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This article traces the development of fluctuation theory and its deep connection to irreversibility, from equilibrium to near-equilibrium, and finally to far-from-equilibrium systems. Classical fluctuation theorems, which capture the…

Quantum Physics · Physics 2025-12-30 Sounak Bandyopadhyay , Arnab Ghosh

Turbulent flows are out-of-equilibrium because the energy supply at large scales and its dissipation by viscosity at small scales create a net transfer of energy among all scales. Here, the energy cascade is approximated by a combined…

Fluid Dynamics · Physics 2021-01-11 Amilcare Porporato , Milad Hooshyar , Andrew D Bragg , Gabriel Katul

We show, in two different ways, that the Tsallis' partition function and its derivatives are related to thermodynamic quantities such as entropy, internal energy, etc., in the same way as in Boltzmann-Gibbs' formalism, with the Lagrange…

Statistical Mechanics · Physics 2007-05-23 F. Q. Potiguar , U. M. S. Costa

Traditionally, it is understood that fluctuations in the equilibrium distribution are not evident in thermodynamic systems of large $N$ (the number of particles in the system) \cite{Huang1}. In this paper we examine the validity of this…

Mathematical Physics · Physics 2007-10-03 Kieran Kelly , Przemysław Repetowicz , Seosamh macRéamoinn

The laws of thermodynamics provide a clear concept of the temperature for an equilibrium system in the continuum limit. Meanwhile, the equipartition theorem allows one to make a connection between the ensemble average of the kinetic energy…

Statistical Mechanics · Physics 2009-11-13 Alex V. Popov , Rigoberto Hernandez

The applicability of stochastic differential equations to thermodynamics is considered and a new form, different from the classical Ito and Stratonovich forms, is introduced. It is shown that the new presentation is more appropriate for the…

Statistical Mechanics · Physics 2015-06-05 R. Tsekov

The thermodynamics for a system with given temperature, density, and volume is described by the Canonical ensemble. The thermodynamics for a corresponding system with the same temperature, volume, and average density is described by the…

Statistical Mechanics · Physics 2016-01-12 Debajit Chakraborty , James Dufty , Valentin V. Karasiev

A formula to calculate the quantum fluctuations of energy in small subsystems of a hot and relativistic gas is derived. We find an increase in fluctuations for subsystems of small sizes, but we agrees with the energy fluctuations in the…

Nuclear Theory · Physics 2021-10-08 Rajeev Singh

We revisit stochastic thermodynamics for a system with discrete energy states in contact with a heat and particle reservoir.

Statistical Mechanics · Physics 2015-06-19 Christian Van den Broeck , Massimiliano Esposito

In phenomenological thermodynamics, the canonical coordinates of a physical system split in pairs with each pair consisting of an extensive quantity and an intensive one. In the present paper, the quasi-thermodynamic fluctuation theory of a…

Mathematical Physics · Physics 2013-11-13 Artur E. Ruuge

We propose a generalization of stochastic thermodynamics to systems of active particles, which move under the combined influence of stochastic internal self-propulsions (activity) and a heat bath. The main idea is to consider joint…

Soft Condensed Matter · Physics 2019-11-20 Grzegorz Szamel

The explicit thermodynamic functions, in particular, the specific heat of a spin system interacting with a spin bath which exerts finite dissipation on the system are determined. We show that the specific heat is a sum of the products of a…

Quantum Physics · Physics 2013-04-29 Sudarson Sekhar Sinha , Arnab Ghosh , Deb Shankar Ray

Stochastic thermodynamics as reviewed here systematically provides a framework for extending the notions of classical thermodynamics like work, heat and entropy production to the level of individual trajectories of well-defined…

Statistical Mechanics · Physics 2015-06-05 Udo Seifert

We consider a situation where an $N$-level system (NLS) is coupled successively to two heat baths with different temperatures without being necessarily thermalized and approaches a steady state. For this situation we apply a general…

Statistical Mechanics · Physics 2021-08-09 Heinz-Jürgen Schmidt , Jochen Gemmer

In an attempt to derive thermodynamics from classical mechanics, an approximate expression for the equilibrium temperature of a finite system has been derived [M. Bianucci, R. Mannella, B. J. West, and P. Grigolini, Phys. Rev. E 51, 3002…

Statistical Mechanics · Physics 2015-06-24 Artur B. Adib

Thermal fluctuations constantly and evenly excite all vibrational modes in an equilibrium crystal. As the temperature rises, these fluctuations promote the formation of defects and eventually melting. In active solids, the self-propulsion…

Soft Condensed Matter · Physics 2024-09-25 Helena Massana-Cid , Claudio Maggi , Nicoletta Gnan , Giacomo Frangipane , Roberto Di Leonardo

The nonequilibrium fluctuation relation is a cornerstone of quantum thermodynamics. It is widely believed that the system-bath heat exchange obeys the famous Jarzynski-W\'{o}jcik fluctuation theorem. However, this theorem is established in…

Quantum Physics · Physics 2024-08-01 Wei Wu , Jun-Hong An

We review a series of experimental studies of the thermodynamics of nonequilibrium processes at the microscale. In particular, in these experiments we studied the fluctuations of the thermodynamic properties of a single optically-trapped…

Statistical Mechanics · Physics 2016-06-22 L. Dinis , I. A. Martínez , É. Roldán , J. M. R. Parrondo , R. A. Rica

Stochastic thermodynamics is a framework for describing non-equilibrium processes at the level of fluctuating trajectories, where the state of a system evolves as a stochastic time series, allowing thermodynamic quantities such as work,…

The thermodynamics of small quantum many-body systems strongly coupled to a heat bath at low temperatures with non-Markovian behavior are new challenges for quantum thermodynamics, as traditional thermodynamics is built on large systems…

Quantum Physics · Physics 2019-04-23 Jen-Tsung Hsiang , B. L. Hu