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Ion transport underlies the operation of biological ion channels and governs the performance of electrochemical energy-storage devices. A long-standing anomaly is that smaller alkali metal ions, such as Li$^+$, migrate more slowly in water…

Soft Condensed Matter · Physics 2026-01-14 Zhenyu Wei , Mu Chen , Jun Ren , Pinyao He , Wei Xu , Wei Liu , Fei Zheng , Yin Zhang , Wei Si , Jinjie Sha , Zhonghua Ni , Yunfei Chen

Matter at low temperatures exhibits unusual properties such as superfluidity, superconductivity, Bose-Einstein condensation, and supersolidity. These states display quantum mechanical behaviours at scales much larger than atomic dimensions.…

Statistical Mechanics · Physics 2007-05-23 Gregory P. Bewley , Daniel P. Lathrop , Katepalli R. Sreenivasan

We present Monte Carlo simulation results on the equilibrium relaxation of the two dimensional lattice Coulomb gas with fractional charges, which exhibits a close analogy to the primary relaxation of fragile supercooled liquids. Single…

Statistical Mechanics · Physics 2007-05-23 S. J. Lee , B. Kim , J. -R. Lee

The Stokes-Einstein relation for the self-diffusion coefficient of a spherical particle suspended in an incompressible fluid is an asymptotic result in the limit of large Schmidt number, that is, when momentum diffuses much faster than the…

Soft Condensed Matter · Physics 2015-06-17 F. Balboa Usabiaga , X. Xie , R. Delgado-Buscalioni , A. Donev

The Stokes-Einstein (SE) relation has been widely applied to quantitatively describe the Brownian motion. Notwithstanding, here we show that even for a simple fluid, the SE relation may not be completely applicable. Namely, although the SE…

Statistical Mechanics · Physics 2021-03-17 Hanqing Zhao , Hong Zhao

We investigate the origin of the Stokes-Einstein relation in liquids. The hard-sphere dynamics is analyzed using a new measure of structural relaxation - the minimum Euclidean distance between configurations of particles. It is shown that…

Soft Condensed Matter · Physics 2007-05-23 Tomas Oppelstrup , Babak Sadigh , Srikanth Sastry , Mikhail Dzugutov

Among the numerous anomalies of water, the acceleration of dynamics under pressure is particularly puzzling. Whereas the diffusivity anomaly observed in experiments has been reproduced in several computer studies, the parallel viscosity…

We report shear viscosity of heavy water supercooled $33\,\mathrm{K}$ below its melting point, revealing a 15-fold increase compared to room temperature. We also confirm our previous data for the viscosity of supercooled light water, and…

Chemical Physics · Physics 2023-09-19 Pierre Ragueneau , Frédéric Caupin , Bruno Issenmann

In simulations of supercooled, high-density liquid silica we study a range of temperature T in which we find both crystal nucleation, as well as the characteristic dynamics of a glass forming liquid, including a breakdown of the…

Materials Science · Physics 2015-05-14 Ivan Saika-Voivod , Richard K. Bowles , Peter H. Poole

We study the transport and the relaxation properties of a molecular supercooled liquid by molecular-dynamics numerical simulations. The focus is on the translational motion. Jump motion is detected. At lower temperature the Stokes-Einstein…

Statistical Mechanics · Physics 2007-05-23 Cristiano De Michele , Dino Leporini

It is demonstrated that self-diffusion and shear viscosity data for the TIP4P/Ice water model reported recently [L. Baran, W. Rzysko and L. MacDowell, J. Chem. Phys. {\bf 158}, 064503 (2023)] obey the microscopic version of the…

Statistical Mechanics · Physics 2023-08-02 Sergay Khrapak , Alexey Khrapak

We review the effect of water anomalies on the properties of low temperature water. When supercooled, liquids dynamical properties change drastically. Supercooled liquids undergo an at least exponential decrease of their diffusion…

Soft Condensed Matter · Physics 2020-01-14 V. Teboul , A. P. Kerasidou

Within mean field Gross-Pitaevskii framework, ultra cold atomic condensates with long range interaction is predicted to have a supersolid like ground state beyond a critical interaction strength. Such mean field supersolid like ground state…

Quantum Gases · Physics 2015-04-17 Rashi Sachdeva , Sankalpa Ghosh

We investigate the behavior of a one-dimensional diatomic fluid under a shock wave excitation. We find that the properties of the resulting shock wave are in striking contrast with those predicted by hydrodynamic and kinetic approaches,…

Statistical Mechanics · Physics 2009-11-11 Pablo I. Hurtado

The Stokes-Einstein-Sutherland (SES) equation is at the foundation of statistical physics, relating a particle's diffusion coefficient and size with the fluid viscosity, temperature and the boundary condition for the particle-solvent…

We investigate the dimensional dependence of dynamical fluctuations related to dynamic heterogeneity in supercooled liquid systems using kinetically constrained models. The $d$-dimensional spin-facilitated East model with embedded probe…

Statistical Mechanics · Physics 2017-09-13 Soree Kim , Dayton G. Thorpe , Juan P. Garrahan , David Chandler , YounJoon Jung

In this paper we present predictions for thermodynamic and transport properties of a BCS Bose-Einstein crossover theory, below Tc, which theory satisfies the reasonable constraints that it yield (i) the Leggett ground state and (ii) BCS…

Superconductivity · Physics 2007-05-23 Qijin Chen , Ioan Kosztin , K. Levin

We study the relaxation dynamics of a binary Lennard-Jones liquid in the presence of an amorphous wall generated from equilibrium particle configurations. In qualitative agreement with the results presented in Nature Phys. {\bf 8}, 164…

Statistical Mechanics · Physics 2014-06-16 Glen M Hocky , Ludovic Berthier , Walter Kob , David R. Reichman

In the supercooled regime at elevated pressure two forms of liquid water, high-density (HDL) and low-density (LDL), have been proposed to be separated by a coexistence line ending at a critical point, but a connection to ambient conditions…

Soft Condensed Matter · Physics 2011-06-27 K. T. Wikfeldt , A. Nilsson , L. G. M. Pettersson

One of water's unsolved puzzles is the question of what determines the lowest temperature to which it can be cooled before freezing to ice. The supercooled liquid has been probed experimentally to near the homogeneous nucleation temperature…

Soft Condensed Matter · Physics 2011-12-08 Emily B. Moore , Valeria Molinero