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We present the results of a new perturbation calculation in polymer statistics which starts from a ground state that already correctly predicts the long chain length behaviour of the mean square end--to--end distance $\langle R_N^2 \rangle\…

Condensed Matter · Physics 2009-10-28 S. R. Shannon , T. C. Choy , R. J. Fleming

We report the results of extensive Dynamic Monte Carlo simulations of systems of self-assembled Equilibrium Polymers without rings in good solvent. Confirming recent theoretical predictions, the mean-chain length is found to scale as $\Lav…

Soft Condensed Matter · Physics 2009-10-31 J. P. Wittmer , A. Milchev , M. E. Cates

Self-avoiding polymers in strictly two-dimensional ($d=2$) melts are investigated by means of molecular dynamics simulation of a standard bead-spring model with chain lengths ranging up to N=2048. % The chains adopt compact configurations…

Soft Condensed Matter · Physics 2015-05-18 H. Meyer , J. P. Wittmer , T. Kreer , A. Johner , J. Baschnagel

For a self-repelling polymer chain consisting of n segments we calculate the persistence length L(j,n), defined as the projection of the end-to-end vector on the direction of the j`th segment. This quantity shows some pronounced variation…

Soft Condensed Matter · Physics 2009-11-10 Lothar Schäfer , Knut Elsner

Using a finite size scaling form for reunion probability, we show numerically the existence of a binding-unbinding transition for Directed polymers with random interaction. The cases studied are (A1) two chains in 1+1 dimensions, (A2) two…

Condensed Matter · Physics 2009-10-28 Sutapa Mukherji , Somendra M. Bhattacharjee , A. Baumgärtner

We consider polymers in which M randomly selected pairs of monomers are restricted to be in contact. Analytical arguments and numerical simulations show that an ideal (Gaussian) chain of N monomers remains expanded as long as M<<N; its mean…

Condensed Matter · Physics 2009-10-28 Yacov Kantor , Mehran Kardar

Extensive Monte Carlo data analysis gives clear evidence that collapsed linear polymers in two dimensions fall in the universality class of athermal, dense self-avoiding walks, as conjectured by B.Duplantier [Phys.Rev.Lett. 71, 4274…

Statistical Mechanics · Physics 2007-05-23 Marco Baiesi , Enzo Orlandini , Attilio L. Stella

The breakdown of dynamical scaling for a dilute polymer solution in 2D has been suggested by Shannon and Choy [Phys. Rev. Lett. {\bf 79}, 1455 (1997)]. However, we show here both numerically and analytically that dynamical scaling holds…

Soft Condensed Matter · Physics 2009-11-10 E. Falck , O. Punkkinen , I. Vattulainen , T. Ala-Nissila

We present Monte Carlo simulations of semidilute solutions of long self-attracting chain polymers near their Ising type critical point. The polymers are modeled as monodisperse self-avoiding walks on the simple cubic lattice with attraction…

Soft Condensed Matter · Physics 2009-10-30 H. Frauenkron , P. Grassberger , HLRZ Juelich , Germany

We examine the scaling of the linear dimension of the system size of a real polymer solution at constant excess free energy and in two different spacial dimensionalities, d=d0 and d=d1. Standard results for the functional form of the excess…

Soft Condensed Matter · Physics 2008-09-23 C. P. Lowe , M. W. Dreischor

We introduce a new disorder regime for directed polymers in dimension $1+1$ that sits between the weak and strong disorder regimes. We call it the intermediate disorder regime. It is accessed by scaling the inverse temperature parameter…

Probability · Mathematics 2014-03-28 Tom Alberts , Konstantin Khanin , Jeremy Quastel

We calculate the correction-to-scaling exponent $\omega_T$ that characterizes the approach to the scaling limit in multicomponent polymer solutions. A direct Monte Carlo determination of $\omega_T$ in a system of interacting self-avoiding…

Soft Condensed Matter · Physics 2009-11-11 Andrea Pelissetto , Ettore Vicari

We study the collapse of two-dimensional polymers, via an O($n$) model on the square lattice that allows for dilution, bending rigidity and short-range monomer attractions. This model contains two candidates for the theta point,…

Mathematical Physics · Physics 2016-09-12 Eric Vernier , Jesper Lykke Jacobsen , Hubert Saleur

Previous theories of dilute polymer solutions have failed to distinguish clearly between two very different ways of taking the long-chain limit: (I) $N \to\infty$ at fixed temperature $T$, and (II) $N \to\infty$, $T \to T_\theta$ with $x…

High Energy Physics - Lattice · Physics 2010-12-17 Alan D. Sokal

We use an off-lattice microscopic model for solutions of equilibrium polymers (EP) in a lamellar shear flow generated by means of a self-consistent external field between parallel hard walls. The individual conformations of the chains are…

Soft Condensed Matter · Physics 2009-10-31 A. Milchev , J. P. Wittmer , D. P. Landau

We numerically investigate the influence of self-attraction on the critical behaviour of a polymer in two dimensions, by means of an analysis of finite-size results of transfer-matrix calculations. The transfer matrix is constructed on the…

Statistical Mechanics · Physics 2015-06-25 H. W. J. Blöte , M. T. Batchelor , B. Nienhuis

We report extensive simulations of the relaxation dynamics of a self-avoiding polymer confined inside a cylindrical pore. In particular, we concentrate on examining how confinement influences the scaling behavior of the global relaxation…

Soft Condensed Matter · Physics 2009-11-13 A. Arnold , B. Bozorgui , D. Frenkel , B. -Y. Ha , S. Jun

We show random polymer is diffusive in dimensions 1 and 2 in probability in an intermediate scaling regime. The scale is $\beta= o(N^{-1/4})$ in d=1 and $\beta=o((\log N)^{-1/2})$ in $d=2$ as $N\rightarrow \infty$.

Probability · Mathematics 2012-01-31 Zi Sheng Feng

We report results of extensive Dynamical Monte Carlo investigations on self-assembled Equilibrium Polymers (EP) without loops in good solvent. (This is thought to provide a good model of giant surfactant micelles.) Using a novel algorithm…

Soft Condensed Matter · Physics 2009-10-31 J. P. Wittmer , A. Milchev , M. E. Cates

A scaling relation for the disjoining pressure of strongly confined polymer fluids is proposed for the first time, which yields directly the scaling exponent, nu, of the radius of gyration for polymers. To test the proposed scaling relation…

Soft Condensed Matter · Physics 2015-03-11 Armando Gama Goicochea , Elías Pérez
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