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We present a first-principles calculation of the electronic properties of crystalline silicon and gallium arsenide in a uniform electric field. Polarized Wannier-like functions which are confined in a finite region are obtained by…

Materials Science · Physics 2007-05-23 Pablo Fernández , Andrea Dal Corso , Alfonso Baldereschi

We consider the applicability of phase space Wannier functions" to electronic structure calculations. These generalized Wannier functions are analogous to localized plane waves and constitute a complete, orthonormal set which is…

Other Condensed Matter · Physics 2010-07-22 D. J. Sullivan , J. J. Rehr , J. W. Wilkins , K. G. Wilson

We present a general ab initio method based on Wannier functions using the covariant derivative for simulating the photocurrent in solids. The method is widely applicable to charge/spin DC and AC photocurrent at any perturbation levels in…

Computational Physics · Physics 2024-08-02 Junqing Xu , Haixiao Xiao

We discuss a method for determining the optimally-localized set of generalized Wannier functions associated with a set of Bloch bands in a crystalline solid. By ``generalized Wannier functions'' we mean a set of localized orthonormal…

Materials Science · Physics 2009-10-30 Nicola Marzari , David Vanderbilt

We describe a method to calculate the electronic properties of an insulator under an applied electric field. It is based on the minimization of an electric enthalpy functional with respect to the orbitals, which behave as Wannier functions…

Materials Science · Physics 2019-10-22 Pawel Lenarczyk , Mathieu Luisier

Since the seminal work of Marzari and Vanderbilt, maximally localized Wannier functions have become widely used as a real-space representation of the electronic structure of periodic materials. In this paper we introduce selectively…

Strongly Correlated Electrons · Physics 2016-04-08 Runzhi Wang , Emanuel A. Lazar , Hyowon Park , Andrew J. Millis , Chris A. Marianetti

We present a semi-automated method for obtaining an initial estimate of Wannier functions, designed to facilitate the construction of Wannier functions for describing low-energy effective models of solids, particularly those relevant to…

Strongly Correlated Electrons · Physics 2025-12-24 Tatsuki Oikawa , Kota Ido , Takahiro Misawa , Takashi Koretsune , Kazuyoshi Yoshimi

We investigate the electronic structure of over-coordinated defects in amorphous silicon via density-functional total-energy calculations, with the aim of understanding the relationship between topological and electronic properties on a…

Materials Science · Physics 2007-05-23 M. Fornari , N. Marzari , M. Peressi , A. Baldereschi

The construction of Wannier functions from Bloch orbitals offers a unitary freedom that can be exploited to yield Wannier functions with advantageous properties. Minimizing the spatial variance is a well-known choice; another, previously…

Materials Science · Physics 2026-04-29 Aaron Mahler , Jacob Z. Williams , Neil Qiang Su , Weitao Yang

Thanks to the nearsightedness principle, the low-energy electronic structure of solids can be represented by localized states such as the Wannier functions. Wannier functions are actively being applied to a wide range of phenomena in…

Materials Science · Physics 2021-12-22 Jae-Mo Lihm , Cheol-Hwan Park

Localized Wannier functions provide an efficient and intuitive means by which to compute dielectric properties from first principles. They are most commonly constructed in a post-processing step, following total-energy minimization.…

Materials Science · Physics 2012-05-16 David D. O'Regan , Mike C. Payne , Arash A. Mostofi

Localized Wannier functions provide an efficient and intuitive framework to compute electric polarization from first-principles. They can also be used to represent the electronic systems at fixed electric field and to determine dielectric…

Materials Science · Physics 2020-01-28 Pawel Lenarczyk , Mathieu Luisier

We review the formalisms of the self-consistent GW approximation to many-body perturbation theory and of the generation of optimally-localized Wannier functions from groups of energy bands. We show that the quasiparticle Bloch wave…

Materials Science · Physics 2009-11-13 D. R. Hamann , David Vanderbilt

We generalize the Wannier interpolation of the electron-phonon matrix elements to the case of polar-optical coupling in polar semiconductors. We verify our methodological developments against experiments, by calculating the widths of the…

Materials Science · Physics 2015-09-30 J. Sjakste , N. Vast , M. Calandra , F. Mauri

We discuss a method for constructing generalized Wannier functions that are maximally localized at the minima of a one-dimensional periodic potential with a double-well per unit cell. By following the approach of (Marzari M and Vanderbilt D…

Quantum Gases · Physics 2013-07-04 Michele Modugno , Giulio Pettini

Wannier functions provide a localized representation of spectral subspaces of periodic Hamiltonians, and play an important role for interpreting and accelerating Hartree-Fock and Kohn-Sham density functional theory calculations in quantum…

Computational Physics · Physics 2018-01-29 Anil Damle , Antoine Levitt , Lin Lin

Time-dependent Wannier functions were initially proposed as a means for calculating the polarization current in crystals driven by external fields. In this work, we present a simple gauge where Wannier states are defined based on the…

Materials Science · Physics 2024-10-29 Cristian M. Le , Hannes Hübener , Ofer Neufeld , Angel Rubio

We establish a first-principles theory of vacuum Wannier functions unifying tight-binding and nearly-free-electron descriptions across solid-vacuum interfaces. Analytic solutions for canonical Wannier functions in arbitrary dimension and…

Materials Science · Physics 2026-03-17 Tyler Wu , Tomás Arias

We propose a general method of constructing Wannier functions in disordered systems directly out of energy eigenstates. This method consists of two successive operations: (i) a phase transformation setting the proper localization center;…

Disordered Systems and Neural Networks · Physics 2015-12-24 Junbo Zhu , Zhu Chen , Biao Wu

A standard task in solid state physics and quantum chemistry is the computation of localized molecular orbitals known as Wannier functions. In this manuscript, we propose a new procedure for computing Wannier functions in one-dimensional…

Mathematical Physics · Physics 2025-10-21 Abinand Gopal , Hanwen Zhang
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