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In this article, we derive fully guaranteed error bounds for the energy of convex nonlinear mean-field models. These results apply in particular to Kohn-Sham equations with convex density functionals, which includes the reduced Hartree-Fock…

Modeling many-body quantum systems with strong interactions is one of the core challenges of modern physics. A range of methods has been developed to approach this task, each with its own idiosyncrasies, approximations, and realm of…

Statistical Mechanics · Physics 2018-11-21 Brett Larder , Dirk Gericke , Scott Richardson , Paul Mabey , Thomas White , Gianluca Gregori

Several problems in machine learning, statistics, and other fields rely on computing eigenvectors. For large scale problems, the computation of these eigenvectors is typically performed via iterative schemes such as subspace iteration or…

Numerical Analysis · Mathematics 2020-11-03 Vasileios Charisopoulos , Austin R. Benson , Anil Damle

We solve by Chebyshev spectral collocation some genuinely nonlinear Liouville-Bratu-Gelfand type, 1D and a 2D boundary value problems. The problems are formulated on the square domain $[-1, 1]\times[-1, 1]$ and the boundary condition…

Numerical Analysis · Mathematics 2020-11-30 Calin-Ioan Gheorghiu

Chebyshev filtered subspace iteration is a well-known algorithm for the solution of (symmetric/Hermitian) algebraic eigenproblems which has been implemented in several application codes~\cite{Kronik:2006ff, abinit:2020} or in stand alone…

Numerical Analysis · Mathematics 2026-03-12 Edoardo Di Napoli , Xinzhe Wu

The implementation of an efficient self-consistent field (SCF) method including both scalar relativistic effects and spin-orbit interaction in density functional theory (DFT) is presented. We make use of Gaussian-type orbitals (GTOs) and…

Chemical Physics · Physics 2024-05-03 Yannick J. Franzke , Werner M. Schosser , Fabian Pauly

This work continues a program to systematically generalize the Skyrme Hartree-Fock method for medium and heavy nuclei by applying effective field theory (EFT) methods to Kohn-Sham density functional theory (DFT). When conventional Kohn-Sham…

Nuclear Theory · Physics 2007-05-23 Anirban Bhattacharyya , R. J. Furnstahl

We present two approximation methods for computing eigenfrequencies and eigenmodes of large-scale nonlinear eigenvalue problems resulting from boundary element method (BEM) solutions of some types of acoustic eigenvalue problems in…

Numerical Analysis · Mathematics 2024-09-23 Mohamed El-Guide , Agnieszka Miedlar , Yousef Saad

We explore the class of exponential integrators known as exponential time differencing (ETD) method in this letter to design low complexity nonlinear Fourier transform (NFT) algorithms that compute discrete approximations of the scattering…

Computational Physics · Physics 2019-08-27 Vishal Vaibhav

In this paper, we present a parallel numerical algorithm for solving the phase field crystal equation. In the algorithm, a semi-implicit finite difference scheme is derived based on the discrete variational derivative method. Theoretical…

Computational Engineering, Finance, and Science · Computer Science 2017-03-06 Ying Wei , Chao Yang , Jizu Huang

One of the most promising techniques used for studying the electronic properties of materials is based on Density Functional Theory (DFT) approach and its extensions. DFT has been widely applied in traditional solid state physics problems…

Materials Science · Physics 2013-06-03 Nicola Varini , Davide Ceresoli , Layla Martin-Samos , Ivan Girotto , Carlo Cavazzoni

The Kohn-Sham scheme of density functional theory is one of the most widely used methods to solve electronic structure problems for a vast variety of atomistic systems across different scientific fields. While the method is fast relative to…

We propose an efficient algorithm for the recently published electron/hole-transfer Dynamical-weighted State-averaged Constrained CASSCF (eDSC/hDSC) method studying charge transfer states and D$_1$-D$_0$ crossings for systems with odd…

Computational Physics · Physics 2024-09-24 Tian Qiu , Joseph E. Subotnik

The general procedure underlying Hartree-Fock and Kohn-Sham density functional theory calculations consists in optimizing orbitals for a self-consistent solution of the Roothaan-Hall equations in an iterative process. It is often ignored…

Chemical Physics · Physics 2017-03-16 Alain C. Vaucher , Markus Reiher

We study the accuracy of Kohn-Sham density functional theory (DFT) for warm- and hot-dense matter (WDM and HDM). Specifically, considering a wide range of systems, we perform accurate ab initio molecular dynamics simulations with…

Computational Physics · Physics 2024-11-21 Phanish Suryanarayana , Arpit Bhardwaj , Xin Jing , Shashikant Kumar , John E. Pask

Density Compensation Function (DCF) is widely used in non-Cartesian MRI reconstruction, either for direct Non-Uniform Fast Fourier Transform (NUFFT) reconstruction or for iterative undersampled reconstruction. Current state-of-the-art…

Medical Physics · Physics 2025-10-17 Rui Luo , Peng Hu , Haikun Qi

A semi-spectral Chebyshev method for solving numerically singular integral equations is presented and applied in the quarkonium bound-state problem in momentum space. The integrals containing both, logarithmic and Cauchy singular kernels,…

Quantum Physics · Physics 2016-09-08 A. Deloff

We show that deep neural networks can be integrated into, or fully replace, the Kohn-Sham density functional theory scheme for multi-electron systems in simple harmonic oscillator and random external potentials with no feature engineering.…

Materials Science · Physics 2021-02-25 Kevin Ryczko , David Strubbe , Isaac Tamblyn

Hybrid density functional theory (DFT) remains intractable for large periodic systems due to the demanding computational cost of exact exchange. We apply the tensor hypercontraction (THC) (or interpolative separable density fitting)…

Computational Physics · Physics 2023-10-13 Adam Rettig , Joonho Lee , Martin Head-Gordon

A new numerical algorithm for solving the symmetric eigenvalue problem is presented. The technique deviates fundamentally from the traditional Krylov subspace iteration based techniques (Arnoldi and Lanczos algorithms) or other…

Computational Engineering, Finance, and Science · Computer Science 2009-11-13 Eric Polizzi