Related papers: Frenkel Excitons in Random Systems With Correlated…
We analyze the effects of intersite energy correlations on the linear optical properties of one-dimensional disordered Frenkel exciton systems. The absorption line width and the factor of radiative rate enhancement are studied as a function…
On the optical absorption and the density of states of Frenkel exciton systems on square, rectangular, and triangular lattices with nearest-neighbor interactions and a Gaussian distribution of transition frequencies. The analysis is based…
A phenomenological coupled exciton model is proposed in order to characterize optical excitations in extended dendrimers. An onsite exciton state is assigned at each phenyl rings and a nearest neighbor hopping integral which obeys the…
A phenomenological coupled exciton model is proposed in order to characterize optical excitations in extended dendrimers. An onsite exciton state is assigned at each phenyl rings and a nearest neighbor hopping integral which obeys the…
Optical absorption in a random one-dimensional lattice in the presence of paired correlated disorder is studied. The absorption line shape is evaluated by solving the microscopic equations of motion of the Frenkel-exciton problem in the…
We analyze the peculiarities of the motional narrowing effect in disordered one-dimensional Frenkel chains with off-diagonal disorder, induced by uncorrelated Gaussian fluctuations in the positions of the host units. A clear difference in…
We report the amplitude scaling behavior of Frenkel exciton chains with nearest-neighbor correlated off-diagonal random interactions. The band center spectrum and its localization properties are investigated through the integrated density…
The interplay between coherence and system-environment interactions is at the basis of a wide range of phenomena, from quantum information processing to charge and energy transfer in molecular systems, biomolecules, and photochemical…
We theoretically analyze the excitation energy transfer between two closely spaced linear molecular J-aggregates, whose excited states are Frenkel excitons. The aggregate with the higher (lower) exciton band edge energy is considered as the…
The simulation of the optical properties of supramolecular aggregates requires the development of methods, which are able to treat a large number of coupled chromophores interacting with the environment. Since it is currently not possible…
We investigate theoretically the phenomenon of exchange narrowing in the absorption spectrum of a chain of monomers, which are coupled via resonant dipole-dipole interaction. The individual (uncoupled) monomers exhibit a broad absorption…
We employ the first-principles GW+Bethe Salpeter equation approach to study the electronic structure and optical absorption spectra of uniaxial strained graphene with many-electron effects included. Applied strain not only induces an…
Numerical study of the one-dimensional Frenkel Hamiltonian with on-site randomness is carried out. We focus on the statistics of the energy levels near the lower exciton band edge, i. e. those determining optical response. We found that the…
A method is proposed for calculating the absorption spectrum of a long one-dimensional closed-into-a-ring chain with Frenkel's exciton under diagonal disorder. This disorder is represented by the hyperbolic singularities of atomic fission.…
We investigate the effects of disorder on Frenkel excitons in disordered conjugated polymers with allowed rotations about single bonds. In these materials, the principal effect of the disorder is to modify the transfer integrals appearing…
One-dimensional semiconductors are characterized by strongly bound excitons. Therefore, the Frenkel regime of excitons localized within a few unit cells is readily reached and traditional Wannier exciton models become inadequate. In the…
The Frenkel exciton model was adapted to describe X-ray absorption and resonant inelastic scattering spectra of polynuclear transition metal complexes by means of restricted active space self-consistent field method. The proposed approach…
The theoretical description and the properties of Frenkel excitons in non-covalently bonded molecular aggregates are reviewed from a multi-exciton perspective of dissipative quantum dynamics. First, the photophysical and quantum chemical…
We compare localization properties of one-dimensional Frenkel excitons with Gaussian and Lorentzian uncorrelated diagonal disorder. We focus on the states of the Lifshits tail, which dominate the optical response and low-temperature energy…
We propose an explanation of the bands of extended states appearing in random one dimensional models with correlated disorder, focusing on the Continuous Random Dimer model [A.\ S\'{a}nchez, E.\ Maci\'a, and F.\ Dom\'\i nguez-Adame, Phys.\…