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To understand the crystal structure of n-diamond, a hydrogen-doped (H-doped) diamond model has been investigated using first principles calculations. In particular, hydrogen concentration dependent elastic constants and lattice parameters…

Materials Science · Physics 2015-05-27 Bin Wen , Roderick Melnik , Shan Yao , Tingju Li

Isolated hydrogen and hydrogen pairs in bulk diamond matrix have been studied using density functional theory calculations. The electronic structure and stability of isolated and paired hydrogen defects are investigated at different…

Materials Science · Physics 2014-04-28 Ashutosh Upadhyay , Akhilesh Kumar Singh , Amit Kumar

Ultra-wide bandgap and the absence of shallow dopants are the major challenges in realizing diamond based electronics. However, the surface functionalization offers an excellent alternative to tune electronic structure of diamonds. Herein,…

Materials Science · Physics 2022-08-05 N. Mohasin Sulthana , K. Ganesan , P. K. Ajikumar , S. Dhara

Surface electronic properties of undoped hydrogen terminated diamond covered with adsorbates or in electrolyte solutions are summarized. The formation of a conductive layer at the surface of diamond is discussed based on Hall effect,…

Materials Science · Physics 2020-05-11 Christoph E. Nebel

Hydrogenated diamond has been regarded as a promising material in electronic device applications, especially in field-effect transistors (FETs). However, the quality of diamond hydrogenation has not yet been established, nor has the…

The surface functionalization of diamond has been extensively studied through a variety of techniques, such as oxidation. Several oxygen groups have been correspondingly detected on the oxidized diamond, such as COC (ester), CO (ketonic),…

Hydrogen radical attacks and subsequent hydrogen migrations are considered to play an important role in the atomic-scale mechanisms of diamond chemical vapour deposition growth. We perform a comprehensive analysis of the reactions involving…

The growth of thin amorphous hydrogenated carbon films (a-C:H) on diamond (111) surface from the bombardment of CH2 radicals is studied using molecular dynamics simulations. The structural analysis shows that the local structure (e.g., the…

Materials Science · Physics 2014-11-27 Chuan-guo Zhang , Yong Yang , Ting Hao , Ming Zhang

The phase diagram of model anisotropic particles with four attractive patches in a tetrahedral arrangement has been computed at two different values for the range of the potential, with the aim of investigating the conditions under which a…

Materials Science · Physics 2013-06-26 Eva G. Noya , Carlos Vega , Jonathan P. K. Doye , Ard A. Louis

The atomic structure and physical properties of few-layered <111> oriented diamond nanocrystals (diamanes), covered by hydrogen atoms from both sides are studied using electronic band structure calculations. It was shown that energy…

Boron-doped diamond (BDD) has attracted much attentions in semi-/super-conductor physics and electrochemistry, where the surface structures play crucial roles. Herein, we systematically re-examined the probable surface reconstructions of…

Materials Science · Physics 2020-10-30 Le The Anh , Shota Iizuka , Yasuaki Einaga , Celine Catalan , Yousoo Kim , Yoshitaka Tateyama

Isolated hydrogen, deuterium, and muonium in diamond have been studied by path-integral molecular dynamics simulations in the canonical ensemble. Finite-temperature properties of these point defects were analyzed in the range from 100 to…

Materials Science · Physics 2009-11-11 Carlos P. Herrero , Rafael Ramirez , Eduardo R. Hernandez

Most of hydrocarbons are either molecular structures or linear polymeric chains. Discovery of graphene and manufacturing of its monohydride -- graphane incite interest in search for three-dimensional hydrocarbon polymers. However up to now…

Materials Science · Physics 2021-11-30 M. V. Kondrin , V. V. Brazhkin

Diamond is a promising candidate for enhancing the negative-ion surface production in the ion sources for neutral injection in fusion reactors; hence evaluation of its reactivity towards hydrogen plasma is of high importance. High quality…

We consider a new C2H nanostructure based on bilayer graphene transformed under the covalent bond of hydrogen atoms adsorbed on its external surface, as well as compounds of carbon atoms located opposite each other in neighboring layers.…

Mesoscale and Nanoscale Physics · Physics 2010-02-04 Leonid A. Chernozatonskii , Pavel B. Sorokin , Alexander G. Kvashnin , Dmitry G. Kvashnin

We use a density-functional based tight-binding method to study diamond growth steps by depositing dicarbon species onto a hydrogen-free diamond (110) surface. Subsequent C_2 molecules are deposited on an initially clean surface, in the…

Materials Science · Physics 2009-10-31 Michael Sternberg , Markus Kaukonen , Risto Nieminen , Thomas Frauenheim

A boron-oxide termination of the diamond (100) surface has been formed by depositing molecular boron oxide $\rm{B_2O_3}$ onto the hydrogen-terminated (100) diamond surface under ultrahigh vacuum conditions and annealing to $\rm{950^{\circ}…

Materials Science · Physics 2024-03-05 Alex K. Schenk , Rebecca Griffin , Anton Tadich , Daniel Roberts , Alastair Stacey

The metastable hexagonal-diamond phase of Si and Ge (and of SiGe alloys) displays superior optical properties with respect to the cubic-diamond one. The latter is the most stable and popular one: growing hexagonal-diamond Si or Ge without…

Materials Science · Physics 2021-02-24 E. Scalise , A. Sarikov , L. Barbisan , A. Marzegalli , D. B. Migas , F. Montalenti , L. Miglio

The relaxed geometries and electronic properties of the hydrogenated phases of the Si(111)-7$\times$7 surface are studied using first-principles molecular dynamics. A monohydride phase, with one H per dangling bond adsorbed on the bare…

Condensed Matter · Physics 2009-10-28 D. R. Alfonso , C. Noguez , D. A. Drabold , S. E. Ulloa

The first-principle method of mathematical modeling was used to calculate the structural, electronic, phonon, and other characteristics of the normal metallic phase of hydrogen at a pressure of 500 GPa. It has been shown that metal hydrogen…

Superconductivity · Physics 2016-07-06 Nikolay Degtyarenko , Evgeny Mazur
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