Related papers: Dynamic first-order phase transition in kineticall…
We investigate the dynamics of kinetically constrained models of glass formers by analysing the statistics of trajectories of the dynamics, or histories, using large deviation function methods. We show that, in general, these models exhibit…
We perform extensive numerical simulations of a paradigmatic model glass former, the hard-sphere fluid with 10% polydispersity. We sample from the ensemble of trajectories with fixed observation time, whereby single trajectories are…
We generalize the simplest kinetically constrained model of a glass-forming liquid by softening kinetic constraints, allowing them to be violated with a small finite rate. We demonstrate that this model supports a first-order dynamical…
In this chapter we summarize recent developments in the study of kinetically constrained models (KCMs) as models for glass formers. After recalling the definition of the KCMs which we cover we study the possible occurrence of ergodicity…
On the example of a mean-field Fredrickson-Andersen kinetically constrained model, we focus on the known property that equilibrium dynamics take place at a first-order dynamical phase transition point in the space of time-realizations. We…
The East model has a dynamical phase transition between an active (fluid) and inactive (glass) state. We show that this phase transition generalizes to "softened" systems where constraint violations are allowed with small but finite…
We find that a Lennard-Jones mixture displays a dynamic phase transition between an active regime and an inactive one. By means of molecular dynamics simulations and of a finite-size study, we show that the space time dynamics in the…
Kinetically constrained models (KCMs) have been used to study and understand the origin of glassy dynamics. Despite having trivial thermodynamic properties, their dynamics slows down dramatically at low temperatures while displaying…
The physics of highly excited Rydberg atoms is governed by blockade or exclusion interactions that hinder the excitation of atoms in the proximity of a previously excited one. This leads to cooperative effects and a relaxation dynamics…
We show how dynamical heterogeneities in glass forming systems emerge as a consequence of the existence of dynamical constraints, and we offer an interpretation of the glass transition as an entropy crisis in trajectory space (space-time)…
We study large deviations of the dynamical activity in the random orthogonal model (ROM). This is a fully connected spin-glass model with one-step replica symmetry breaking behaviour, consistent with the random first-order transition…
Dynamic facilitation theory assumes short-ranged dynamic constraints to be the essential feature of supercooled liquids and draws much of its conclusions from the study of kinetically constrained models. While deceptively simple, these…
In a recent article [M. Merolle et al., Proc. Natl. Acad. Sci. USA 102, 10837 (2005)] it was argued that dynamic heterogeneity in $d$-dimensional glass formers is a manifestation of an order-disorder phenomenon in the $d+1$ dimensions of…
The short- and long-time dynamics of model systems undergoing a glass transition with apparent inversion of Kauzmann and dynamical arrest glass transition lines is investigated. These models belong to the class of the spherical mean-field…
The understanding of thermodynamic glass transition has been hindered by the lack of proper models beyond mean-field theories. Here, we propose a three-dimensional lattice glass model on a simple cubic lattice that exhibits the typical…
Kob and Andersen's simple lattice models for the dynamics of structural glasses are analyzed. Although the particles have only hard core interactions, the imposed constraint that they cannot move if surrounded by too many others causes slow…
A disordered spin model suitable for studying inverse freezing in fragile glass-forming systems is introduced. The model is a microscopic realization of the ``random-first order'' scenario in which the glass transition can be either…
There are deep analogies between the melting dynamics in systems with a first order phase transition and the dynamics from equilibrium in super-cooled liquids. For a class of Ising spin models undergoing a first order transition - namely…
We analyse a first-order dynamical phase transition that takes place in the Fredrickson--Andersen (FA) model. We construct a two-dimensional spin system whose thermodynamic properties reproduce the dynamical large deviations of the FA model…
In this paper we revisit and extend the mapping between two apparently different classes of models. The first class contains the prototypical models described --at the mean-field level-- by the Random First Order Transition (RFOT) theory of…