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We report the functionalization of carbon nanotubes with two azobenzene-based chromophores with large internal dipole moments and opposite dipole orientations. The molecules are attached to the nanotubes non-covalently via a pyrene tether.…

Mesoscale and Nanoscale Physics · Physics 2013-12-24 Yuanchun Zhao , Changshui Huang , Myungwoong Kim , Bryan M. Wong , François Léonard , Padma Gopalan , Mark A. Eriksson

We present a nanoscale color detector based on a single-walled carbon nanotube functionalized with azobenzene chromophores, where the chromophores serve as photoabsorbers and the nanotube as the electronic read-out. By synthesizing…

Materials Science · Physics 2009-03-30 Xinjian Zhou , Thomas Zifer , Bryan M. Wong , Karen L. Krafcik , Francois Leonard , Andrew L. Vance

Recently, individual single-walled carbon nanotubes (SWNTs) functionalized with azo-benzene chromophores were shown to form a new class of hybrid nanomaterials for optoelectronics applications. Here we use a number of experimental…

We investigate the photoconductance of single-walled carbon nanotube-nanocrystalhybrids. The nanocrystals are bound to the nanotubes via molecular recognition. We find that the photoconductance of the hybrids can be adjusted by the…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 B. Zebli , H. A. Vieyra , I. Carmeli , A. Hartschuh , J. P. Kotthaus , A. W. Holleitner

The attachment of semiconducting nanoparticles to carbon nanotubes is one of the most challenging subjects in nanotechnology. Successful high coverage attachment and control over the charge transfer mechanism and photo-current generation…

Materials Science · Physics 2015-07-20 Alina Chanaewa , Beatriz H. Juarez , Horst Weller , Christian Klinke

We use electrostatic force microscopy and scanned gate microscopy to probe the conducting properties of carbon nanotubes at room temperature. Multi-walled carbon nanotubes are shown to be diffusive conductors, while metallic single-walled…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 A. Bachtold , M. S. Fuhrer , S. Plyasunov , M. Forero , Erik H. Anderson , A. Zettl , Paul L. McEuen

The charge transport properties of single superconducting tin nanowires, encapsulated by multiwalled carbon nanotubes have been investigated by multi-probe measurements. The multiwalled carbon nanotube protects the tin nanowire from…

This letter reports a charge transfer p-doping scheme which utilizes one-electron oxidizing molecules to obtain stable, unipolar carbon nanotube transistors with a self-aligned gate structure. This doping scheme allows one to improve…

Materials Science · Physics 2015-07-20 Jia Chen , Christian Klinke , Ali Afzali , Phaedon Avouris

Carboxylic functionalization (-COOH groups) of carbon nanotubes is known to improve their dispersion properties and increase the electrical conductivity of carbon-nanotube - polymer nanocomposites. We have studied experimentally the effects…

This dissertation aims to demonstrate that photoluminescence spectroscopy could be an efficient technique of functionalized carbon nanotube detection and imaging. The advances in nanotechnology and the potential growth in carbon nanotubes…

Applied Physics · Physics 2019-07-26 Ebrima Saho

The ability to control the conductance of single molecules will have a major impact in nanoscale electronics. Azobenzene, a molecule that changes conformation as a result of a trans/cis transition when exposed to radiation, could form the…

Mesoscale and Nanoscale Physics · Physics 2008-11-26 Miriam del Valle , Rafael Gutierrez , Carlos Tejedor , Gianaurelio Cuniberti

The design of single-molecule photoswitchable emitters was the first milestone toward the advent of single-molecule localization microscopy that sets a new paradigm in the field of optical imaging. Several photoswitchable emitters have been…

A mechanically bistable single-walled carbon nanotube can act as a variable-shaped capacitor with a voltage-controlled transition between collapsed and inflated states. This external control parameter provides a means to tune the system so…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 Oleg E. Shklyaev , Eric Mockensturm , Vincent H. Crespi

The conduction of a single-wall carbon nanotube depends on the pitch. If there are an integral number of carbon hexagons per pitch, then the system is periodic along the tube axis and allows "holes" (, and not "electrons",) to move inside…

Mesoscale and Nanoscale Physics · Physics 2010-03-30 S. Fujita , S. Moon , Y. Takato , James McNabb , S. Godoy

Cavity optomechanics allows the characterization of a vibration mode, its cooling and quantum manipulation using electromagnetic fields. Regarding nanomechanical as well as electronic properties, single wall carbon nanotubes are a…

Mesoscale and Nanoscale Physics · Physics 2020-04-06 Stefan Blien , Patrick Steger , Niklas Hüttner , Richard Graaf , Andreas K. Hüttel

Optical activation of material properties illustrates the potentials held by tuning light-matter interactions with impacts ranging from basic science to technological applications. Here, we demonstrate for the first time that composite…

Materials Science · Physics 2020-11-17 Kwang Jin Lee , Elke Beyreuther , Sohail A. Jalil , Sang Jun Kim , Lukas Eng , Chunlei Guo , Pascal Andre

The dynamical conductance of electrically contacted single-walled carbon nanotubes is measured from dc to 10 GHz as a function of source-drain voltage in both the low-field and high-field limits. The ac conductance of the nanotube itself is…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 Z. Yu , P. J. Burke

Carbon based optoelectronic devices promise to revolutionize modern integrated circuits by combining outstanding electrical and optical properties into a unified technology. By coupling nanoelectronic devices to nanophotonic structures…

Mesoscale and Nanoscale Physics · Physics 2013-06-25 Svetlana Khasminskaya , Feliks Pyatkov , Benjamin S. Flavel , Wolfram H. P. Pernice , Ralph Krupke

We identify a class of covalent functionalizations that preserves or controls the conductance of single-walled metallic carbon nanotubes. [2+1] cycloadditions can induce bond cleaving between adjacent sidewall carbons, recovering in the…

Materials Science · Physics 2009-11-11 Young-Su Lee , Nicola Marzari

Self-assembled functionalized nano particles are at the focus of a number of potential applications, in particular for molecular scale electronics devices. Here we perform experiments of self-assembly of 10 nm Au nano particles (NPs),…

Mesoscale and Nanoscale Physics · Physics 2015-09-15 Yannick Viero , Guillaume Copie , David Guerin , Christophe Krzeminski , Dominique Vuillaume , Stephane Lenfant , Fabrizio Cleri
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