Related papers: Non-uniform deformations in liquid crystalline ela…
A thermodynamically related model is developed for describing elastic rubber-like behavior of amorphous and crystallizing polymers and demonstrated on example of simple extension. Both the “entropic” and “energetic”…
In this paper we propose a nonlinear elasticity model of macromolecular conformational change (deformation) induced by electrostatic forces generated by an implicit solvation model. The Poisson-Boltzmann equation for the electrostatic…
In this paper, the two-dimensional pure bending of a hyperelastic substrate coated by a nematic liquid crystal elastomer (abbreviated as NLCE) is studied within the framework of nonlinear elasticity. The governing system, arising from the…
Deformations of conventional solids are described via elasticity, a classical field theory whose form is constrained by translational and rotational symmetries. However, flexible metamaterials often contain an additional approximate…
Bead spring models for polymers in solution are nonlinear if either the finite extensibility of the polymer, excluded volume effects or hydrodynamic interactions between polymer segments are taken into account. For such models we use a…
The elasticity of rubbery polymer networks has been considered to be entropy-driven. On the other hand, studies on single polymer chain mechanics have revealed that the elasticity of ultimately stretched polymer chains is dominated by the…
Instabilities in thin elastic sheets, such as wrinkles, are of broad interest both from a fundamental viewpoint and also because of their potential for engineering applications. Nematic liquid crystal elastomers offer a new form of control…
This letter presents a closed-form integral-equation formulation that models the director tilting in nematic liquid crystals. The proposed formulation is computationally efficient compared to numerical methods and provides a physical…
We start from a variational model for nematic elastomers that involves two energies: mechanical and nematic. The first one consists of a nonlinear elastic energy which is influenced by the orientation of the molecules of the nematic…
We model polydomain liquid-crystal elastomers by extending the neo-classical soft and semi-soft free energies used successfully to describe monodomain samples. We show that there is a significant difference between polydomains cross-linked…
We present molecular dynamics computer simulations of filaments of model non-Newtonian liquid stretched in a uniaxial deformation to the point of breaking. The liquid consists of Lennard-Jones monomers bound into chains of 100 monomers by…
A micrometer-scale elastic shell immersed in a nematic liquid crystal may be deformed by the host if the cost of deformation is comparable to the cost of elastic deformation of the nematic. Moreover, such inclusions interact and form chains…
Nonlinear plastic modes (NPMs) are collective displacements that are indicative of imminent plastic instabilities in elastic solids. In this work we formulate the atomistic theory that describes the reversible evolution of NPMs and their…
In this article, we study minimization of the Landau-de Gennes energy for liquid crystal elastomer.The total energy, is of the sum of the Lagrangian elastic stored energy function of the elastomer and the Eulerian Landau-de Gennes energy of…
We introduce a nonlinear, one-dimensional bending-twisting model for an inextensible bi-rod that is composed of a nematic liquid crystal elastomer. The model combines an elastic energy that is quadratic in curvature and torsion with a…
In this work we will derive an anisotropic generalisation of the finitely extensible chain model, due to Kuhn and Gr\"un, which is well known in rubber elasticity. This provides a chain energy that couples elastic behaviour to a probability…
Extra-large deformations in ultra-soft elastic materials are ubiquitous, yet systematic studies and methods to understand the mechanics of such huge strains are lacking. Here we investigate this complex problem systematically with a simple…
Liquid crystal elastomers (LCEs) marry the large deformation response of a cross-linked polymer network with the nematic order of liquid crystals pendent to the network. Of particular interest is the actuation of LCE sheets where the…
Liquid crystalline networks (LCNs) are stimuli-responsive materials formed from polymeric chains cross-linked with rod-like mesogenic segments, which, in the nematic phase, align along a non-polar director. A key characteristic of these…
A general procedure to investigate the elastic response and calculate the elastic constants of stressed and unstressed materials through continuum field modeling, particularly the phase field crystal (PFC) models, is presented. It is found…