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Related papers: Electronic Correlations in CoO2, the Parent Compou…

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Layered Co oxide NaxCoO2.yH2O with the superconducting transition temperature Tc =4.5 K has been studied by 59Co-NMR. The Knight shift K estimated from the observed spectra for powder sample exhibits almost temperature(T)-independent…

Superconductivity · Physics 2015-06-24 Yoshiaki Kobayashi , Mai Yokoi , Masatoshi Sato

Colloidal cobalt-doped TiO2 (anatase) nanocrystals were synthesized and studied by electronic absorption, magnetic circular dichroism, transmission electron microscopy, magnetic susceptibility, cobalt K-shell X-ray absorption spectroscopy,…

Materials Science · Physics 2007-05-23 J. Daniel Bryan , Steve M. Heald , Scott A. Chambers , Daniel R. Gamelin

Studies of the NMR Knight shift K of Na0.3CoO2.yH2O have been carried out in detail. The suppression of K by the occurrence of the superconductivity reported previously by the present authors in both magnetic field directions perpendicular…

Superconductivity · Physics 2009-11-11 Yoshiaki Kobayashi , Taketo Moyoshi , Hidekazu Watanabe , Mai Yokoi , Masatoshi Sato

We report on the effect of Ni substitution at the Co site on the physical properties of NaxCoO2 system by investigating the series NaxCo1-yNiyO2 (x=0.75, 0<y<0.15). An upturn in the resistivity is observed in all Ni substituted samples as…

Strongly Correlated Electrons · Physics 2009-11-11 N. Gayathri , M. Premila , A. Bharathi , V. S. Sastry , C. S. Sundar , Y. Hariharan

The magnetic properties and structure of LixCoO2 for x between 0.5 and 1.0 are reported. Co4+ is found to be high-spin in LixCoO2 for x between 0.94 and 1.0 and low-spin for x between 0.50 and 0.78. Weak antiferromagnetic coupling is…

Strongly Correlated Electrons · Physics 2009-02-12 J. T. Hertz , Q. Huang , T. McQueen , T. Klimczuk , J. W. G. Bos , L. Viciu , R. J. Cava

It has been recently shown that under pressure trilayer Ruddlesden-Popper nickelate La$_4$Ni$_3$O$_{10}$ (LNO) becomes superconducting below a critical temperature $\sim$20 K, in addition to the infinite-layer and bilayer systems. Motivated…

Strongly Correlated Electrons · Physics 2024-06-12 I. V. Leonov

We report here the synthesis of single-phase bulk samples of CoO2, the x = 0 end member of the AxCoO2 systems (A = Li, Na), from a pristine LiCoO2 sample using an electrochemical technique to completely de-intercalate lithium. Thus,…

Strongly Correlated Electrons · Physics 2007-10-10 T. Motohashi , Y. Katsumata , T. Ono , R. Kanno , M. Karppinen , H. Yamauchi

Electronic topology in metallic kagome compounds is under intense scrutiny. We present transport experiments in Na2/3CoO2 in which the Na order differentiates a Co kagome sub-lattice in the triangular CoO2 layers. Hall and magnetoresistance…

Strongly Correlated Electrons · Physics 2021-11-09 I. F. Gilmutdinov , R. Schönemann , D. Vignolles , C. Proust , I. R. Mukhamedshin , L. Balicas , H. Alloul

We report the $^{59}$Co NMR studies of the in-plane anisotropy of bilayer hydrated Na$_{x}\mathrm{CoO_{2}} \cdot$$y\mathrm{H_{2}O}$ using a oriented powder sample by a magnetic field in Fluorinert FC70. We found for the first time the…

Superconductivity · Physics 2009-11-11 C. Michioka , Y. Itoh , H. Ohta , M. Kato , K. Yoshimura

We report a state-of-the-art photoemission (ARPES) study of high quality single crystals of the NaxCoO2 series focusing on the fine details of the low-energy states. The Fermi velocity is found to be small (< 0.5 eV.A) and only weakly…

Superconductivity · Physics 2009-11-11 D. Qian , D. Hsieh , L. Wray , A. Fedorov , D. Wu , J. L. Luo , N. L. Wang , L. Viciu , R. J. Cava , M. Z. Hasan

We report on susceptibility measurements in the strongly correlated layered cobalt oxide [BiBa0.66K0.36O2]CoO2, which demonstrate the existence of a magnetic quantum critical point (QCP) governing the electronic properties. The investigated…

Strongly Correlated Electrons · Physics 2010-07-12 P. Limelette , W. Saulquin , H. Muguerra , D. Grebille

We have investigated a set of sodium cobaltates (NaxCoO2) samples with various sodium content (0.67 \le x \le 0.75) using Nuclear Quadrupole Resonance (NQR). The four different stable phases and an intermediate one have been recognized. The…

Strongly Correlated Electrons · Physics 2014-07-07 T. A. Platova , I. R. Mukhamedshin , A. V. Dooglav , H. Alloul

The electronic structure of Sr0.35CoO2, structurally analogous to the layered NaxCoO2, has been evaluated using the local spin density approximation (LSDA). We find that evident c-dispersions appear in both the e'g and a1g Co-derived bands,…

Strongly Correlated Electrons · Physics 2007-05-23 R. J. Xiao , H. X. Yang , L. F. Xu , H. R. Zhang , Y. G. Shi , J. Q. Li

We investigate the electronic properties of Ba[Fe(1-x)Co(x)]2As2 (x =0.02, 0.04) in the lightly electron-doped regime by 59Co and 75As NMR. We demonstrate that Co doping significantly suppresses the magnetic ordering temperature to the SDW…

Superconductivity · Physics 2015-05-13 F. L. Ning , K. Ahilan , T. Imai , A. S. Sefat , R. Jin , M. A. McGuire , B. C. Sales , D. Mandrus

Engineered $Na_{0.75}CoO_2$ is considered a prime candidate to achieve high-efficiency thermoelectric systems to regenerate electricity from waste heat. In this work, three elements with outmost electronic configurations, (1) an open d…

Chemical Physics · Physics 2019-02-27 M. H. N. Assadi , S. Li , A. B. Yu

CoO has an odd number of electrons in its unit cell, and therefore is expected to be metallic. Yet, CoO is strongly insulating owing to significant electronic correlations, thus classifying it as a Mott insulator. We investigate the…

We report 59Co NMR studies on the magnetically oriented powder samples of Co-oxide superconductors NaxCoO2yH2O with Tc ~ 4.7 K. From two-dimensional powder pattern in the NMR spectrum, the ab-plane Knight shift in the normal state was…

Superconductivity · Physics 2015-06-24 M. Kato , C. Michioka , T. Waki , Y. Itoh , K. Yoshimura , K. Ishida , H. Sakurai , E. Takayama-Muromachi , K. Takada , T. Sasaki

The doping and temperature dependent optical conductivity spectra of the quasi-two-dimensional Ca_{2-x}Sr_xRuO_4 (0.0=<x=<2.0) system were investigated. In the Mott insulating state, two electron correlation-induced peaks were observed…

Strongly Correlated Electrons · Physics 2009-11-07 J. S. Lee , Y. S. Lee , T. W. Noh , S. -J. Oh , Jaejun Yu , S. Nakatsuji , H. Fukazawa , Y. Maeno

Sodium cobaltate Na_xCoO_2 as dopable strongly correlated layered material with a triangular sublattice still poses a challenging problem in condensed matter. The intriguing interplay between lattice, charge, spin and orbital degrees of…

Strongly Correlated Electrons · Physics 2014-07-22 Lewin Boehnke , Frank Lechermann

NaOsO$_{\text{3}}$ undergoes a metal-insulator transition (MIT) at 410 K, concomitant with the onset of antiferromagnetic order. The excitation spectra have been investigated through the MIT by resonant inelastic x-ray scattering (RIXS) at…

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