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Solid solutions occur when multiple chemical species share sites of a common crystal lattice. Although the single site occupation is random, chemical interaction preferences bias the occupation probabilities of neighboring sites, and this…

Materials Science · Physics 2021-04-14 Nathaniel Hoffman , Michael Widom

For a large class of fluids exhibiting ultrasoft bounded pair potentials, particles form crystals consisting of clusters located in the lattice sites, with a density-independent lattice constant. Here we present an investigation on the…

Soft Condensed Matter · Physics 2009-11-13 Angel J. Moreno , Christos N. Likos

Clustering is a common task in machine learning, but clusters of unlabelled data can be hard to quantify. The application of clustering algorithms in chemistry is often dependant on material representation. Ascertaining the effects of…

Machine Learning · Computer Science 2023-05-29 Samantha Durdy , Michael W. Gaultois , Vladimir Gusev , Danushka Bollegala , Matthew J. Rosseinsky

Collective organization in matter plays a significant role in its expressed physical properties. Typically, it is detected via an order parameter, appropriately defined for each given system's observed emergent patterns. Recent developments…

Statistical Mechanics · Physics 2016-08-16 V. S. Vijayaraghavan , R. G. James , J. P. Crutchfield

Recent advances in classical density functional theory are combined with stochastic process theory and rare event techniques to formulate a theoretical description of nucleation, including crystallization, that can predict nonclassical…

Chemical Physics · Physics 2019-04-09 James F. Lutsko

The formation, movement and gluing of clusters can be described through a system of non local balance laws. Here, the well posedness of this system is obtained, as well as various stability estimates. Remarkably, qualitative properties of…

Analysis of PDEs · Mathematics 2024-10-15 Rinaldo M. Colombo , Mauro Garavello

Entropy notions for $\varepsilon$-incremental practical stability and incremental stability of deterministic nonlinear systems under disturbances are introduced. The entropy notions are constructed via a set of points in state space which…

Optimization and Control · Mathematics 2022-09-13 Michelle S. Chong

We propose an information-theoretical measure, the \textit{relative cluster entropy} $\mathcal{D_{C}}[P \| Q] $, to discriminate among cluster partitions characterised by probability distribution functions $P$ and $Q$. The measure is…

Statistical Mechanics · Physics 2022-10-05 A. Carbone , L. Ponta

We present a clustering method and provide a theoretical analysis and an explanation to a phenomenon encountered in the applied statistical literature since the 1990's. This phenomenon is the natural adaptability of the order when using a…

Statistics Theory · Mathematics 2022-03-23 Thierry Dumont

The entropy distribution of the intracluster medium and the shape of its confining potential well completely determine the X-ray properties of a relaxed cluster of galaxies, motivating us to explore the origin of intracluster entropy and to…

Astrophysics · Physics 2009-11-07 G. Mark Voit , Michael L. Balogh , Richard G. Bower , Cedric G. Lacey , Greg L. Bryan

Influence of surrounding matter on the properties of clusters is considered by an approach combining the methods of statistical and quantum mechanics. A cluster is treated as a bound N-particle system and surrounding matter as thermostat.…

Statistical Mechanics · Physics 2015-06-25 V. I. Yukalov , E. P. Yukalova

Five different methods which can be used to analytically calculate entropies that are nonconcave as functions of the energy in the thermodynamic limit are discussed and compared. The five methods are based on the following ideas and…

Statistical Mechanics · Physics 2010-05-17 Hugo Touchette

A statistical description of heavy particles suspended in incompressible rough self-similar flows is developed. It is shown that, differently from smooth flows, particles do not form fractal clusters. They rather distribute inhomogeneously…

Chaotic Dynamics · Physics 2007-05-23 J. Bec , M. Cencini , R. Hillerbrand

The X-ray luminosity and temperature of clusters and groups of galaxies do not scale in a self-similar manner. This has often been interpreted as a sign that the intracluster medium has been substantially heated by non-gravitational…

Astrophysics · Physics 2009-10-31 Greg L. Bryan

Configurational entropy is an important factor in the free energy change of many macromolecular recognition and binding processes, and has been intensively studied. Despite great progresses that have been made, the global sampling remains…

Biological Physics · Physics 2012-12-04 Wenzhao Li , Kai Wang , Suyan Tian , Pu Tian

We investigate the formation of cluster crystals with multiply occupied lattice sites on a spherical surface in systems of ultra-soft particles interacting via repulsive, bounded pair potentials. Not all interactions of this kind lead to…

Soft Condensed Matter · Physics 2018-07-31 Stefano Franzini , Luciano Reatto , Davide Pini

The maximum entropy method has recently been successfully introduced to a variety of natural language applications. In each of these applications, however, the power of the maximum entropy method is achieved at the cost of a considerable…

cmp-lg · Computer Science 2008-02-03 John D. Lafferty , Bernhard Suhm

A new method that accurately describes strongly correlated states and captures dynamical correlation is presented. It is derived as a modification of coupled-cluster theory with single and double excitations (CCSD) through consideration of…

Chemical Physics · Physics 2013-07-15 Daniel Kats , Frederick R. Manby

In recent years, a better understanding of the Monte Carlo method has provided us with many new techniques in different areas of statistical physics. Of particular interest are so called cluster methods, which exploit the considerable…

Statistical Mechanics · Physics 2007-05-23 Werner Krauth

In physics, entanglement 'reduces' the entropy of an entity, because the (von Neumann) entropy of, e.g., a composite bipartite entity in a pure entangled state is systematically lower than the entropy of the component sub-entities. We show…

Neurons and Cognition · Quantitative Biology 2023-07-26 Diederik Aerts , Jonito Aerts Argëlles , Lester Beltran , Suzette Geriente , Sandro Sozzo