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The manipulation of single magnetic molecules may enable new strategies for high-density information storage and quantum-state control. However, progress in these areas depends on developing techniques for addressing individual molecules…

We study single-electron transport in a three-ion molecule with strong uniaxial anisotropy and in the presence of a transverse magnetic field. Two magnetic ions are connected to each other through a third, nonmagnetic ion. The magnetic ions…

Mesoscale and Nanoscale Physics · Physics 2014-05-12 Javier I. Romero , Eduardo R. Mucciolo

We present a new mechanism for a spin blockade effect associated with a change in the type of magnetic anisotropy over oxidation state in a single molecule transistor, by taking an example of an individual Eu$_{2}$(C$_{8}$H$_{8}$)$_{3}$…

Mesoscale and Nanoscale Physics · Physics 2016-11-23 Guangpu Luo , Kyungwha Park

The quantum tunneling of the magnetization vector are studied theoretically in single-domain ferromagnetic nanoparticles placed in an external magnetic field at an arbitrarily directed angle in the $ZX$ plane. We consider the…

Statistical Mechanics · Physics 2009-10-31 Rong Lu , Jia-Lin Zhu , Zhi-Rong Liu , Lee Chang , Bing-Lin Gu

Magnetization measurements of a truly axial symmetry Mn12-tBuAc molecular nanomagnet with a spin ground state of S = 10 show resonance tunneling. This compound has the same magnetic anisotropy as Mn12-Ac but the molecules are better…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 W. Wernsdorfer , M. Murugesu , G. Christou

The linear conductance of a molecular conductor oscillating between two metallic leads is investigated numerically both for Hubbard interacting and noninteracting electrons. The molecule-leads tunneling barriers depend on the molecule…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 K. A. Al-Hassanieh , C. A. Büsser , G. B. Martins , E. Dagotto

While the tunneling conductance between two spherical-like conducting particles depends on the relative inter-particle distance, the wave function overlap between states of two rod-like particles, and so the tunneling conductance, depends…

Disordered Systems and Neural Networks · Physics 2014-10-01 Biagio Nigro , Claudio Grimaldi

We calculate the quantum tunneling rate of a ferromagnetic particle of $\sim 100 \AA$ diameter in a magnetic field of arbitrary angle. We consider the magnetocrystalline anisotropy with the biaxial symmetry and that with the tetragonal…

Soft Condensed Matter · Physics 2009-10-30 Gwang-Hee Kim , Dae Sung Hwang

We consider electronic transport through break-junctions bridged by a single molecule in the Kondo regime. We describe the system by a two-channel Anderson model. We take the tunneling matrix elements to depend on the position of the…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 Jernej Mravlje , Anton Ramsak

The dynamical theory of thermally activated resonant magnetization tunneling in uniaxially anisotropic magnetic molecules such as Mn_12Ac (S=10) is developed.The observed slow dynamics of the system is described by master equations for the…

Statistical Mechanics · Physics 2009-10-31 D. A. Garanin , E. M. Chudnovsky

Tunneling between the two lowest energy levels of single molecule magnets with Ising type anisotropy, accompanied by the emission or absorption of phonons, is considered. Quantitatively accurate calculations of the rates for such tunneling…

Mesoscale and Nanoscale Physics · Physics 2015-10-05 Yun Liu , Anupam Garg

Simple methods are presented allowing the determination of the magnetic anisotropy axes of a crystal of a single-molecule magnet (SMM). These methods are used to determine an upper bound of the easy axis tilts in a standard Mn12-Ac crystal.…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 W. Wernsdorfer , N. E. Chakov , G. Christou

We consider tunneling transport through a Mn$_{12}$ molecular magnet using spin density functional theory. A tractable methodology for constructing many-body wavefunctions from Kohn-Sham orbitals allows for the determination of…

Mesoscale and Nanoscale Physics · Physics 2010-02-08 L. Michalak , C. M. Canali , M. R. Pederson , M. Paulsson , V. G. Benza

We study a possible mechanism of the switching of the magnetic easy axis as a function of hole concentration in (Ga,Mn)As epilayers. In-plane uniaxial magnetic anisotropy along [110] is found to exceed intrinsic cubic magnetocrystalline…

Materials Science · Physics 2009-11-11 K. Hamaya , T. Watanabe , T. Taniyama , A. Oiwa , Y. Kitamoto , Y. Yamazaki

We theoretically study the transport properties of a supramolecular spin valve, consisting of a carbon nanotube with two attached magnetic molecules, weakly coupled to metallic contacts. The emphasis is put on analyzing the change of the…

Mesoscale and Nanoscale Physics · Physics 2019-03-19 A. Plominska , I. Weymann

The crossover between thermally assisted and pure quantum tunneling has been studied in single crystals of high spin (S=10) uniaxial molecular magnet Mn12 using micro-Hall-effect magnetometry. Magnetic hysteresis and relaxation experiments…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 Louisa Bokacheva , Andrew D. Kent , Marc A. Walters

We study the interplay of the Kondo effect and spin-polarized tunneling in a class of systems exhibiting uniaxial magnetic anisotropy, such as magnetic molecules, magnetic adatoms, or quantum dots coupled to a single localized magnetic…

Mesoscale and Nanoscale Physics · Physics 2012-06-06 Maciej Misiorny , Ireneusz Weymann , Jozef Barnas

The symmetry of magnetic quantum tunneling (MQT) in the single molecule magnet Mn12-acetate has been determined by sensitive low-temperature magnetic measurements in the pure quantum tunneling regime and high frequency EPR spectroscopy in…

Mesoscale and Nanoscale Physics · Physics 2009-09-29 E. del Barco , A. D. Kent , S. Hill , J. M. North , N. S. Dalal , E. M. Rumberger , D. N. Hendrickson , N. Chakov , G. Christou

The time-dependent transport through single-molecule magnets coupled to magnetic or non-magnetic electrodes is studied in the framework of the generalized master equation method. We investigate the transient regime induced by the periodic…

Mesoscale and Nanoscale Physics · Physics 2015-09-02 V. Moldoveanu , I. V. Dinu , B. Tanatar , C. P. Moca

Tunneling of electrons through rotor-stator anthracene aldehyde molecular interfaces is studied with a combined ab initio and model approach. Molecular electronic structure calculated from first principles is utilized to model different…

Chemical Physics · Physics 2016-05-27 Irina Petreska , Vladimir Ohanesjan , Ljupco Pejov , Ljupco Kocarev