lengths. The theory is validated for the case of an associating…
We reexamine results obtained with the recently proposed density functional theory framework based on forces (force-DFT) [Tschopp et al., Phys. Rev. E 106, 014115 (2022)]. We compare inhomogeneous density profiles for hard sphere fluids to…
We investigate the force of flowing granular material on an obstacle. A sphere suspended in a discharging silo experiences both the weight of the overlaying layers and drag of the surrounding moving grains. In experiments with frictional…
We consider the Asakura-Oosawa model of hard sphere colloids and ideal polymers in contact with a porous matrix modeled by immobilized configurations of hard spheres. For this ternary mixture a fundamental measure density functional theory…
We derive an exact equation for density changes induced by a general external field that corrects the hydrostatic approximation where the local value of the field is adsorbed into a modified chemical potential. Using linear response theory…
A hard sphere fluid confined by hard, structureless, and parallel walls is investigated using a certain version of weighted density functional theory. The density profile, the excess coverage, the finite size contribution to the free…
Recent calculations have shown that the linear proportionality between black hole entropy and area can be explained by performing a density matrix calculation for a massless free field theory. By applying the same formalism to an empirical…
We present a systematic simulation campaign to investigate the pairwise interaction of two mobile, monodisperse particles submerged in a viscous fluid and subjected to monochromatic oscillating flows. To this end, we employ the immersed…
Quantitative predictions are presented of a depletion-induced torque and force acting on a single colloidal hard rod immersed in a solvent of hard spheres close to a planar hard wall. This torque and force, which are entirely of entropic…
We introduce the isothermal cavity, static holographic screen, and accelerating surface as holographic screen to study the entropic force in the presence of the Schwarzschild black hole. These may merge to provide a consistent holographic…
A unified formulation of the density functional theory is constructed on the foundations of entropic inference in both the classical and the quantum regimes. The theory is introduced as an application of entropic inference for inhomogeneous…
We examine the effective force between two nanometer scale solutes in water by Molecular Dynamics simulations. Macroscopic considerations predict a strong reduction of the hydrophobic attraction between solutes when the latter are charged.…
We simulate model systems of charged spherical particles in their counterion solution and measure the thermodynamic pressure and the pair distribution function from which we derive effective potentials of mean force. For a system with only…
We consider the Casimir force including all important corrections to it for the configuration used in a recent experiment employing an atomic force microscope. We calculate the long-range hypothetical forces due to the exchange of light and…