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We have performed photoemission studies of the electronic structure in LiC$_6$ and KC$_8$, a non-superconducting and a superconducting graphite intercalation compound, respectively. We have found that the charge transfer from the…

Superconductivity · Physics 2011-05-20 Z. -H. Pan , J. Camacho , M. H. Upton , A. V. Fedorov , C. A. Howard , M. Ellerby , T. Valla

Superconductivity in graphite intercalated compounds has been studied for more than 40 years and it is still not fully understood, despite the recent progress and the discovery of relatively high Tc superconductivity in CaC6 and YbC6.…

Superconductivity · Physics 2009-04-14 T. Valla , J. Camacho , Z-H. Pan , A. V. Fedorov , A. C. Walters , C. A. Howard , M. Ellerby

Although not an intrinsic superconductor, it has been long--known that, when intercalated with certain dopants, graphite is capable of exhibiting superconductivity. Of the family of graphite--based materials which are known to superconduct,…

Superconductivity · Physics 2016-08-16 Gabor Csányi , P. B. Littlewood , A. H. Nevidomskyy , Chris J. Pickard , B. D. Simons

Electrons in isolated graphene layers are a two-dimensional gas of massless Dirac Fermions. In realistic devices, however, the electronic properties are modified by elastic deformations, interlayer coupling and substrate interaction. Here…

First-principles calculations of the electronic structure and vibrational modes, in a system of graphene bilayers and trilayers intercalated with alkaline earth atoms, are resented. It is found that, in similarity to the case of…

Superconductivity · Physics 2011-07-12 R. A. Jishi , D. M. Guzman , H. M. Alyahyaei

Quasi free-standing monolayer graphene can be produced by intercalating species like oxygen or hydrogen between epitaxial graphene and the substrate crystal. If the graphene is indeed decoupled from the substrate, one would expect the…

The out-of-plane intercalate phonons of superconducting YbC6 have been measured with inelastic x-ray scattering. Model fits to this data, and previously measured out-of-plane intercalate phonons in graphite intercalation compounds (GICs),…

Superconductivity · Physics 2015-05-20 M. H. Upton , T. R. Forrest , A. C. Walters , C. A. Howard , M. Ellerby , A. H. Said , D. F. McMorrow

Using density functional theory we demonstrate that superconductivity in C6Ca is due to a phonon-mediated mechanism with electron-phonon coupling 0.83 and phonon-frequency logarithmic-average 24.7 meV. The calculated isotope exponents are…

Superconductivity · Physics 2007-05-23 Matteo Calandra , Francesco Mauri

The electron-phonon interaction in monolayer graphene is investigated by using density functional perturbation theory. The results indicate that the electron-phonon interaction strength is of comparable magnitude for all four in-plane…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 K. M. Borysenko , J. T. Mullen , E. A. Barry , S. Paul , Y. G. Semenov , J. M. Zavada , M. Buongiorno Nardelli , K. W. Kim

The low energy phonons of two different graphite intercalation compounds (GICs) have been measured as a function of temperature using inelastic x-ray scattering (IXS). In the case of the non-superconductor BaC6, the phonons observed are…

The electronic structure and selected zone-center phonons in Yb graphite intercalation compound (YbC6) are investigated {theoretically} using density functional calculations and LDA+U approximation for Coulomb correlations in the f shell,…

Superconductivity · Physics 2007-05-23 I. I. Mazin , S. L. Molodtsov

We present a detailed in-situ Raman analysis of stage-1 KC8, CaC6, and LiC6 graphite intercalation compounds (GIC) to unravel their intrinsic finger print. Four main components were found between 1200 cm-1 and 1700 cm-1, and each of them…

Optics · Physics 2013-10-08 J. C. Chacón-Torres , A. Y. Ganin , M. J. Rosseinsky , T. Pichler

In graphene moir\'e superlattices, electronic interactions between layers are mostly hidden as band structures get crowded because of folding, making their interpretation cumbersome. Here, the evolution of the electronic band structure as a…

Mesoscale and Nanoscale Physics · Physics 2021-09-01 Francisco Sanchez-Ochoa , Andres Botello-Mendez , Cecilia Noguez

Using the {\it ab initio} anisotropic Eliashberg theory including Coulomb interactions, we investigate the electron-phonon interaction and the pairing mechanism in the recently-reported superconducting Ca-intercalated bilayer graphene. We…

Superconductivity · Physics 2016-01-25 E. R. Margine , Henry Lambert , Feliciano Giustino

We explore the electronic ground states of Bernal-stacked multilayer graphenes using the Hartree-Fock mean-field approximation and the full-parameter band model. We find that the electron-electron interaction tends to open a band gap in…

Mesoscale and Nanoscale Physics · Physics 2017-07-05 Mikito Koshino , Kyoka Sugisawa , Edward McCann

The field of superconductivity in the class of materials known as graphite intercalation compounds has a history dating back to the 1960s. This paper recontextualizes the field in light of the discovery of superconductivity in CaC6 and YbC6…

We present the results of a neutron scattering study of the high energy phonons in the superconducting graphite intercalation compound CaC$_6$. The study was designed to address hitherto unexplored aspects of the lattice dynamics in…

We study graphene antidot lattices -- superlattices of perforations (antidots) in a graphene sheet -- using a model that accounts for the phonon-modulation of the $\pi$-electron hopping integrals. We calculate the phonon spectra of selected…

Other Condensed Matter · Physics 2010-01-09 Nenad Vukmirovic , Vladimir M. Stojanovic , Mihajlo Vanevic

Radio-frequency compressed ultrafast electron diffraction has been used to probe the coherent and incoherent coupling of impulsive electronic excitation at 1.55 eV (800 nm) to optical and acoustic phonon modes directly from the perspective…

Materials Science · Physics 2015-06-23 Robert P. Chatelain , Vance R. Morrison , Bart L. M. Klarenaar , Bradley J. Siwick

We use first-principles calculation within the density functional theory (DFT) to explore the electronic properties on stage-1 Li- and Li+-graphite-intercalation compounds (GIC) for different concentrations, LiCx/Li+Cx with x= 6,12,18,24,32…

Materials Science · Physics 2020-06-24 Wei-Bang Li , Shih-Yang Lin , Ngoc Thanh Thuy Tran , Kuang-I Lin , Ming-Fa Lin
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