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We report results from a molecular dynamics (MD) simulation on the conformations of a long flexible polyelectrolyte complexed to a charged sphere, \textit{both negatively charged}, in the presence of neutralizing counterions in the strong…

Soft Condensed Matter · Physics 2009-11-07 Rene Messina , Christian Holm , Kurt Kremer

Exact results for the scaling properties of compact polymers on the square lattice are obtained from an effective field theory. The entropic exponent \gamma=117/112 is calculated, and a line of fixed points associated with interacting…

Statistical Mechanics · Physics 2009-10-31 Jane' Kondev , Jesper L. Jacobsen

We study the geometry of a semiflexible polymer at finite temperatures. The writhe can be calculated from the properties of Gaussian random walks on the sphere. We calculate static and dynamic writhe correlation functions. The writhe of a…

Soft Condensed Matter · Physics 2009-10-31 A. C. Maggs

Conformations of a single semiflexible polymer chain dissolved in a low molecular weight liquid crystalline solvents (nematogens) are examined by using a mean field theory. We takes into account a stiffness and partial orientational…

Soft Condensed Matter · Physics 2009-11-07 Akihiko Matsuyama

A lattice model of a hetero-polymer with random hydrophilic-hydrophobic charges interacting with the solvent is introduced, whose continnuum counterpart has been proposed by T. Garel, L. Leibler and H. Orland {J. Phys. II France 4, 2139…

Statistical Mechanics · Physics 2009-10-31 A. Trovato , J. van Mourik , A. Maritan

Directed polymers on 1+1 dimensional lattices coupled to a heat bath at temperature $T$ are studied numerically for three ensembles of the site disorder. In particular correlations of the disorder as well as fractal patterning are…

Disordered Systems and Neural Networks · Physics 2022-09-01 Alexander K. Hartmann

We investigate the collapse kinetics of charged polymers (polyelectrolytes) induced by counterion condensation using coarse-grained molecular dynamics simulations. Under good solvent conditions, polyelectrolytes above the critical charge…

Soft Condensed Matter · Physics 2025-04-18 Susmita Ghosh , Satyavani Vemparala

Entangled polymers are an important class of materials for their toughness, processability, and functionalizability. However, physically detailed modeling of highly entangled polymers can prove challenging, especially as one considers…

Soft Condensed Matter · Physics 2024-10-28 Vickie Chen , Brandon Wang , Joseph D. Peterson

A directed polymer is allowed to branch, with configurations determined by global energy optimization and disorder. A finite size scaling analysis in 2D shows that, if disorder makes branching more and more favorable, a critical transition…

Statistical Mechanics · Physics 2016-08-31 Giovanni Sartoni , Attilio L. Stella

In this work we study a completely degenerated fermion gas at zero temperature within a semiclassical approximation for the Hamiltonian arising in polymer quantum mechanics. Polymer quantum systems are quantum mechanical models quantized in…

Solar and Stellar Astrophysics · Physics 2015-06-22 Guillermo Chacon-Acosta , Hector Hernandez-Hernandez

We analyze a (1+1)-dimension directed random walk model of a polymer dipped in a medium constituted by two immiscible solvents separated by a flat interface. The polymer chain is heterogeneous in the sense that a single monomer may…

Probability · Mathematics 2007-05-23 Erwin Bolthausen , Giambattista Giacomin

We study the Cauchy directed polymer model on $\mathbb{Z}^{1+1}$, where the underlying random walk is in the domain of attraction to the $1$-stable law. We show that, if the random walk satisfies certain regularity assumptions and its…

Probability · Mathematics 2018-08-01 Ran Wei

Chain-like macromolecules (polymers) show characteristic adsorption properties due to their flexibility and internal degrees of freedom, when attracted to surfaces and interfaces. In this review we discuss concepts and features that are…

Soft Condensed Matter · Physics 2009-11-07 Roland Netz , David Andelman

Using a mapping of compact polymers on the Manhattan lattice to spanning trees, we calculate exactly the average number of bends at infinite temperature. We then find, in a high temperature approximation, the energy of the system as a…

Statistical Mechanics · Physics 2010-03-12 Armin Rahmani , Andrea Velenich , Claudio Chamon

These lecture notes are a guided tour through the fascinating world of polymer chains interacting with themselves and/or with their environment. The focus is on the mathematical description of a number of physical and chemical phenomena,…

Probability · Mathematics 2012-05-16 Francesco Caravenna , Frank den Hollander , Nicolas Pétrélis

We show that non-entangled polymers display an elastic-like behaviour at a macroscopic scale (probed at some 0.100 mm thickness) up to at least hundred degrees above the glass transition temperature. This observation, found under…

Soft Condensed Matter · Physics 2016-09-12 H Mendil , P Baroni , Laurence Noirez

We study a heteropolymer model with random contact interactions introduced some time ago as a simplified model for proteins. The model consists of self-avoiding walks on the simple cubic lattice, with contact interactions between nearest…

Soft Condensed Matter · Physics 2009-10-31 Ugo Bastolla , Peter Grassberger

We analyze the localized phase of a general model of a directed polymer in the proximity of an interface that separates two solvents. Each monomer unit carries a charge, $\omega_n$, that determines the type (attractive or repulsive) and the…

Probability · Mathematics 2007-05-23 G. Giacomin , F. L. Toninelli

We consider the energy of a randomly charged polymer. We assume that only charges on the same site interact pairwise. We study the lower tails of the energy, when averaged over both randomness, in dimension three or more. As a corollary, we…

Probability · Mathematics 2015-05-14 Amine Asselah

We consider a polymer with configuration modeled by the path of a Markov chain, interacting with a potential $u+V_n$ which the chain encounters when it visits a special state 0 at time $n$. The disorder $(V_n)$ is a fixed realization of an…

Probability · Mathematics 2015-05-13 Kenneth S. Alexander , Nikos Zygouras
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