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CO adsorption on the Pt(111) surface is studied using first-principles methods. As found in a recent study [Feibelman, et al., J. Phys. Chem. B 105, 4018 (2001)], we find the preferred adsorption site within density functional theory to be…

Materials Science · Physics 2009-11-07 Ilya Grinberg , Yashar Yourdshahyan , Andrew M. Rappe

Multi-component alloys offer broad tunability for addressing challenges in materials science, but their vast configurational space makes their surface chemistry highly sensitive to operating conditions, for example through adsorption and…

Materials Science · Physics 2026-03-03 Pernilla Ekborg-Tanner , Paul Erhart

We present ab initio local-density-functional electronic structure calculations for the (111) and (-1-1-1) surfaces of cubic BN. The energetically stable reconstructions, namely the N adatom, N3 triangle models on the (111), the (2x1),…

Materials Science · Physics 2009-10-31 Krisztina Kadas , Georg Kern , Jurgen Hafner

Using scanning tunneling microscopy together with the first-principles density functional theory calculations we study structural properties of the Si(111)5x2-Au surface covered by Ag adatoms. The STM topography data show that a…

Mesoscale and Nanoscale Physics · Physics 2014-10-09 A. Stepniak , M. Krawiec , M. Jalochowski

Abnormally large stability of Pb nanostructures grown on metallic or semiconductor substrates has been observed even for heights of about 30 monolayers. Using both density-functional theory calculations and analytical models, we demonstrate…

Materials Science · Physics 2024-02-13 A. Ayuela , E. Ogando , N. Zabala

The binary (simple metal) phase diagram Au-Cd contains a number of intermetallic compounds with various distortions, superlattices and vacancies. To understand the reasons of these structural complexities and their phase stability, we…

Materials Science · Physics 2015-10-28 Valentina F. Degtyareva , Nataliya S. Afonikova

Diverse magnetic and electronic properties of halogen-adsorbed silicene are investigated by the first-principles theoretical framework, including the adatom-diversified geometric structures, the atom-dominated energy bands, the spatial spin…

Materials Science · Physics 2019-03-27 Duy Khanh Nguyen , Ngoc Thanh Thuy Tran , Yu-Huang Chiu , Ming-Fa Lin

The system of an iron phthalocyanine molecule on the Au(111) surface, has been studied recently due to its peculiar properties. In particular, several surprising results of scanning tunneling spectroscopy changing the position of the…

Strongly Correlated Electrons · Physics 2022-05-19 A. A. Aligia

Surfaces are at the frontier of every known solid. They provide versatile supports for functional nanostructures and mediate essential physicochemical processes. Being intimately related with 2D materials, interfaces and atomically thin…

We have carried out a density functional study of unoccupied, resonance states in a single Au atom, dimers, a trimer and infinite Au chains on the NiAl(110) surface. Two inequivalent orientations of the ad-chains with substantially…

Materials Science · Physics 2009-11-10 M. Persson

Stable organic radicals serve as model systems for investigating metal-free magnetic phenomena at (sub)nanometer length scales. We have investigated at the single-molecule level the stable $\pi$-radical 2,2-diphenyl-1-picrylhydrazyl (DPPH)…

Instrumentation and Detectors · Physics 2021-01-13 Radovan Vranik , Vitalii Stetsovych , Simon Feigl , Stefan Müllegger

Ab initio total-energy density-functional methods with supercell models have been employed to calculate the c(2x2) structure of the Br-adsorbed Ag(100) and Au(100) surfaces. The atomic geometries of the surfaces and the preferred bonding…

Materials Science · Physics 2016-08-31 Sanwu Wang , Per Arne Rikvold

Functional properties of nanomaterials strongly depend on their surface atomic structure, but they often become largely different from their bulk structure, exhibiting surface reconstructions and relaxations. However, most of the surface…

Materials Science · Physics 2021-10-01 Juhyeok Lee , Chaehwa Jeong , Yongsoo Yang

We study the electronic structure of the chiral semimetal PdGa by means of the de Haas-van Alphen and Shubnikov-de Haas effect. We find that the Fermi surface of PdGa comprises multiple pockets split by spin-orbit coupling. We compare our…

Strongly Correlated Electrons · Physics 2025-04-18 Nico Huber , Ivan Volkau , Alexander Engelhardt , Ilya Sheikin , Andreas Bauer , Christian Pfleiderer , Marc A. Wilde

The adsorption of C60 on Si(111) has been studied by means of first-principles density functional calculations. A 2x2 adatom surface reconstruction was used to simulate the terraces of the 7x7 reconstruction. The structure of several…

Using density-functional-theory we study the electronic and structural properties of a monolayer of Cu on the fcc (100) and (111) surfaces of the late 4d transition metals, as well as a monolayer of Pd on Mo bcc(110). We calculate the…

P-wave interaction in cold atoms may give rise to exotic topological superfluids. However, the realization of p-wave interaction in cold atom system is experimentally challenging. Here we propose a simple scheme to synthesize effective…

Quantum Gases · Physics 2016-03-31 Bin Wang , Zhen Zheng , Han Pu , Xubo Zou , Guangcan Guo

The (111) surface of CaF$_2$ has been intensively studied with large-amplitude frequency-modulation atomic force microscopy and atomic contrast formation is now well understood. It has been shown that the apparent contrast patterns obtained…

Materials Science · Physics 2007-05-23 Franz J. Giessibl , Michael Reichling

We present a detailed appraisal of the optical and plasmonic properties of ordered alloys of the form Au$_{x}$Ag$_{y}$Cu$_{1-x-y}$, as predicted by means of first-principles many-body perturbation theory augmented by a semi-empirical…

Materials Science · Physics 2019-09-04 Okan K. Orhan , David D. O'Regan

The nucleation, distribution, composition and structure of Pd nanocrystals in SiO$_2$ multilayers containing Ge, Si, and Pd are studied using High Resolution Transmission Electron Microscopy (HRTEM) and X-ray Photoelectron Spectroscopy…