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The statistical mechanical description of small systems staying in thermal equilibrium with an environment can be achieved by means of the Hamiltonian of mean force. In contrast to the reduced density matrix of an open quantum system, or…

Statistical Mechanics · Physics 2020-10-28 Peter Talkner , Peter Hänggi

We use quantum estimation theory to derive a thermodynamic uncertainty relation in Markovian open quantum systems, which bounds the fluctuation of continuous measurements. The derived quantum thermodynamic uncertainty relation holds for…

Statistical Mechanics · Physics 2020-07-30 Yoshihiko Hasegawa

According to the recently obtained thermodynamic uncertainty relation, the microcanonical regions with a negative heat capacity can be accessed within a canonical-like description by using a thermostat with a fluctuating inverse…

Statistical Mechanics · Physics 2007-05-23 L. Velazquez

We derive a formula that defines quantum fluctuations of energy in subsystems of a hot relativistic gas. For small subsystem sizes we find substantial increase of fluctuations compared to those known from standard thermodynamic…

High Energy Physics - Phenomenology · Physics 2021-12-15 Arpan Das , Wojciech Florkowski , Radoslaw Ryblewski , Rajeev Singh

Gibbs and Boltzmann definitions of temperature agree only in the macroscopic limit. The ambiguity in identifying the equilibrium temperature of a finite sized `small' system exchanging energy with a bath is usually understood as a…

Biological Physics · Physics 2015-03-09 Purushottam D. Dixit

We present a fluctuation relation for heat dissipation in a nonequilibrium system. A nonequilibrium work is known to obey the fluctuation theorem in any time interval $t$. A heat, which differs from a work by an energy change, is shown to…

Statistical Mechanics · Physics 2012-06-19 Jae Dong Noh , Jong-Min Park

The microcanonical ensemble has long been a starting point for the development of thermodynamics from statistical mechanics. However, this approach presents two problems. First, it predicts that the entropy is only defined on a discrete set…

Statistical Mechanics · Physics 2017-06-07 William Griffin , Michael Matty , Robert H. Swendsen

Equilibrium statistics of finite Hamiltonian systems is fundamentally described by the microcanonical ensemble (ME). Canonical, or grand-canonical partition functions are deduced from this by Laplace transform. Only in the thermodynamic…

Nuclear Theory · Physics 2008-11-26 D. H. E. Gross

A general fluctuational-electrodynamic theory is developed to investigate radiative heat exchanges between objects which are assumed small compared with their thermal wavelength (dipolar approximation) in N-body systems immersed in a…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Riccardo Messina , Maria Tschikin , Svend-Age Biehs , Philippe Ben-Abdallah

The grand canonical ensemble lies at the core of quantum and classical statistical mechanics. A small system thermalizes to this ensemble while exchanging heat and particles with a bath. A quantum system may exchange quantities represented…

Quantum Physics · Physics 2016-07-25 Nicole Yunger Halpern , Philippe Faist , Jonathan Oppenheim , Andreas Winter

A fluctuation relation for heat engines (FRHE) has been derived recently. In the beginning, the system is in contact with the cooler bath. The system is then coupled to the hotter bath and external parameters are changed cyclically,…

Statistical Mechanics · Physics 2015-06-05 Sourabh Lahiri , Shubhashis Rana , A. M. Jayannavar

The canonical ensemble plays a crucial role in statistical mechanics in and out of equilibrium. For example, the standard derivation of the fluctuation theorem relies on the assumption that the initial state of the heat bath is the…

Statistical Mechanics · Physics 2022-04-20 Eiki Iyoda , Kazuya Kaneko , Takahiro Sagawa

We review the general aspects of the concept of temperature in equilibrium and non-equilibrium statistical mechanics. Although temperature is an old and well-established notion, it still presents controversial facets. After a short…

Statistical Mechanics · Physics 2017-11-13 A. Puglisi , A. Sarracino , A. Vulpiani

Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble. Classically this is the manifold of all points in the N-body phase space with the given total energy. Due to Boltzmann's principle,…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble. Classically this is the manifold of all points in the $N-$body phase space with the given total energy. Due to Boltzmann's principle,…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

We study the thermodynamics of ultrasmall metallic grains with level spacing $\delta$ comparable or smaller than the pairing correlation energy, at finite temperatures, $T \gsim \delta$. We describe a method which allows to find quantum…

Superconductivity · Physics 2007-05-23 G. Falci , A. Fubini

Classical thermodynamics is unrivalled in its range of applications and relevance to everyday life. It enables a description of complex systems, made up of microscopic particles, in terms of a small number of macroscopic quantities, such as…

Quantum Physics · Physics 2016-01-13 James Millen , André Xuereb

In this review paper, we discuss the statistical description in non-equilibrium regimes of energy fluctuations originated by the interaction between a quantum system and a measurement apparatus applying a sequence of repeated quantum…

A few decades after Hill's work on nano-thermodynamics, the development of a thermodynamic framework, to account consistently for the fluctuations of small systems due to their interactions with the surrounding environment, is still…

Statistical Mechanics · Physics 2019-09-23 Salvatore Calabrese , Lamberto Rondoni , Amilcare Porporato

We consider a quantum system with $N$ degrees of freedom which is classically chaotic. When $N$ is large, and both $\hbar$ and the quantum energy uncertainty $\Delta E$ are small, quantum chaos theory can be used to demonstrate the…

chao-dyn · Physics 2009-10-28 Mark Srednicki