Related papers: On the Microscopic Origin of Cholesteric Pitch
We study the effects of chirality at the segment scale on the thermodynamics of block copolymer melts using self consistent field theory. In linear diblock melts where segments of one block prefer a twisted, or cholesteric, texture, we show…
Chirality plays a crucial role in determining the structure of many systems in nature. Twisted or helical aggregates as a consequence of self-assembly can be seen in many biological and synthetic materials. Despite extensive theoretical and…
Lyotropic cholesteric liquid crystal phases are ubiquitously observed in biological and synthetic polymer solutions, characterized by a complex interplay between thermal fluctuations, entropic and enthalpic forces. The elucidation of the…
Stiff, elongated biomolecules such as filamentous viruses, DNA or cellulose nanocrystals are known to form liquid crystals often exhibiting a helical supramolecular organization. Little is known about the microscopic origin, size and…
Chirality is ubiquitous in nature and plays crucial roles in biology, medicine, physics and materials science. Understanding and controlling chirality is therefore an important research challenge with broad implications in fundamental and…
Recent numerical simulations of hard helical particle systems unveiled the existence of a novel chiral nematic phase, termed screw-like, characterised by the helical organization of the particle C$_2$ symmetry axes round the nematic…
The migration of helical particles in viscous shear flows plays a crucial role in chiral particle sorting. Attaching a non-chiral head to a helical particle leads to a rheotactic torque inducing particle reorientation. This phenomenon is…
Chirality induced spin selectivity, discovered about two decades ago in helical molecules, is a non-equilibrium effect that emerges from the interplay between geometrical helicity and spin-orbit interactions. Several model Hamiltonians…
We have investigated the relationship between the morphology of helical particles and the features of the cholesteric (N$^\ast $) phase that they form. Using an Onsager-like theory, applied to systems of hard helices, we show that the…
We show that the recently observed chirality in the charge ordered phase of TiSe2 can be understood as a form of orbital ordering. The microscopic mechanism driving the transition between the novel chiral state and the non-chiral charge…
Chirality is of primary importance in many areas of chemistry and has been extensively investigated since its discovery. We introduce here the description of central chirality for tetrahedral molecules using a geometrical approach based on…
In solid state physics, any symmetry breaking is known to be associated with emergence of an order parameter. However, the order parameter for molecular and crystal chirality, which is a consequence of parity and mirror symmetry breaking,…
The development of quantitative methods for characterizing molecular chirality can provide an important tool for studying chirality induced phenomena in molecular systems. Significant progress has been made in recent years toward…
In a nematic gel, the appearance of nematic order is accompanied by a spontaneous elongation of the gel parallel to the nematic director. If such a gel is made chiral, it has a tendency to form a cholesteric helical texture, in which local…
We introduce a comprehensive numerical framework to generically infer the emergent macroscopic properties of uniaxial nematic and cholesteric phases from that of their microscopic constituent mesogens. This approach, based on the full…
Major advances in X-ray sources including the development of circularly polarized and orbital angular momentum pulses make it possible to probe matter chirality at unprecedented energy regimes and with Angstr\"om and femtosecond…
Molecular chirality has traditionally been viewed as a binary property where a molecule is classified as either chiral or achiral, yet in the recent decades mathematical methods for quantifying chirality have been explored. Here we use toy…
Predicting the macroscopic chiral behaviour of cholesteric liquid crystals from the microscopic chirality of the particles is highly non-trivial, even when the chiral interactions are purely entropic in nature. Here we introduce a novel…
Chirality refers to the asymmetry of objects that cannot be superimposed on their mirror image. It is a concept that exists in various scientific fields and has profound consequences. Although these are perhaps most widely recognized within…
Anomalous Hall effect arising from non-trivial spin configuration (chirality) is studied based on the $s$-$d$ model. Considering a weak coupling case, the interaction is treated perturbatively. Scattering by normal impurities is included.…