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Related papers: Thermodynamic Entropy and Chaos in a Discrete Hydr…

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Boltzmann defined the entropy of a macroscopic system in a macrostate $M$ as the $\log$ of the volume of phase space (number of microstates) corresponding to $M$. This agrees with the thermodynamic entropy of Clausius when $M$ specifies the…

Statistical Mechanics · Physics 2009-11-10 S. Goldstein , Joel L. Lebowitz

The evolution of entropy is derived with respect to dynamical systems. For a stochastic system, its relative entropy $D$ evolves in accordance with the second law of thermodynamics; its absolute entropy $H$ may also be so, provided that the…

Chaotic Dynamics · Physics 2010-08-31 X. San Liang

We show that macroscopic irreversible thermodynamics for viscous fluids can be derived from exact information-theoretic thermodynamic identities valid at the microscale. Entropy production, in particular, is a measure of the loss of…

Statistical Mechanics · Physics 2025-02-17 Danilo Forastiere , Francesco Avanzini , Massimiliano Esposito

Comparison of the thermodynamic entropy with Boltzmann's principle shows that under conditions of constant volume the total number of arrangements in simple thermodynamic systems with temperature-independent heat capacities is TC/k. A…

General Physics · Physics 2009-11-13 David Sands

We investigate, via computer simulations, the time evolution of the (Boltzmann) entropy of a dense fluid not in local equilibrium. The macrovariables $M$ describing the system are the (empirical) particle density $f=\{f(\un{x},\un{v})\}$…

Statistical Mechanics · Physics 2009-11-10 P. L. Garrido , S. Goldstein , J. L. Lebowitz

This paper presents an {\it ab initio} derivation of the expression given by irreversible thermodynamics for the rate of entropy production for different classes of diffusive processes. The first class are Lorentz gases, where…

Chaotic Dynamics · Physics 2009-11-07 J. R. Dorfman , P. Gaspard , T. Gilbert

The thermodynamic formalism expresses chaotic properties of dynamical systems in terms of the Ruelle pressure $\psi(\beta)$. The inverse-temperature like variable $\beta$ allows one to scan the structure of the probability distribution in…

chao-dyn · Physics 2017-09-20 C. Appert , H. van Beijeren , M. H. Ernst , J. R. Dorfman

We derive a large-scale hydrodynamic equation, including diffusive and dissipative effects, for systems with generic static position-dependent driving forces coupling to local conserved quantities. We show that this equation predicts…

Statistical Mechanics · Physics 2021-12-10 Joseph Durnin , Andrea De Luca , Jacopo De Nardis , Benjamin Doyon

The standard Large Deviation Theory (LDT) mirrors the Boltzmann-Gibbs (BG) factor which describes the thermal equilibrium of short-range Hamiltonian systems, the velocity distribution of which is Maxwellian. It is generically applicable to…

General Physics · Physics 2022-02-03 Ugur Tirnakli , Mauricio Marques , Constantino Tsallis

Boltzmann-Sanov and Cramer-Chernoff's theorems provide large deviation probabilities, entropy, and rate functions for the spatial distribution of systems and the total internal energy of an ensemble respectively. By the method of Lagrange's…

Statistical Mechanics · Physics 2021-09-17 D. P. Shinde

An explicit relation between the dimensional loss ($\Delta D$), entropy production and transport is established under thermal gradients, relating the microscopic and macroscopic behaviors of the system. The extensivity of $\Delta D$ in…

Chaotic Dynamics · Physics 2007-05-23 Kenichiro Aoki , Dimitri Kusnezov

We discuss the form of the entropy for classical hamiltonian systems with long-range interaction using the Vlasov equation which describes the dynamics of a $N$-particle in the limit $N\to\infty$. The stationary states of the hamiltonian…

Statistical Mechanics · Physics 2007-05-23 T. M. Rocha Filho , A. Figueiredo , M. A. Amato

We study the probability densities of finite-time or \local Lyapunov exponents (LLEs) in low-dimensional chaotic systems. While the multifractal formalism describes how these densities behave in the asymptotic or long-time limit, there are…

chao-dyn · Physics 2009-10-31 Awadhesh Prasad , Ramakrishna Ramaswamy

The entropic lattice Boltzmann framework proposed the construction of the discrete equilibrium by taking into consideration minimization of a discrete entropy functional. The effect of this form of the discrete equilibrium on properties of…

Fluid Dynamics · Physics 2023-03-16 S. A. Hosseini , I. V. Karlin

The issue of the thermodynamics of a system of distinguishable particles is discussed in this paper. In constructing the statistical mechanics of distinguishable particles from the definition of Boltzmann entropy, it is found that the…

Chemical Physics · Physics 2009-12-03 Chi-Ho Cheng

Based on a cocycle structure, we identify a new derivation of the Boltzmann distribution for finite energy-level systems from the maximal entropy principle (MEP). Our approach does not rely on the method of the Lagrange multiplier, and it…

Statistical Mechanics · Physics 2025-12-30 Chuan-Tsung Chan , Chan-Yi Chang , Zhong-Tang Wu

A statistical thermodynamic approach of moving particles forming an elastic body is presented which leads to reveal molecular-mechanical properties of classical and nonextensive dynamical systems. We derive the Boltzmann-Gibbs (BG) entropy…

Statistical Mechanics · Physics 2009-11-10 Enrique Canessa

We investigate the behavior of the Gibbs-Shannon entropy of the stationary nonequilibrium measure describing a one-dimensional lattice gas, of L sites, with symmetric exclusion dynamics and in contact with particle reservoirs at different…

Statistical Mechanics · Physics 2015-05-13 B. Derrida , J. L. Lebowitz , E. R. Speer

As recently manifested , the quench dynamics of isolated quantum systems consisting of a finite number of particles, is characterized by an exponential spreading of wave packets in the many-body Hilbert space. This happens when the…

Chaotic Dynamics · Physics 2020-03-23 Samy Mailoud , Fausto Borgonovi , Felix Izrailev

We consider an isolated system in an arbitrary state and provide a general formulation using first principles for an additive and non-negative statistical quantity that is shown to reproduce the equilibrium thermodynamic entropy of the…

Chemical Physics · Physics 2013-04-18 P. D. Gujrati
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