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A multispecies diffuse interface model is formulated in a fluctuating hydrodynamics framework for the purpose of simulating surfactant interfaces at the nanoscale. The model generalizes previous work to ternary mixtures, employing a…

Fluid Dynamics · Physics 2025-08-26 John B. Bell , Andrew Nonaka , Alejandro L. Garcia

A number of recent experiments have showed that surfactants can modify the growth mode of an epitaxial film, suppressing islanding and promoting layer-by-layer growth. Here I introduce a set of coupled equations to describe the…

Condensed Matter · Physics 2009-10-22 Albert-László Barabási

We investigated the effect of surfactants on an interface between two kinds of liquid by molecular dynamics simulation. We adopted the simple bead-spring model with two atoms as the surfactants. We controlled the interfacial tension of the…

Statistical Mechanics · Physics 2024-10-14 Shunta Kikuchi , Hiroshi Watanabe

Using coarse grained models we investigate the behavior of water adjacent to an extended hydrophobic surface peppered with various fractions of hydrophilic patches of different sizes. We study the spatial dependence of the mean interface…

Statistical Mechanics · Physics 2014-09-09 Adam P. Willard , David Chandler

The behavior of thin liquid films is known to be strongly affected by the presence of surfactants at the interfaces. The detailed mechanism by which the latter enhance film stability is still a matter of debate, in particular concerning the…

Soft Condensed Matter · Physics 2019-07-24 Lorène Champougny , Benoit Scheid , Frédéric Restagno , Jan Vermant , Emmanuelle Rio

We investigate the dynamical behavior of both binary fluid and ternary microemulsion systems in two dimensions using a recently introduced hydrodynamic lattice-gas model of microemulsions. We find that the presence of amphiphile in our…

comp-gas · Physics 2009-10-28 Andrew N. Emerton , Peter V. Coveney , Bruce M. Boghosian

We use a lattice gas cellular automata model in the presence of random dynamic scattering sites and quenched disorder in the two-phase immiscible model with the aim of producing an interface dynamics similar to that observed in Hele-Shaw…

Fluid Dynamics · Physics 2015-08-06 R. M. Azevedo , R. R. Montenegro-Filho , M. D. Coutinho-Filho

We study the topology of fluid interfaces in the 3D Ising model in the rough phase. It turns out that such interfaces are accurately described as dilute gases of microscopic handles, and the stiffness of the interface increases with the…

Condensed Matter · Physics 2015-06-25 M. Caselle , F. Gliozzi , U. Magnea

Insoluble surfactants adsorbed at liquid-liquid or gas-liquid interfaces alter interfacial tension, leading to variations in the normal stress jump and generating tangential Marangoni stresses that can dramatically affect the flow dynamics.…

Fluid Dynamics · Physics 2025-07-15 Zhong-Han Xue , Jacques Magnaudet , Jie Zhang

The propagation and roughening of a fluid-gas interface through a disordered medium in the case of capillary driven spontaneous imbibition is considered. The system is described by a conserved (model B) phase-field model, with the structure…

Disordered Systems and Neural Networks · Physics 2009-10-31 M. Dube , M. Rost , K. R. Elder , M. Alava , S. Majaniemi , T. Ala-Nissila

Phase field models for two-phase flow with a surfactant soluble in possibly both fluids are derived from balance equations and an energy inequality so that thermodynamic consistency is guaranteed. Via a formal asymptotic analysis, they are…

Fluid Dynamics · Physics 2013-03-12 Harald Garcke , Kei Fong Lam , Björn Stinner

We study the effect of surfactant on the dynamics of a bubble bursting through an interface. We perform fully three-dimensional direct numerical simulations using a hybrid interface-tracking/level-set method accounting for…

Fluid Dynamics · Physics 2021-02-24 C. R. Constante-Amores , L. Kahouadji , A. Batchvarov , S. Shin , J. Chergui , D. Juric , O. K. Matar

A hybrid method is developed to simulate two-phase flows with soluble surfactants. In this method, the interface and bulk surfactant concentration equations of diffuse-interface form, which include source terms to consider surfactant…

Fluid Dynamics · Physics 2023-11-28 Yan Ba , Haihu Liu , Wenqiang Li , Wenjing Yang

New diffuse interface and sharp interface models for soluble and insoluble surfactants fulfilling energy inequalities are introduced. We discuss their relation with the help of asymptotic analysis and present an existence result for a…

Fluid Dynamics · Physics 2016-10-27 Helmut Abels , Harald Garcke , Kei Fong Lam , Josef Weber

An existing phase-field model of two immiscible fluids with a single soluble surfactant present is discussed in detail. We analyze the well-posedness of the model and provide strong evidence that it is mathematically ill-posed for a large…

Numerical Analysis · Mathematics 2013-03-20 Stefan Engblom , Minh Do-Quang , Gustav Amberg , Anna-Karin Tornberg

Interfacial roughening denotes the nonequilibrium process by which an initially flat interface reaches its equilibrium state, characterized by the presence of thermally excited capillary waves. Roughening of fluid interfaces has been first…

Statistical Mechanics · Physics 2013-02-28 Markus Gross , Fathollah Varnik

We study numerically and experimentally the breakup of a pendant droplet loaded with a soluble surfactant. We consider the limit in which surfactant sorption is limited only by diffusion. Surfactant transfer toward the interface is enhanced…

Fluid Dynamics · Physics 2026-05-06 M. Rubio , S. Rodríguez-Aparicio , J. M. Montanero , M. A. Herrada

Extremely small amounts of surface-active contaminants are known to drastically modify the hydrodynamic response of the water-air interface. Surfactant concentrations as low as a few thousand molecules per square micron are sufficient to…

Fluid Dynamics · Physics 2021-09-13 G. Koleski , J. -C. Loudet , A. Vilquin , B. Pouligny , T. Bickel

We study the features of a radial Stokes flow due to a submerged jet directed toward a liquid-air interface. The presence of surface-active impurities confers to the interface an in-plane elasticity that resists the incident flow. Both…

Soft Condensed Matter · Physics 2019-12-20 T. Bickel , J. -C. Loudet , G. Koleski , B. Pouligny

Surfactants can have a detrimental effect on the drag reduction in shear flow over superhydrophobic surfaces in Cassie state. While surfactant-free gas-liquid interfaces are often well approximated as shear-free, surfactants can impede the…

Fluid Dynamics · Physics 2023-06-21 Tobias Baier
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