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Molecules of bisthiolterthiophene have been adsorbed on the two facing gold electrodes of a mechanically controllable break junction in order to form metal-molecule(s)-metal junctions. Current-voltage (I-V) characteristics have been…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 C. Kergueris , J. -P. Bourgoin , S. Palacin , D. Esteve , C. Urbina , M. Magoga , C. Joachim

Non-local conductance experiments using tunnel junctions can provide valuable spectroscopic information on both the transport and relaxation of quasiparticles in superconductors, as these techniques directly probe the quasiparticle charge…

Superconductivity · Physics 2026-04-30 Kevin M. Ryan , Detlef Beckmann , Venkat Chandrasekhar

The subbands of weakly coupled double-layer two dimensional electron gas systems consist of narrowly spaced pairs whose corresponding wavefunctions are symmetric and antisymmetric combinations of isolated layer subband wavefunctions. The…

Mesoscale and Nanoscale Physics · Physics 2009-10-28 L. Swierkowski , A. H. MacDonald

We report first-principles calculations of the inelastic current-voltage (I-V) characteristics of a gold point contact and a molecular junction in the nonresonant regime. Discontinuities in the I-V curves appear in correspondence to the…

Mesoscale and Nanoscale Physics · Physics 2015-06-24 Yu-Chang Chen , Michael Zwolak , Massimiliano Di Ventra

Spectral weights and current-voltage characteristics of an artificial diatomic molecule are calculated, considering cases where the dots connected in series are in general different. The spectral weights allow us to understand the effects…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 F. Ramirez , E. Cota , S. E. Ulloa

The inelastic electron tunneling spectrum (IETS)of highly oriented pyrolitic graphite (HOPG) has been measured with scanning tunneling spectroscopy (STS) at 6K. The observed spectral features are in very good agreement with the vibrational…

Condensed Matter · Physics 2009-11-10 L. Vitali , M. A. Schneider , K. Kern , L. Wirtz , A. Rubio

The dynamics of a single spin embedded in a the tunnel junction between ferromagnetic contacts is strongly affected by the exchange coupling to the tunneling electrons. Moment reversal of the local spin induced by the bias voltage across…

Mesoscale and Nanoscale Physics · Physics 2008-06-04 J. Fransson

We present a scattering theory description for the inelastic current noise in the presence of electron-vibration interactions. In this description, we specify elastic and inelastic scattering contributions to the shot noise by examining…

Mesoscale and Nanoscale Physics · Physics 2017-09-15 Sejoong Kim

We calculate non-perturbatively the inelastic effects on the conductance through a conjugated molecular wire-metal heterojunction, including realistic electron-phonon coupling. We show that at sub-band-gap energies the current is dominated…

Materials Science · Physics 2009-10-31 H. Ness , A. J. Fisher

A detailed computational analysis has been performed, considering copper atomic contacts that are exposed directly to water molecules, hydroxyl groups, and monatomic as well as molecular hydrogen and oxygen species. The optimized physical…

Chemical Physics · Physics 2020-02-28 Firuz Demir , Kevin Dean , George Kirczenow

We consider the transport spectroscopy of a quantum dot with an even number of electrons at finite bias voltage within the Coulomb blockade diamond. We calculate the tunneling current due to the elastic and inelastic co-tunneling processes…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 M. R. Wegewijs , Yu. V. Nazarov

In molecular charge transport, transition voltage spectroscopy (TVS) holds the promise that molecular energy levels can be explored at bias voltages lower than required for resonant tunneling. We investigate the theoretical basis of this…

Mesoscale and Nanoscale Physics · Physics 2011-09-09 Fatemeh Mirjani , Joseph M. Thijssen , Sense Jan van der Molen

We study the effect of electron-vibron interactions on the inelastic transport properties of single-molecule nanojunctions. We use the non-equilibrium Green's functions technique and a model Hamiltonian to calculate the effects of…

Mesoscale and Nanoscale Physics · Physics 2015-03-19 L. K. Dash , H. Ness , R. W. Godby

We have combined ab initio quantum chemistry calculations with a rate-equation formalism to analyze electroluminescence spectra in single-molecule junctions, measured recently by several groups in Scanning Tunneling Microscope setups. In…

Mesoscale and Nanoscale Physics · Physics 2010-05-20 Johannes S. Seldenthuis , Herre S. J. van der Zant , Mark A. Ratner , Joseph M. Thijssen

Several aspects of intermolecular effects in molecular conduction have been studied in recent years. These experimental and theoretical studies, made on several setups of molecular conduction junctions, have focused on the current-voltage…

Mesoscale and Nanoscale Physics · Physics 2013-06-21 Michael Galperin , Abraham Nitzan

We carry out experiments on single-molecule junctions at low temperatures, using the mechanically controlled break junction technique. Analyzing the results received with more than ten different molecules the nature of the first peak in the…

Mesoscale and Nanoscale Physics · Physics 2012-03-21 Daniel Secker , Stefan Wagner , Stefan Ballmann , Rainer Härtle , Michael Thoss , Heiko B. Weber

In this paper we develop an analytical framework for the study of electrochemical impedance of mixed ionic and electronic conductors (MIEC). The framework is based on first-principles and it features the coupling of electrochemical…

Chemical Physics · Physics 2017-08-23 Francesco Ciucci , Yong Hao , David G. Goodwin

Vibrationally inelastic electron transport through a molecular bridge that is connected to two leads is investigated. The study is based on a generic model of vibrational excitation in resonant transmission of electrons through a molecular…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Martin Cizek , Michael Thoss , Wolfgang Domcke

For electrons tunneling between parallel two-dimensional electron systems, conservation of in-plane momentum produces sharply resonant current-voltage characteristics and provides a uniquely sensitive probe of the underlying electronic…

Condensed Matter · Physics 2009-10-28 S. Q. Murphy , J. P. Eisenstein , L. N. Pfeiffer , K. W. West

It is widely believed that when a molecule with thiol (S-H) end groups bridges a pair of gold electrodes, the S atoms bond to the gold and the thiol H atoms detach from the molecule. However, little is known regarding the details of this…

Chemical Physics · Physics 2015-06-11 Firuz Demir , George Kirczenow