Related papers: Thermodynamic fluctuation relation for temperature…
Thermodynamic fluctuation theory originated with Einstein who inverted the relation $S=k_B\ln\Omega$ to express the number of states in terms of entropy: $\Omega= \exp(S/k_B)$. The theory's Gaussian approximation is discussed in most…
Traditional thermodynamics governs the behaviour of large systems that evolve between states of thermal equilibrium. For these large systems, the mean values of thermodynamic quantities (such as work, heat and entropy) provide a good…
In a recent paper [P. Strasberg and M. Esposito, Phys. Rev. E {\bf 101}, 050101(R) (2020)] an attempt is presented to formulate the nonequilibrium thermodynamics of an open system in terms of the Hamiltonian of mean force. The purpose of…
A thermodynamic-like formalism is developed for superstatistical systems based on conditional entropies. This theory takes into account large-scale variations of intensive variables of systems in nonequilibrium stationary states. Ordinary…
We analyze the microscopic evolution of a system undergoing a far-from-equilibrium thermodynamic process. Explicitly accounting for the degrees of freedom of participating heat reservoirs, we derive a hybrid result, similar in form to both…
This article is the first in a series dealing with the thermodynamic properties of quantum Coulomb systems. In this first part, we consider a general real-valued function $E$ defined on all bounded open sets of $\R^3$. Our aim is to give…
We establish an analytical criterion for dynamical thermalization within harmonic systems, applicable to both classical and quantum models. Specifically, we prove that thermalization of various observables, such as particle energies in…
The characteristic function for heat fluctuations in a non equilibrium system is characterised by a large deviation function whose symmetry gives rise to a fluctuation theorem. In equilibrium the large deviation function vanishes and the…
At the very foundation of the second law of thermodynamics lies the fact that no heat engine operating between two reservoires of temperatures $T_C\leq T_H$ can overperform the ideal Carnot engine: $\langle W \rangle / \langle Q_H \rangle…
Stochastic thermodynamics extends the notions and relations of classical thermodynamics to small systems that experience strong fluctuations. The definitions of work and heat and the microscopically reversible condition are two key concepts…
When making the connection between the thermodynamics of irreversible processes and the theory of stochastic processes through the fluctuation-dissipation theorem, it is necessary to invoke a postulate of the Einstein-Boltzmann type. For…
We investigate the emergence of temperature $T$ in the system-plus-reservoir paradigm starting from the fundamental microcanonical scenario at total fixed energy $E$ where, contrary to the canonical approach, $T=T(E)$ is not a control…
Based on the view that thermal equilibrium should be characterized through macroscopic observations, we develop a general theory about typicality of thermal equilibrium and the approach to thermal equilibrium in macroscopic quantum systems.…
Thermodynamic length is a path function that generalizes the notion of length to the surface of thermodynamic states. Here, we show how to measure thermodynamic length in far-from-equilibrium single molecule experiments using the work…
For fluctuating currents in non-equilibrium steady states, the recently discovered thermodynamic uncertainty relation expresses a fundamental relation between their variance and the overall entropic cost associated with the driving. We show…
The thermodynamical properties of a generalized Dicke model are calculated and related with the critical properties of its energy spectrum, namely the quantum phase transitions (QPT) and excited state quantum phase transitions (ESQPT). The…
The effect of the Berendsen thermostat on the dynamical properties of bulk SPC/E water is tested by generating power spectra associated with fluctuations in various observables. The Berendsen thermostat is found to be very effective in…
We derive a general quantum exchange fluctuation theorem for multipartite systems with arbitrary coupling strengths by taking into account the informational contribution of the back-action of the quantum measurements, which contributes to…
The nonzero ground-state energy of the quantum mechanical harmonic oscillator implies quantum fluctuations around the minimum of the potential with the mean square value proportional to Planck's constant. In classical mechanics thermal…
We show how to use a central limit approximation for additive co-cycles to describe non-equilibrium and far from equilibrium thermodynamic behavior. We consider first two weakly coupled Hamiltonian dynamical systems initially at different…