Related papers: Studying Thermodynamics of Metastable States
Using two extremely different models of glass formers in two and three dimensions we demonstrate how to encode the subtle changes in the geometric rearrangement of particles during the scenario of the glass transition. We construct a…
In this note we discuss metastability in a long-but-finite range disordered model for the glass transition. We show that relaxation is dominated by configuration belonging to metastable states and associate an in principle computable…
Thermodynamic phase transitions, a central concept in physics and chemistry, are typically controlled by an interplay of enthalpic and entropic contributions. In most cases, the estimation of the enthalpy in simulations is straightforward…
The optimization problems defining meta-stable or stationary equilibrium are explored. The Gibbs scheme is modified aiming to describe the statistical properties of a class of non-equilibrium and metastable states. The system is assumed to…
The metastable states of a glass are counted by adding a weak pinning field which explicitly breaks the ergodicity. Their entropy, that is the logarithm of their number, is extensive in a range of temperatures $T_G < T < T_C$ only, where…
We investigate the non-equilibrium dynamics of the bosonic Hubbard model starting from inhomogeneous superfluid or Mott insulator initial states using the truncated Wigner approximation (TWA). We find that the relaxation of the system…
The thermodynamics of the dissipative two-state system is calculated exactly for all temperatures and level asymmetries for the case of Ohmic dissipation. We exploit the equivalence of the two-state system to the anisotropic Kondo model and…
A phase transformation in a metastable phase can be affected when it is subjected to a high intensity ultrasound wave. In this study we determined the effect of oscillation in pressure and temperature on a phase transformation using the…
Langer theory of metastability provides a description of the lifetime and properties of the metastable phase of the Ising model field-driven transition, describing the magnetic field-driven transition in ferromagnets and the chemical…
The time evolution of a homogeneous bidisperse granular suspension is studied in the context of the Enskog kinetic equation. The influence of the surrounding viscous gas on the solid particles is modeled via a deterministic viscous drag…
When a liquid melt is cooled, a glass or phase transition can be obtained depending on the cooling rate. Yet, this behavior has not been clearly captured in energy landscape models. Here a model is provided in which two key ingredients are…
Predictions of relative stabilities of (competing) molecular crystals are of great technological relevance, most notably for the pharmaceutical industry. However, they present a long-standing challenge for modeling, as often minuscule free…
Customarily, crystalline solids are defined to be {\em rigid} since they resist changes of shape determined by their boundaries. However, rigid solids cannot exist in the thermodynamic limit where boundaries become irrelevant. Particles in…
Metastable quantum dynamics of an asymmetric triangular cluster that is coupled to a reservoir is investigated. The dynamics is governed by bath-mediated transitions, which in part require a thermal activation process. The decay rate is…
Nonequilibrium steady state of isothermal biochemical cycle kinetics has been extensively studied, but much less investigated under non-isothermal conditions. However, once the heat exchange between subsystems is rather slow, the isothermal…
Applying the time-dependent Ginzburg-Landau equations, transitions between metastable states of a superconducting ring are investigated in the presence of an external magnetic field. It is shown that if the ring exhibits several metastable…
Equations that govern the temperature-dependence of the rate constants, Gibbs energies,enthalpies, entropies and heat capacities of activation for folding and unfolding of spontaneously-folding fixed two-state systems have been derived…
Temperature plays a crucial role in metastable phenomena, not only by contributing to determine the state (phase) of a system, but also ruling the decay probability to more stable states. Such a situation is encountered in many different…
Rate- and state-dependent friction law for velocity-step tests is analyzed from a thermodynamic point of view. A simple macroscopic non-equilibrium thermodynamic model with a single internal variable reproduces instantaneous jump and…
We discuss the physical basis of the statistical mechanics of self-gravitating systems. We show the correspondance between statistical mechanics methods based on the evaluation of the density of states and partition function and…