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The stability of a single-walled carbon nanotube placed on top of a catalytic nickel nanoparticle is investigated by means of molecular dynamics simulations. As a case study, we consider the $(12,0)$ nanotube consisting of 720 carbon atoms…

Chemical Physics · Physics 2016-10-07 Alexey V. Verkhovtsev , Stefan Schramm , Andrey V. Solov'yov

Water confined in nanoscale cavities plays a crucial role in everyday phenomena in geology and biology, as well as technological applications at the water-energy nexus. However, even understanding the basic properties of nano-confined water…

We use molecular dynamics simulations to study the diffusion of water inside deformed carbon nanotubes, with different degrees of eccentricity at 300K. We found a water structural transition between tubular-like to single-file for the (7,7)…

Dimensions and molecular structure play pivotal roles in the principle of heat conduction. The dimensional characteristics of solution within nanoscale systems depend on the degrees of confinement. However, the influence of such variations…

Soft Condensed Matter · Physics 2024-05-14 Shun Imamura , Yusei Kobayashi , Eiji Yamamoto

An overview is presented of the various phases predicted to occur when gases are absorbed within a bundle of carbon nanotubes. The behavior may be characterized by an effective dimensionality, which depends on the species and the…

Soft Condensed Matter · Physics 2007-05-23 M. Mercedes Calbi , Milton W. Cole , Silvina M. Gatica , Mary J. Bojan , George Stan

The momentum distribution of the protons in ice Ih, ice VI, high density amorphous ice and water in carbon nanotubes at low temperatures has been measured using deep inelastic neutron scattering. We find that the momentum distribution for…

Recently unusual properties of water in single-walled carbon nanotubes (CNT) with diameters ranging from 1.05 nm to 1.52 nm were observed. It was found that water in the CNT remains in an ice-like phase even when the temperature ranges…

Mesoscale and Nanoscale Physics · Physics 2017-03-23 Siddhartha Sen , Kumar S. Gupta

Carbon nanotubes can serve as one-dimensional nanoreactors for the in-tube synthesis of various nanostructures. Experimental observations have shown that chains, inner tubes, or nanoribbons can grow by the thermal decomposition of…

Materials Science · Physics 2023-06-13 Somayeh Eskandari , János Koltai , István László , Mehran Vaezi , Jenő Kürti

Recently, X.Ma et al. [Phys. Rev. Lett. 118, 027402 (2017)] have suggested that water molecules encapsulated in (6,5) single-wall carbon nanotube experience a temperature-induced quasiphase transition around 150 K interpreted as changes in…

Spontaneous entry of water molecules inside single-wall carbon nanotubes (SWCNTs) has been confirmed by both simulations and experiments. Using molecular dynamics simulations, we have studied the thermodynamics of filling of a (6,6) carbon…

Mesoscale and Nanoscale Physics · Physics 2015-01-27 Hemant Kumar , Chandan Dasgupta , Prabal K. Maiti

The molecular dynamics method, based on an empirical potential energy surface, was used to study the effect of catalyst particle size on the growth mechanism and structure of single-walled carbon nanotubes (SWNTs). The temperature for…

Materials Science · Physics 2009-11-11 Feng Ding , Arne Rosen , Kim Bolton

Experiments and computer simulations demonstrate that water spontaneously fills the hydrophobic cavity of a carbon nanotube. To gain a quantitative thermody- namic understanding of this phenomenon, we use the recently developed Two Phase…

Mesoscale and Nanoscale Physics · Physics 2011-08-22 Hemant Kumar , Biswaroop Mukherjee , Shiang-Tai Lin Chandan Dasgupta , A. K. Sood , Prabal K. Maiti

A simple 1D lattice gas model is presented, which very well describes the equilibrium and kinetic behaviors of water confined in a thin carbon nanotube found in an atomistic molecular dynamics(MD) simulation {[} Nature {\bf 414}, 188 (2001)…

Statistical Mechanics · Physics 2007-05-23 Xin Zhou , Cheng-Quan Li , Mitsumasa Iwamoto

In this article we investigate through molecular dynamics simulations the diffusion behavior of the TIP4P/2005 water when confined in pristine and deformed carbon nanotubes (armchair and zigzag). To analyze different diffusive mechanisms,…

Soft Condensed Matter · Physics 2021-02-03 Bruno H. S. Mendonça , Patricia Ternes , Evy Salcedo , Alan B. de Oliveira , Marcia C. Barbosa

We use molecular dynamics simulations to study the diffusion of water inside deformed carbon nanotubes with different degrees of deformation at 300 K. We found that the number of hydrogen bonds that water forms depends on nanotube topology,…

Soft Condensed Matter · Physics 2020-01-16 Bruno H. S. Mendonça , Patricia Ternes , Evy Salcedo , Alan B. de Oliveira , Marcia C. Barbosa

We have used atomistic molecular dynamics (MD) simulations to study the structure and dynamics of water molecules inside an open ended carbon nanotube placed in a bath of water molecules. The size of the nanotube allows only a single file…

Statistical Mechanics · Physics 2007-12-20 Biswaroop Mukherjee , Prabal K. Maiti , Chandan Dasgupta , A. K. Sood

Classical Molecular Dynamics (MD) simulations are employed as a tool to investigate structural properties of ice crystals under several temperature and pressure conditions. All ice crystal phases are analyzed by means of a computational…

Materials Science · Physics 2015-05-28 M. Cogoni , B. D'Aguanno , L. N. Kuleshova , D. W. M. Hofmann

Single wall carbon nanotubes cooled to cryogenic temperatures are outstanding electronic as well as nano-electromechanical model systems. To probe a largely unperturbed system, we measure a suspended carbon-nanotube device where the…

Mesoscale and Nanoscale Physics · Physics 2019-06-26 K. J. G. Götz , F. J. Schupp , A. K. Hüttel

The temperature-dependent transverse mechanical properties of single-walled nanotubes are studied using a molecular mechanics approach. The stretching and bond angle force constants describing the mechanical behaviour of the sp^{2} bonds…

Atomic and Molecular Clusters · Physics 2015-05-19 Fabrizio Scarpa , Luca Boldrin , Hua-Xin Peng , Chrystel Remillat , Sondipon Adhikari

We explore by molecular dynamic simulations the thermodynamical behavior of an anomalous fluid confined inside rigid and flexible nanopores. The fluid is modeled by a two length scale potential. In the bulk this system exhibits the density…

Soft Condensed Matter · Physics 2014-02-05 Jose Rafael Bordin , Leandro B. Krott , Marcia C. Barbosa
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