Related papers: NMR Spectroscopy and the Crystal-Field Interaction…
High-resolution Zeeman spectroscopy of electronic-nuclear hyperfine levels of ${^5\mathrm{I}_8}\rightarrow{^5\mathrm{I}_7}$ transitions in Ho$^{3+}$:Y$_2$SiO$_5$ is reported. Crystal-field parameters determined for the two $C_1$ symmetry…
Single-spin magnetic resonance spectroscopy promises to yield structural and chemical information at the level of individual atoms or molecules, in a non-invasive way. Here, we use an Er3+ paramagnetic center in a CaWO4 crystal, detected by…
We report a comprehensive specific heat and inelastic neutron scattering study to explore the possible origin of multiferroicity in HoCrO$_3$. We have performed specific heat measurements in the temperature range 100 mK - 290 K and…
The hyperfine structure of atoms and ions is widely used in fundamental and applied research. Accurate knowledge of hyperfine splitting values is essential for quantum metrology applications as well as for improving the performance of…
A novel, to the best of our knowledge, ultralow-temperature luminescence thermometry strategy is proposed, based on a measurement of relative intensities of hyperfine components in the spectra of Ho$^{3+}$ ions doped into a crystal. A…
Quantum sensors have attracted broad interest in the quest towards sub-micronscale NMR spectroscopy. Such sensors predominantly operate at low magnetic fields. Instead, however, for high resolution spectroscopy, the high-field regime is…
We report Zeeman infra-red spectroscopy of electronic-nuclear levels of $^5$I$_8 \rightarrow ^5$I$_7$ transitions of Ho$^{3+}$ in the C$_{\rm 4v}$(F$^-$) centre in CaF$_2$ with the magnetic field along the $\langle 111\rangle$ direction of…
We report on THz absorption spectroscopy combined with high magnetic fields of polycrystalline RCrO3 (R= Pr, Sm, Er) aiming understanding spin wave resonances at their low temperature magnetic phases. Our measurements show that the…
The design of a wideband decimeter-wave (200 - 900 MHz) spectrometer with a magnetic induction of up to ~ 10 T is described. This spectrometer is intended for studying electronic - nuclear oscillations in antiferromagnets at low…
Nuclear spin hyperpolarization provides a promising route to overcome the challenges imposed by the limited sensitivity of nuclear magnetic resonance. Here we demonstrate that dissolution of spin-polarized pentacene-doped naphthalene…
Computational crystal-field models have provided consistent models of both electronic and Zeeman-hyperfine structure for several rare earth ions. These techniques have not yet been applied to the Zeeman-hyperfine structure of Eu$^{3+}$…
Rare-earth spin ensembles are a promising platform for microwave quantum memory applications due to their hyperfine transitions, which can exhibit exceptionally long coherence times when using an operation point with zero first-order Zeeman…
The symmetric splitting of two spin-wave branches in an antiferromagnetic resonance (AFR) experiment has been an essential measurement of antiferromagnets for over half a century. In this work, circularly polarized time-domain THz…
We use complementary optical spectroscopy methods to directly measure the lowest crystal-field energies of the rare-earth quantum magnet LiY$_{1-x}$Ho$_{x}$F$_{4}$, including their hyperfine splittings, with more than 10 times higher…
Optically active spin defects in solids offer promising platforms to investigate nuclear spin clusters with high sensitivity and atomic-site resolution. To leverage near-surface defects for molecular structure analysis in chemical and…
We report on the magnetic and Mossbauer properties of polycrystalline HoFe1-xCrxO3 compounds. Magnetization data reveals the continuous tailoring of magnetic transition due to weakening of Ho3+ Fe3+ and Fe3+ Fe3+ interactions in the entire…
We report dielectric spectroscopy of single-crystalline \ce{NdMgAl11O19}, a magnetoplumbite hexaaluminate in which localized \ce{Nd^{3+}} moments coexist with a polarizable \ce{AlO5} bipyramidal network. The real part of the permittivity,…
Two nanosized PrF3 samples were synthesized using two different procedures. The X-ray and HRTEM experiments showed high crystallinity of synthesized sample. Comparison of enhanced 141Pr NMR spectra of microsized (45 $\mu$m) and nanosized…
We present a comprehensive spectroscopic study of C$_{2v}$ point-group symmetry sites in Sm$^{3+}$:CaF$_2$/SrF$_2$ codoped with either NaF or LiF. Data includes electron paramagnetic resonance measurements of Zeeman and hyperfine…
Multidimensional coherent optical spectroscopy is one of the most powerful tools for investigating complex quantum mechanical systems. While it was conceived decades ago in magnetic resonance spectroscopy using micro- and radio-waves, it…