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Many processes in chemistry, physics, and biology depend on thermally activated events in which the system changes its state by surmounting an activation barrier. Examples range from chemical reactions, protein folding, and nucleation…

Chemical Physics · Physics 2023-04-26 Pierpaolo Pravatto , Barbara Fresch , Giorgio J. Moro

We make a brief review of the Kramers escape rate theory for the probabilistic motion of a particle in a potential well U(x), and under the influence of classical fluctuation forces. The Kramers theory is extended in order to take into…

Quantum Physics · Physics 2007-05-23 A. J. Faria , H. M. Franca , R. C. Sponchiado

Fusion can be described by the time evolution of a dinuclear system with two degrees of freedom, the relative motion and transfer of nucleons. In the presence of the coupling between two collective modes, we solve the Fokker-Planck equation…

Nuclear Theory · Physics 2015-03-27 Juhee Hong

We consider the problem of optimization of an effective trapping potential in a nanostructure with a quasi-one-dimensional geometry. The optimization is performed to achieve certain target optical properties of the system. We formulate and…

Materials Science · Physics 2015-05-13 Ilya Grigorenko , Herschel Rabitz , Alaxander Balatsky

We present a class of 2D systems which shows a counterintuitive property that contradicts a semi classical intuition: A 2D quantum particle "prefers" tunneling through a barrier rather than traveling above it. Viewing the one particle 2D…

Quantum Physics · Physics 2011-02-14 Denys I. Bondar , Wing-Ki Liu , Misha Yu. Ivanov

We investigate the orgin of ``quantum superarrivals'' in the reflection and transmission probabilities of a Gaussian wave packet for a rectangular potential barrier while it is perturbed by either reducing or increasing its height. There…

Quantum Physics · Physics 2009-11-07 Md. Manirul Ali , A. S. Majumdar , Dipankar Home

We present a novel path-integral method for the determination of time-dependent and time-averaged reaction rates in multidimensional, periodically driven escape problems at weak thermal noise. The so obtained general expressions are…

Statistical Mechanics · Physics 2015-06-24 Jörg Lehmann , Peter Reimann , Peter Hänggi

In this short note, we propose a new and short approach to polynomial escape rates, which can be applied to various open systems with intermittency. The tool of our approach is the maximal large deviations developed in \cite{mldp}.

Dynamical Systems · Mathematics 2025-03-04 Yaofeng Su

We identify a fundamental phenomenon of heterogeneous one dimensional random walks: the escape (traversal) time is maximized when the heterogeneity in transition probabilities forms a pyramid-like potential barrier. This barrier corresponds…

Probability · Mathematics 2020-07-29 Asaf Cassel , Shie Mannor , Guy Tennenholtz

The Kramers problem in the energy-diffusion limited regime of very low friction is difficult to deal with analytically becasue of the repeated recrossings of the barrier that typically occur before an asymptotic rate constant is achieved.…

Statistical Mechanics · Physics 2009-10-31 Jose M. Sancho , Aldo H. Romero , Katja Lindenberg

A new model for the double well potential is presented in the paper. In the new potential, the exchanging rate could be easily calculated by the perturbation method in supersymmetric quantum mechanics. It gives good results whether the…

Quantum Physics · Physics 2015-05-18 Guihua Tian

The paper studies a dynamic blocking problem, motivated by a model of optimal fire confinement. While the fire can expand with unit speed in all directions, barriers are constructed in real time. An optimal strategy is sought, minimizing…

Analysis of PDEs · Mathematics 2020-12-03 Alberto Bressan , Maria Teresa Chiri

We propose an efficient novel path sampling-based framework designed to accelerate the investigation of rare events in complex molecular systems. A key innovation is the shift from sampling restricted path ensemble distributions, as in…

Chemical Physics · Physics 2025-03-28 Gianmarco Lazzeri , Peter G. Bolhuis , Roberto Covino

We revise the encounter-based approach to imperfect diffusion-controlled reactions, which employs the statistics of encounters between a diffusing particle and the reactive region to implement surface reactions. We extend this approach to…

Statistical Mechanics · Physics 2023-10-03 Denis S. Grebenkov

We consider the application of Kramers theory to the microscopic calculation of rates of conformational transitions of macromolecules. The main difficulty in such an approach is to locate the transition state in a huge configuration space.…

Biomolecules · Quantitative Biology 2008-09-02 Marcello Sega , Pietro Faccioli , Francesco Pederiva , Henri Orland

Using the different versions of phenomenological proximity potential as well as other parametrizations within the proximity concept, we perform a detailed comparative study of fusion barriers for asymmetric colliding nuclei with asymmetry…

Nuclear Theory · Physics 2014-11-21 Ishwar Dutt , Rajeev K. Puri

We analyze the behavior of a Brownian particle moving in a double-well potential. The escape probability of this particle over the potential barrier from a metastable state toward another state is known as the Kramers problem. In this work…

Chaotic Dynamics · Physics 2009-11-13 A. O. Bolivar

We consider an insurance company modelling its surplus process by a Brownian motion with drift. Our target is to maximise the expected exponential utility of discounted dividend payments, given that the dividend rates are bounded by some…

Risk Management · Quantitative Finance 2019-01-23 Julia Eisenberg , Paul Krühner

The dynamics of active particles is of interest at many levels and is the focus of theoretical and experimental research. There have been many attempts to describe the dynamics of particles affected by random active forces in terms of an…

Statistical Mechanics · Physics 2020-01-08 Dan Wexler , Nir S. Gov , Kim Ø. Rasmussen , Golan Bel

Finding optimal reaction coordinates and predicting accurate kinetic rates for activated processes are two of the foremost challenges of molecular simulations. We introduce an algorithm that tackles the two problems at once: starting from a…

Statistical Mechanics · Physics 2023-10-30 Line Mouaffac , Karen Palacio-Rodriguez , Fabio Pietrucci