Related papers: Microcanonical vs. canonical thermodynamics
We propose a description of pairing properties in finite systems within the canonical and microcanonical ensembles. The approach is derived by solving the BCS and self-consistent quasiparticle random-phase approximation with the…
Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble, whereas canonical ones fail in the most interesting, mostly inhomogeneous, situations like phase separations or away from the thermodynamic…
Particle number fluctuations are studied in the microcanonical ensemble. For the Boltzmann statistics we deduce exact analytical formulae for the microcanonical partition functions in the case of non-interacting massless neutral particles…
For substitutional crystalline solids typically referred to classical discrete system under constant composition, macroscopic structure in thermodynamically equilibrium state can be typically obtained through canonical average, where a set…
Shortened abstract: Microcanonical equilibrium macrostates are characterized as the solutions of a constrained minimization problem, while canonical equilibrium macrostates are characterized as the solutions of a related, unconstrained…
It is generally believed that, in the thermodynamic limit, the microcanonical description as a function of energy coincides with the canonical description as a function of temperature. However, various examples of systems for which the…
We reconsider some general aspects about the mean field thermodynamical description of the astrophysical systems based on the microcanonical ensemble. Starting from these basis, we devote a special attention to the analysis of the scaling…
Conventional thermo-statistics address infinite homogeneous systems within the canonical ensemble. (Only in this case this is equivalent to the fundamental microcanonical ensemble.) However, some 170 years ago the original motivation of…
The thermodynamic properties such as the specific heat are uniquely determined by the second moments of the energy distribution for a given ensemble averaging. However for small particle numbers the results depend on the ensemble chosen. We…
First order phase transitions are described in terms of the microcanonical and canonical ensemble, with special attention to finite size effects. Difficulties in interpreting a "caloric curve" are discussed. A robust parameter indicating…
Microcanonical thermodynamics allows the application of statistical mechanics both to finite and even small systems and also to the largest, self-gravitating ones. However, one must reconsider the fundamental principles of statistical…
The unconstrained ensemble describes completely open systems in which energy, volume and number of particles fluctuate. Here we show that not only equilibrium states can exist in this ensemble, but also that completely open systems can…
A framework is presented for carrying out simulations of equilibrium systems in the microcanonical ensemble using annealing in an energy ceiling. The framework encompasses an equilibrium version of simulated annealing, population annealing…
The anisotropic quantum Heisenberg model with Curie-Weiss-type interactions is studied analytically in several variants of the microcanonical ensemble. (Non)equivalence of microcanonical and canonical ensembles is investigated by studying…
It is shown, that the only reason for possibility of using microcanonical ensemble is that there are probabilistic processes in microworld, that are not described by quantum mechanic. On a simple example it is demonstrated, that canonical…
A generalization of the microcanonical ensemble suggests a simple strategy for the simulation of first order phase transitions. At variance with flat-histogram methods, there is no iterative parameters optimization, nor long waits for…
Recent progress in the synthesis and processing of nano-structured materials and systems calls for an improved understanding of thermal properties on small length scales. In this context, the question whether thermodynamics and, in…
The thermodynamics of a system of interacting bosonic particles and antiparticles in the presence of the Bose-Einstein condensate is studied in the framework of the Skyrme-like mean-field model. It is assumed that the total charge density…
The thermodynamical properties of a generalized Dicke model are calculated and related with the critical properties of its energy spectrum, namely the quantum phase transitions (QPT) and excited state quantum phase transitions (ESQPT). The…
Mean-field models, while they can be cast into an {\it extensive} thermodynamic formalism, are inherently {\it non additive}. This is the basic feature which leads to {\it ensemble inequivalence} in these models. In this paper we study the…