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We present an implementation of the relativistic quantum-chemical density matrix renormalization group (DMRG) approach based on a matrix-product formalism. Our approach allows us to optimize matrix product state (MPS) wave functions…

Chemical Physics · Physics 2017-10-24 Stefano Battaglia , Sebastian Keller , Stefan Knecht

The presence of many degenerate $d/f$ orbitals makes polynuclear transition metal compounds such as iron-sulfur clusters in nitrogenase challenging for state-of-the-art quantum chemistry methods. To address this challenge, we present the…

Chemical Physics · Physics 2023-12-22 Chunyang Xiang , Weile Jia , Wei-Hai Fang , Zhendong Li

The density-matrix renormalization-group (DMRG) algorithm is extended to treat time-dependent problems. The method provides a systematic and robust tool to explore out-of-equilibrium phenomena in quantum many-body systems. We illustrate the…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 M. A. Cazalilla , J. B. Marston

We have developed an efficient method for performing density matrix renormalization group (DMRG) simulations of the SU(N) Fermi-Hubbard chain with open boundary conditions, fully leveraging the SU(N) symmetry of the problem. This method…

Strongly Correlated Electrons · Physics 2025-06-04 Pierre Nataf

Configuration-interaction-type calculations on electronic and vibrational structure are often the method of choice for the reliable approximation of many-particle wave functions and energies. The exponential scaling, however, limits their…

Computational Physics · Physics 2019-05-24 Alberto Baiardi , Christopher J. Stein , Vincenzo Barone , Markus Reiher

This thesis gives an extension for the Density Matrix Renormalisation Group (DMRG) to two dimensions and described a newly developed combination of the DMRG and a Green Function Monte Carlo simulation (GFMC). The first two chapters focus on…

Statistical Mechanics · Physics 2007-05-23 M. S. L. du Croo de Jongh

The Density Matrix Renormalization Group (DMRG) method has become a prominent tool for simulating strongly correlated electronic systems characterized by dominant static correlation effects. However, capturing the full scope of electronic…

Chemical Physics · Physics 2024-11-13 Nicholas Bauman , Libor Veis , Karol Kowalski , Jiri Brabec

We introduce the Nuclear Electronic All-Particle Density Matrix Renormalization Group (NEAP-DMRG) method for solving the time-independent Schr\"odinger equation simultaneously for electrons and other quantum species. In contrast to already…

Chemical Physics · Physics 2020-05-29 Andrea Muolo , Alberto Baiardi , Robin Feldmann , Markus Reiher

We report a way of wave function estimation for the density matrix renormalization group (DMRG) method applied to quantum systems, which has 2-site modulation, when the system size extension is necessary in both the finite and the infinite…

Quantum Physics · Physics 2011-02-11 Hiroshi Ueda , Tomotoshi Nishino , Koichi Kusakabe

During the past 15 years, the density matrix renormalization group (DMRG) has become increasingly important for ab initio quantum chemistry. Its underlying wavefunction ansatz, the matrix product state (MPS), is a low-rank decomposition of…

Chemical Physics · Physics 2014-09-25 Sebastian Wouters , Dimitri Van Neck

We present a detailed analysis of a new, iterative density reconstruction algorithm. This algorithm uses a decreasing smoothing scale to better reconstruct the density field in Lagrangian space. We implement this algorithm to run on the…

Cosmology and Nongalactic Astrophysics · Physics 2024-09-19 Xinyi Chen , Nikhil Padmanabhan

A new approach to large-scale nuclear structure calculations, based on the Density Matrix Renormalization Group (DMRG), is described. The method is tested in the context of a problem involving many identical nucleons constrained to move in…

Nuclear Theory · Physics 2011-05-12 J. Dukelsky , S. Pittel

We use the adaptive time-dependent density matrix renormalization group method (t-DMRG) to study the nonequilibrium dynamics of a benchmark quantum impurity system which has a time-dependent Hamiltonian. This model is a resonant-level…

Strongly Correlated Electrons · Physics 2009-04-01 Cheng Guo , Andreas Weichselbaum , Stefan Kehrein , Tao Xiang , Jan von Delft

Density Matrix Renormalization Group (DMRG) and its extensions in the form of Matrix Product States (MPS) are arguably the choice for the study of one dimensional quantum systems in the last three decades. However, due to the limited…

Strongly Correlated Electrons · Physics 2023-04-13 Xiangjian Qian , Mingpu Qin

We have applied the momentum space version of the Density Matrix Renormalization Group method ($k$-DMRG) in quantum chemistry in order to study the accuracy of the algorithm in the new context. We have shown numerically that it is possible…

Strongly Correlated Electrons · Physics 2009-02-06 O. Legeza , J. Roder , B. A. Hess

There has been recent interest in the deployment of ab initio density matrix renormalization group computations on high performance computing platforms. Here, we introduce a reformulation of the conventional distributed memory ab initio…

Chemical Physics · Physics 2021-06-24 Huanchen Zhai , Garnet Kin-Lic Chan

The density matrix renormalization group (DMRG) approach is extended to complex-symmetric density matrices characteristic of many-body open quantum systems. Within the continuum shell model, we investigate the interplay between many-body…

Nuclear Theory · Physics 2009-11-11 J. Rotureau , N. Michel , W. Nazarewicz , M. Ploszajczak , J. Dukelsky

The infinite Density Matrix Renormalisation Group (iDMRG) algorithm is a highly successful numerical algorithm for the study of low-dimensional quantum systems, and is also frequently used to initialise the more popular finite DMRG…

Strongly Correlated Electrons · Physics 2015-12-02 Robert N. C. Pfeifer

We present a generalized framework, renormalized density matrix downfolding (RDMD), to derive systematically improvable, highly accurate, and nonperturbative effective models from ab initio calculations. This framework moves beyond the…

Strongly Correlated Electrons · Physics 2025-02-27 Yueqing Chang , Sonali Joshi , Lucas K. Wagner

We reformulate the density matrix renormalization group method (DMRG) in terms of a single block, instead of the standard left and right blocks used in the construction of the superblock. This version of the DMRG, which we call the puncture…

Condensed Matter · Physics 2009-10-31 M. A. Martin-Delgado , J. Rodriguez-Laguna , G. Sierra
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